High strength steel having good toughness

• US 8,636,856 B2
• Filed: 02/18/2011
• Issued: 01/28/2014
• Est. Priority Date: 02/18/2011
• Status: Active Grant

• Current Assignee: Siderca Saic
• Original Assignee: Siderca Saic
• Inventors: Altschuler, Eduardo, Perez, Teresa, Lopez, Edgardo, Espinosa, Constantino, Gomez, Gonzalo
• Primary Examiner(s): WALCK, BRIAN D
• Application Number:
  US13/031,131
• Publication Number:
  US 20120211131A1
• Time in Patent Office: 1,075 Days
• Field of Search: 148/519, 148/590, 148/594, 148/653, 148/654, 148/663, 148/909, 148/333, 148/334, 148/593
• US Class Current: 148/590
• CPC Class Codes: C21D 1/25 Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
• CPC Class Codes: C21D 2211/008 Martensite
• CPC Class Codes: C21D 8/105 of ferrous alloys
• CPC Class Codes: C21D 9/08 for tubular bodies or pipes
• CPC Class Codes: C22C 38/002 containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
• CPC Class Codes: C22C 38/02 containing silicon
• CPC Class Codes: C22C 38/04 containing manganese
• CPC Class Codes: C22C 38/06 containing aluminium
• CPC Class Codes: C22C 38/22 with molybdenum or tungsten
• CPC Class Codes: C22C 38/26 with niobium or tantalum
• CPC Class Codes: C22C 38/44 with molybdenum or tungsten
• CPC Class Codes: C22C 38/46 with vanadium
• CPC Class Codes: C22C 38/48 with niobium or tantalum
• CPC Class Codes: C22C 38/50 with titanium or zirconium
• CPC Class Codes: Y10T 428/12 All metal or with adjacent metals

Abstract

Embodiments of the present disclosure comprise carbon steels and methods of manufacture. In one embodiment, quenching and tempering procedure is performed in which a selected steel composition is formed and heat treated to yield a slightly tempered microstructure having a fine carbide distribution. In another embodiment, a double austenizing procedure is disclosed in which a selected steel composition is formed and subjected to heat treatment to refine the steel microstructure. In one embodiment, the heat treatment may comprise austenizing and quenching the formed steel composition a selected number of times (e.g., 2) prior to tempering. In another embodiment, the heat treatment may comprise subjecting the formed steel composition to austenizing, quenching, and tempering a selected number of times (e.g., 2). Steel products formed from embodiments of the steel composition in this manner (e.g., seamless tubular bars and pipes) will possess high yield strength, e.g., at least about 165 ksi, while maintaining good toughness.

Claims

1. A method of making a steel tube, comprising:

providing a carbon steel composition comprising;

about 0.20 wt. % to about 0.30 wt. % carbon;

about 0.30 wt. % to about 0.70 wt. % manganese

about 0.10 wt. % to about 0.30 wt. % silicon;

about 0.90 wt. % to about 1.50 wt. % chromium;

about 0.60 wt. % to about 1.00 wt. % molybdenum;

about 0.020 wt. % to about 0.40 wt. % niobium; and

about 0.01 wt. % to about 0.04 wt. % aluminum;

forming the steel composition into a tube;

heating the formed steel tube in a heating operation to a first temperature of about 880°

C. to about 950°

C. for about 10 to 30 minutes;

quenching the formed steel tube in a quenching operation from the first temperature at a first rate such that the microstructure of the quenched steel is greater than or equal to about 95% martensite by volume; and

tempering the formed steel tube after the quenching operation by heating the formed steel tube to a second temperature less than about 550°

C.;

wherein the steel tube after tempering has a yield strength greater than about 165 ksi and wherein the Charpy V-notch energy is greater or equal to about 80 J/cm² in the longitudinal direction and 60 J/cm² in the transverse direction at about room temperature.

2. The method of claim 1, wherein the first temperature is between about 900°

C. to about 950°

C. for about 10 to 30 minutes.

3. The method of claim 1, wherein the second temperature is between about 450°

C. to about 550°

C. for about 5 to 30 minutes.

4. The method of claim 1, wherein the grain size of the formed steel composition after quenching is between about 5 to about 15 μ

m.

