Method and apparatus for reducing a nitrogen oxide

• US 8,617,473 B2
• Filed: 09/29/2009
• Issued: 12/31/2013
• Est. Priority Date: 06/19/2002
• Status: Expired due to Fees

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: deRuyter, John C.
• Primary Examiner(s): Duong, Tom
• Application Number:
  US12/568,990
• Publication Number:
  US 20100021355A1
• Time in Patent Office: 1,554 Days
• Field of Search: 422/177, 422/50, 422/62, 422/80, 423/235, 423/239, 110/345, 702/22, 702/23, 702/30
• US Class Current: 422/169
• CPC Class Codes: B01D 53/8631 Processes characterised by a specific device
• CPC Class Codes: B01D 53/8696 Controlling the catalytic process
• CPC Class Codes: B01D 53/90 Injecting reactants
• CPC Class Codes: B01D 53/9431 Processes characterised by a specific device
• CPC Class Codes: B01D 53/9495 Controlling the catalytic process
• CPC Class Codes: F01N 13/009 having two or more separate purifying devices arranged in series
• CPC Class Codes: F01N 2610/02 the substance being ammonia or urea
• CPC Class Codes: F01N 3/2066 Selective catalytic reduction [SCR]
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

This invention relates to an apparatus for reducing a nitrogen oxide. In particular, it relates to the use of a gas analyzer to obtain information related to the compositional content of a multi-component gas mixture that contains a nitrogen oxide for the purpose of assisting in the control of the reduction. In particular, the apparatus provides control of the reaction of reduction, and, more particularly, control of the injection of a reducing agent into the gas mixture containing the nitrogen oxide. The apparatus enables the calculation of the amount of reducing agent to be injected in relation to information about the compositional content of the gas mixture, and a gas analyzer containing an array of chemo/electro-active materials may be used in conjunction therewith.

Claims

1. An apparatus for reducing a nitrogen oxide contained in a multi-component gas mixture emitted by an emissions source, comprising

(a) an exhaust conduit for transporting the gas mixture downstream from the emissions source,

(b) an injector for injecting a reducing agent into the conduit, and

(c) one or more gas analyzers located in the conduit downstream of the injector;

wherein a gas analyzer comprises an array of chemo/electro-active materials selected as a member from the group of three arrays of chemo/electro-active material consisting of;

(i) an array comprising ZnO_x, Nb_aTi_bO_x, Ni_aZn_bO_x, Sb_aSn_bO_x, Ta_aTi_bO_x, and Ti_aZn_bO_x;

(ii) an array comprising SnO_x, Ti_aZn_bO_x, Nb_aTi_bO_x, Ni_aZn_bO_x, Ta_aTi_bO_x, and Ga_aTi_bZn_cO_x;

(iii) an array comprising Nb_aTi_bO_x, Ni_aZn_bO_x, Ga_aTi_bZn_cO_x;

Sb_aSn_bO_x, Ta_aTi_bO_x, and Ti_aZn_bO_x;

wherein a, b and c are each independently about 0.0005 to about 1; and

wherein x is a number sufficient so that the oxygen present balances the charges of the other elements in the chemo/electro-active material; and

wherein a gas analyzer outputs at least one signal that is related to the individual concentration within the gas mixture of an individual gas component therein, and at least one signal that is related to the collective concentration within the gas mixture of a subgroup of the component gases therein.

2. An apparatus according to claim 1 further comprising a catalyst to catalyze the reduction of the nitrogen oxide.

3. An apparatus according to claim 2 wherein a catalyst is located upstream from a gas analyzer.

4. An apparatus according to claim 2 wherein a catalyst is located downstream from a gas analyzer.

5. An apparatus according to claim 2 wherein a first catalyst is located upstream from a gas analyzer, and a second catalyst is located downstream from the gas analyzer.

6. An apparatus according to claim 5 wherein a catalyst comprises a plurality of vertically arranged catalyst beds, and a first catalyst bed is located vertically upstream from a gas analyzer, and a second catalyst bed is located vertically downstream from the gas analyzer.

7. An apparatus according to claim 2 wherein a first gas analyzer is located upstream from a catalyst, and a second gas analyzer is located downstream from the catalyst.

8. An apparatus according to claim 2 which comprises a plurality of gas analyzers, and wherein a first catalyst is located upstream from a plurality of gas analyzers, and a second catalyst is located downstream from the plurality of gas analyzers.

9. An apparatus according to claim 2 wherein a gas analyzer that is upstream from all catalyst, and a gas analyzer that is downstream from all catalyst, both output a signal to a decision-making routine.

10. An apparatus according to claim 1 which comprises a plurality of gas analyzers.

11. An apparatus according to claim 1 further comprising one or more gas analyzers located in the conduit upstream from the injector.

12. An apparatus according to claim 1 wherein a gas analyzer outputs at least one signal that is related to the individual concentration within the gas mixture of an individual gas component therein.

13. An apparatus according to claim 1 wherein a gas analyzer outputs at least one signal that is related to the collective concentration within the gas mixture of a subgroup of the component gases therein.

14. An apparatus according to claim 1 wherein a gas analyzer outputs a signal to a decision-making routine or a map.

15. An apparatus according to claim 1 wherein a gas analyzer outputs a signal to a decision-making routine that controls the injection of reducing agent, and/or that calculates an amount of reducing agent to be injected.

16. An apparatus according to claim 1 wherein a gas analyzer outputs at least one signal that is related to (a) the individual concentration within the gas mixture of an individual nitrogen oxide component therein, (b) the collective concentration within the gas mixture of all nitrogen oxide components therein, and/or (c) the individual concentration within the gas mixture of a reducing agent.

17. An apparatus according to claim 1 wherein a gas analyzer outputs at least one signal that is related to the individual concentration within the gas mixture of one or more or all nitrogen oxide components therein, and the signal is outputted to a decision-making routine that calculates an amount of reducing agent to be injected.

18. An apparatus according to claim 1 wherein the combustion source is stationary.

19. An electrical generating plant, a furnace, a steam turbine or a gas turbine comprising an apparatus for reducing a nitrogen oxide gas according to claim 1.

20. An apparatus according to claim 1 wherein a gas analyzer comprises chemo/electro-active material array (I), being an array comprising ZnO_x, Nb_aTi_bO_x, Ni_aZn_bO_x, Sb_aSn_bO_x, Ta_aTi_bO_x, and Ti_aZn_bO_x.

21. An apparatus according to claim 1 wherein a gas analyzer comprises chemo/electro-active material array (II), being an array comprising SnO_x, Ti_aZn_bO_x, Nb_aTi_bO_x, Ni_aZn_bO_x, Ta_aTi_bO_x, and Ga_aTi_bZn_cO_x.

22. An apparatus according to claim 1 wherein a gas analyzer comprises chemo/electro-active material array (III), being an array comprising Nb_aTi_bO_x, Ni_aZn_bO_x, Ga_aTi_bZn_cO_x;

Sb_aSn_bO_x, Ta_aTi_bO_x, and Ti_aZn_bO_x.