Compositions containing tetrafluoropropene and carbon dioxide

• US 8,623,808 B2
• Filed: 08/05/2011
• Issued: 01/07/2014
• Est. Priority Date: 04/29/2004
• Status: Expired due to Term

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Singh, Rajiv R., Pham, Hang T., Shankland, Ian
• Primary Examiner(s): WEBB, GREGORY E
• Application Number:
  US13/204,428
• Publication Number:
  US 20110289748A1
• Time in Patent Office: 886 Days
• Field of Search: 510/408, 510/412, 252/67, 252/68
• US Class Current: 510/408
• CPC Class Codes: C08J 2203/06 CO2, N2 or noble gases
• CPC Class Codes: C08J 2203/162 Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
• CPC Class Codes: C08J 2205/052 Closed cells, i.e. more than 50% of the pores are closed
• CPC Class Codes: C08J 2300/22 Thermoplastic resins
• CPC Class Codes: C08J 2323/06 Polyethene
• CPC Class Codes: C08J 2323/12 Polypropene
• CPC Class Codes: C08J 2325/06 Polystyrene
• CPC Class Codes: C08J 2367/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds; C08J2367/06 takes precedence
• CPC Class Codes: C08J 9/122 Hydrogen, oxygen, CO2, nitrogen or noble gases
• CPC Class Codes: C08J 9/127 Mixtures of organic and inorganic blowing agents
• CPC Class Codes: C08J 9/146 only fluorine as halogen atoms
• CPC Class Codes: C09K 3/30 for aerosols aerosol containers B65D83/14
• CPC Class Codes: C09K 5/045 containing only fluorine as halogen
• CPC Class Codes: C11D 7/5063 Halogenated hydrocarbons containing heteroatoms, e.g. fluoro alcohols
• CPC Class Codes: Y10T 29/4973 Replacing of defective part

Abstract

Disclosed are compositions useful in a wide variety of applications, including heat transfer fluids which possess a highly desirable and unexpectedly superior combination of properties, and heat transfer systems and methods based on these fluids. The preferred heat transfer fluid comprises from about 1 to about 40 percent, on a weight basis, of carbon dioxide (CO₂) and from about 99 to about 60 percent, on a weight basis, of a compound having the Formula I XCF_zR_3-z (I), where X is a C₂ or a C₃ unsaturated, substituted or unsubstituted, alkyl radical, each R is independently Cl, F, Br, I or H, and z is 1 to 3. A preferred compound of Formula I is tetrafluoropropene, particularly 1,1,1,3-tetrafluoropropene and/or 1,1,1,3-tetrafluoropropene.

Claims

1. A composition comprising from about 1 to about 40 percent by weight of carbon dioxide (CO₂) and from about 60 to about 99 percent by weight of one or more compounds of Formula I, XCF₃(I), where X is a C₂ unsaturated, substituted, alkyl radical.

2. The composition of claim 1 wherein said one or more compounds of Formula I comprises 1,1,1,3-tetrafluoropropene (HFO-1234) and wherein said composition has a vapor pressure of at least about 30 psia at 35°

F.

3. The composition of claim 1 wherein said one or more compounds of Formula I comprises 1,1,1,3-tetrafluoropropene (HFO-1234ze).

4. The composition of claim 3 wherein said one or more compounds of Formula I comprises trans-1,1,1,3-tetrafluoropropene (transHFO-1234ze) and wherein said composition has a vapor pressure of at least about 30 psia at 35°

F.

5. A heat transfer composition comprising the composition of claim 1 and further comprising at least one lubricant.

6. The heat transfer composition of claim 5 wherein said lubricant is selected from the group consisting of mineral oil, silicone oil, polyalkyl benzenes (PABs), polyol esters (POEs), polyalkylene glycols (PAGs), polyalkylene glycol esters (PAG esters), polyvinyl ethers (PVEs), poly(alpha-olefins) (PAOs), and combinations of these.

7. A blowing agent comprising a composition of claim 1.

8. A blowing agent of claim 7 wherein said compound of formula I and said CO₂ together comprise at least about 5% by weight of the blowing agent.

9. A foamable composition comprising the blowing agent of claim 8.

10. A method of replacing an existing refrigerant contained in a refrigerant system comprising removing at least a portion of said existing refrigerant from said system and replacing at least a portion of said existing refrigerant by introducing into said system a refrigerant composition comprising a composition of claim 1.

11. The method of claim 10 wherein said existing refrigerant system comprises at least a first compressor having a first displacement and further comprising the step of removing said first compressor from the system and inserting in said system at least a second compressor having a larger displacement than said first compressor.

12. A sprayable composition comprising a material to be sprayed and a propellant comprising the composition of claim 1.

13. The sprayable composition of claim 12 in the form of an aerosol.

14. The sprayable composition of claim 12 wherein said material to be sprayed is selected from the group consisting of cosmetics, cleaning solvent, lubricants and medicinal materials.

15. A method of sterilizing an article comprising contacting said article with a composition comprising the composition of claim 1.

16. The composition of claim 1 in the form of a heat transfer fluid having a refrigeration capacity substantially matching that of R-22.

17. The composition of claim 1 in the form of a heat transfer fluid having a refrigeration capacity substantially matching that of R-407C.

18. The composition of claim 1 in the form of a heat transfer fluid having a refrigeration capacity substantially matching that of R-410A.

19. The composition of claim 1 comprising from about 5 to about 35 percent by weight of carbon dioxide (CO₂) and from about 65 to about 95 percent by weight of one or more compounds of Formula I.