5. The method of claim 1, wherein the microstructure of the steel tube, comprises a plurality of approximately spherical carbides having a largest dimension less than or equal to about 150 nm after tempering.

6. The method of claim 1, wherein microstructure of the steel tube comprises a plurality of elongated carbides having a length less than or equal to about 1 μ

m and a thickness less than or equal to about 200 nm after tempering.

7. The method of claim 1, wherein the first quenching rate is between about 15°

C./sec to 50°

C./sec.

8. The method of claim 1, wherein the steel composition further comprises:

about 0.24 wt. % to about 0.27 wt. % carbon;

about 0.45 wt. % to about 0.55 wt. % manganese;

about 0.20 wt. % to about 0.30 wt. % silicon;

about 0.90 wt. % to about 1.00 wt. % chromium;

about 0.65 wt. % to about 0.70 wt. % molybdenum; and

about 0.025 wt. % to about 0.30 wt. % niobium.

9. The method of claim 1, wherein the composition further comprises at least one of:

less than or equal to about 0.50 wt. % nickel;

less than or equal to about 0.005 wt. % vanadium;

less than or equal to about 0.010 wt. % titanium and

less than or equal to about 0.05 wt. % calcium.

10. The method of claim 1, wherein the composition comprises substantially no vanadium.

11. The method of claim 1, wherein the remainder of the microstructure consists essentially of bainite after the quenching operation.

12. The method of claim 1, wherein after the quenching operation and before the tempering operation, the formed steel tube undergoes a second heating operation and a second quenching operation.

13. The method of claim 1, wherein after tempering, the formed steel tube undergoes a second heating operation, a second quenching operation, and a second tempering operation.

14. A method of forming a steel tube, comprising:

providing a steel rod comprising;

about 0.20 wt. % to about 0.30 wt. % carbon;

about 0.30 wt. % to about 0.70 wt. % manganese;

about 0.10 wt. % to about 0.30 wt. % silicon;

about 0.90 wt. % to about 1.50 wt. % chromium;

about 0.60 wt. % to about 1.00 wt. % molybdenum;

about 0.020 wt. % to about 0.40 wt. % niobium; and

about 0.01 wt. % to about 0.04 wt. % aluminum;

forming the steel rod into a tube in a hot forming operation at a temperature of about 1200°

C. to 1300°

C.;

heating the formed steel tube in a first heating operation to a temperature of about 880°

C. to 950°

C. for about 10 to 30 minutes;

quenching the formed steel tube in a first quenching operation after the first heating operation at a rate such that the microstructure of the quenched steel is greater than or equal to about 95% martensite by volume; and

tempering the formed steel tube after the first quenching operation by heating the formed steel tube to a temperature between about 450°

C. to about 550°

C. for between about 5 minutes to about 30 minutes;

wherein the steel tube after tempering has a yield strength greater than about 165 ksi and wherein the Charpy V-notch energy is greater or equal to about 80 J/cm² in the longitudinal direction and about 60 J/cm² in the transverse direction at about room temperature.

15. The method of claim 14, wherein the first heating operation is at a temperature of about 900°

C. to 950°

C., and further comprising, prior to said tempering;

heating the formed steel tube in a second heating operation to a temperature lower than that of the first heating operation of about 880°

C. to 930°

C. for about 10 to 30 minutes; and

quenching the formed steel tube in a second quenching operation after the second heating operation such that the microstructure of the quenched steel is greater than or equal to about 95% martensite by volume;

wherein the steel tube after tempering has a yield strength greater than about 170 ksi and wherein the Charpy V-notch energy is greater or equal to about 80 J/cm² in the longitudinal direction and about 60 J/cm² in the transverse direction at about room temperature.

16. The method of claim 15, further comprising, after said first quenching operation and prior to said second quenching operation, tempering the formed steel tube at a temperature below about 550°

C.

17. The method of claim 14, wherein the microstructure of the steel tube comprises a plurality of approximately spherical carbides having a largest dimension less than or equal to about 150 nm after tempering.

18. The method of claim 14, wherein microstructure of the steel tube comprises a plurality of elongated carbides having a length less than or equal to about 1 μ

m and a thickness less than or equal to about 200 nm after tempering.