Antireflective film, polarizing plate and image display device

• US 8,623,475 B2
• Filed: 02/09/2012
• Issued: 01/07/2014
• Est. Priority Date: 11/22/2006
• Status: Active Grant

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Inventors: Inoue, Rikio, Yoneyama, Hiroyuki, Mifune, Hiroyuki
• Primary Examiner(s): Hon, Sophie
• Application Number:
  US13/370,081
• Publication Number:
  US 20120262785A1
• Time in Patent Office: 698 Days
• Field of Search: 428/1.3, 428/1.4, 428/446, 349/122, 349/137, 359/586
• US Class Current: 428/1.3
• CPC Class Codes: C09K 2323/03 Viewing layer characterised by chemical composition
• CPC Class Codes: C09K 2323/031 Polarizer or dye
• CPC Class Codes: C09K 2323/04 Charge transferring layer characterised by chemical composition, i.e. conductive
• CPC Class Codes: G02B 1/111 using layers comprising organic materials
• CPC Class Codes: G02B 2207/121 Antistatic or EM shielding layer
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]

Abstract

An antireflective film is provided and includes: a transparent substrate; at least one conductive layer formed from a composition including at least one transparent conductive polymeric material and a compound forming a cross-liking site, the compound having a plurality of cross-linking reactive groups, at least one of which cross-links with the transparent conductive polymeric material; and at least one low refractive index layer.

Claims

1. An antireflective film comprising:

a transparent substrate;

a conductive layer formed from a composition including a transparent conductive polymeric material and a compound forming a cross-linking site, the compound forming a cross-linking site having a plurality of cross-linking reactive groups, at least one of which cross-links with the transparent conductive polymeric material; and

a low refractive index layer,

wherein the transparent conductive polymeric material is a complex of a π

-conjugated conductive polymer and a polymer dopant,

wherein the compound forming a cross-linking site is a compound having a first group capable of cross-linking with the polymer dopant and a second group having an ethylenically unsaturated double bond;

wherein the first group is a glycidyl group, an oxetane group, or an isocyanate group;

wherein the polymer dopant is a polyanionic polymer that has anionic groups in a molecule which enable chemically oxidative doping of the conductive polymer by the polymer dopant; and

wherein the amount of the cross-linking site-forming compound is from 0.05 to 1.0 g/m² and the surface resistance of the conductive layer is from 10⁴ to 10¹¹ Ω

/sq.

2. The antireflective film of claim 1, further comprising:

at least one layer of a hard coating layer and an antiglare layer between the transparent substrate and the conductive layer.

3. The antireflective film of claim 2, wherein the n-conjugated conductive polymer is a homopolymer or copolymer made from one or two polymers selected from the group consisting of polypyrrole, polythiophene, poly(N-methylpyrrole), poly(3-methylthiophene), poly(-methoxythiophene), and poly(3,4-ethylenedioxythiophene).

4. The antireflective film of claim 1, wherein the polymer dopant has at least one anionic group and at least one non-anionic group.

5. The antireflective film of claim 4, wherein the π

-conjugated conductive polymer is a homopolymer or copolymer made from one or two polymers selected from the group consisting of polypyrrole, polythiophene, poly(N-methylpyrrole), poly(3-methylthiophene), poly(-methoxythiophene), and poly(3,4-ethylenedioxythiophene).

6. The antireflective film of claim 1, wherein the compound forming a cross-linking site has a group cross-linking with the polymer dopant.

7. The antireflective film of claim 6, wherein the π

-conjugated conductive polymer is a homopolymer or copolymer made from one or two polymers selected from the group consisting of polypyrrole, polythiophene, poly(N-methylpyrrole), poly(3-methylthiophene), poly(-methoxythiophene), and poly(3,4-ethylenedioxythiophene).

8. The antireflective film of claim 1, further comprising:

a middle refractive index layer and a high refractive index layer between the conductive layer and the low refractive index layer,

wherein the middle refractive index layer, the high refractive index layer and the low refractive index layer are arranged in increasing order of distance from the transparent substrate, the middle refractive index layer has a refractive index of 1.5 to 1.7, the high refractive index layer has a refractive index of 1.7 to 2.1, and the low refractive index layer has a refractive index of 1.3 to 1.5.

9. The antireflective film of claim 8, wherein the n-conjugated conductive polymer is a homopolymer or copolymer made from one or two polymers selected from the group consisting of polypyrrole, polythiophene, poly(N-methylpyrrole), poly(3-methylthiophene), poly(-methoxythiophene), and poly(3,4-ethylenedioxythiophene).

10. A polarizing plate comprising:

a polarizer; and

two protective films sandwiching the polarizer therebetween, at least one of the two protective films being an antireflective film of claim 1.

11. An image display device comprising a polarizing plate of claim 10.

12. The antireflective film of the polarizing plate of claim 10, wherein the π

-conjugated conductive polymer is a homopolymer or copolymer made from one or two polymers selected from the group consisting of polypyrrole, polythiophene, poly(N-methylpyrrole), poly(3-methylthiophene), poly(-methoxythiophene), and poly(3,4-ethylenedioxythiophene).

13. The antireflective film of claim 1, wherein the π

-conjugated conductive polymer is a homopolymer or copolymer made from one or two polymers selected from the group consisting of polypyrrole, polythiophene, poly(N-methylpyrrole), poly(3-methylthiophene), poly(-methoxythiophene), and poly(3,4-ethylenedioxythiophene).

14. The antireflective film of claim 1, wherein the surface resistance of the conductive layer is from 10⁴ to 10⁵ Ω

/sq.