Multiphase electrochemical reduction of CO 2
First Claim
1. A method for co-producing a reduction product from carbon dioxide and an oxidation product, the method comprising the steps of:
- a. providing an electrochemical cell comprising a cathode region comprising a cathode, an anode region comprising an anode and an ion permeable zone between the anode region and the cathode region;
b. adding a non-aqueous catholyte to the cathode region whereby the catholyte region is non-aqueous;
c. adding an aqueous or gaseous anolyte to the anode region whereby the anode region is either aqueous or gaseous and adding a carbon based organic compound to the anode region;
d. adding carbon dioxide to the cathode region;
e. adding an electrolyte to the anode and cathode regions, the electrolyte being at least one selected from;
an alkali metal salt, an alkaline earth salt;
an onium salt, an aromatic or alkyl amine, a primary, secondary or tertiary amine salt, or a hydrogen halide;
f. adding an oxidizable anodic reactant to the anode region;
g. adding a phase transfer agent to at least one of the anode region and the cathode region; and
h. applying a source of energy across the anode and cathode to reduce the carbon dioxide and produce an oxidation product.
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Abstract
Disclosed is a system and method for reducing carbon dioxide into a carbon based product. The system includes an electrochemical cell having a cathode region which includes a cathode and a non-aqueous catholyte; an anode region having an anode and an aqueous or gaseous anolyte; and an ion permeable zone disposed between the anode region and the cathode region. The ion permeable zone is at least one of (i) the interface between the anolyte and the catholyte, (ii) an ion selective membrane; (iii) at least one liquid layer formed of an emulsion or (iv) a hydrophobic or glass fiber separator. The system and method includes a source of energy, whereby applying the source of energy across the anode and cathode reduces the carbon dioxide and produces an oxidation product.
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Citations
9 Claims
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1. A method for co-producing a reduction product from carbon dioxide and an oxidation product, the method comprising the steps of:
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a. providing an electrochemical cell comprising a cathode region comprising a cathode, an anode region comprising an anode and an ion permeable zone between the anode region and the cathode region; b. adding a non-aqueous catholyte to the cathode region whereby the catholyte region is non-aqueous; c. adding an aqueous or gaseous anolyte to the anode region whereby the anode region is either aqueous or gaseous and adding a carbon based organic compound to the anode region; d. adding carbon dioxide to the cathode region; e. adding an electrolyte to the anode and cathode regions, the electrolyte being at least one selected from;
an alkali metal salt, an alkaline earth salt;
an onium salt, an aromatic or alkyl amine, a primary, secondary or tertiary amine salt, or a hydrogen halide;f. adding an oxidizable anodic reactant to the anode region; g. adding a phase transfer agent to at least one of the anode region and the cathode region; and h. applying a source of energy across the anode and cathode to reduce the carbon dioxide and produce an oxidation product. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9)
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Specification