Transparent ink-jet recording films, compositions, and methods

• US 8,642,143 B2
• Filed: 08/03/2012
• Issued: 02/04/2014
• Est. Priority Date: 08/12/2011
• Status: Active Grant

• Current Assignee: CareStream Health Incorporated
• Original Assignee: CareStream Health Incorporated
• Inventors: Simpson, Sharon M., Vosberg, Heidy M., Leach, Daniel P., Ruzinsky, William J., Devine, William D.
• Primary Examiner(s): Shewareged, Betelhem
• Application Number:
  US13/565,888
• Publication Number:
  US 20130040077A1
• Time in Patent Office: 550 Days
• Field of Search: 428/32.13, 428/32.22, 428/32.25, 428/32.26, 428/32.27, 428/32.28, 428/32.31, 428/32.35
• US Class Current: 428/32.13
• CPC Class Codes: B41M 2205/28 Storage stability; Improved self life
• CPC Class Codes: B41M 2205/36 Backcoats; Back layers
• CPC Class Codes: B41M 5/504 Backcoats
• CPC Class Codes: B41M 5/506 Intermediate layers
• CPC Class Codes: B41M 5/508 Supports
• CPC Class Codes: B41M 5/52 Macromolecular coatings
• CPC Class Codes: B41M 5/5218 characterised by inorganic additives, e.g. pigments, clays
• CPC Class Codes: B41M 5/5254 characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

Abstract

Transparent ink-jet recording films, compositions, and methods are disclosed. Such films exhibit superior resistance to ink-transfer when printed to high optical densities, which is desirable for medical imaging applications.

Claims

1. A transparent ink-jet recording film comprising:

a transparent substrate comprising a polyester, said substrate comprising at least a first surface and a second surface;

at least one under-layer disposed on said first surface, said at least one under-layer comprising gelatin and at least one borate or borate derivative;

at least one image-receiving layer disposed on said at least one under-layer, said at least one image-receiving layer comprising at least one water soluble or water dispersible polymer and at least one inorganic particle, said at least one water soluble or water dispersible polymer comprising at least one hydroxyl group; and

at least one back-coat layer disposed on said second surface, said at least one back-coat layer comprising gelatin, at least one polymer particle comprising at least one thermoplastic polymer, and at least one other hydrophilic colloid comprising at least one of sodium carboxymethylate casein or a polyacrylamide,

wherein said at least one polymer particle comprises a dry coverage of at least about 40 mg/m².

2. The transparent ink-jet recording film according to claim 1, wherein the at least one polymer particle comprises at least one polymer comprising at least one acrylic or methacrylic repeat unit.

3. The transparent ink jet recording film according to claim 1, wherein the at least one polymer particle comprises poly(methyl methacrylate).

4. The transparent ink-jet recording film according to claim 1, wherein the at least one polymer particle comprises a dry coverage of at least about 100 mg/m².

5. The transparent ink-jet recording film according to claim 1, wherein the at least one particle comprises a mean diameter of at least about 5 μ

m and less than about 25 μ

m.

6. The transparent ink-jet recording film according to claim 1, wherein the at least one back-coat layer comprises sodium carboxymethylate casein and at least one polyacrylamide.

7. The transparent ink jet recording film according to claim 1, wherein the at least one back-coat layer further comprises at least one polysiloxane.

8. The transparent ink-jet recording film according to claim 1, wherein the at least one back-coat layer comprises at least one first layer and at least one second layer, said at least one first layer being disposed between said at least one second layer and the second surface of the transparent substrate,

wherein said at least one first layer comprises gelatin and at least one hardener, and said at least one second layer comprises gelatin and the at least one polymer particle.

9. The transparent ink-jet recording film according to claim 8, wherein the at least one second layer further comprises at least one other hydrophilic colloid comprising at least one of sodium carboxymethylate casein or a polyacrylamide.

10. The transparent ink jet recording film according to claim 8, wherein the at least one second layer further comprises sodium carboxymethylate casein and at least one polyacrylamide.

11. The transparent ink jet recording film according to claim 8, wherein the at least one second layer further comprises at least one polysiloxane.

12. The transparent ink-jet recording film according to claim 8, wherein the at least one hardener comprises bis(vinylsulfonyl)methane.

13. The transparent ink jet recording film according to claim 1, wherein the at least one inorganic particle comprises boehmite alumina.

14. The transparent ink-jet recording film according to claim 1, wherein the at least one borate or borate derivative comprises at least one hydrate of sodium tetraborate.

15. The transparent ink-jet recording film according to claim 1, wherein the at least one water soluble or water dispersible polymer comprises poly(vinyl alcohol).

16. The transparent ink-jet recording film according to claim 1 comprising an ink transfer measurement of less than about two squares transferred when subjected to 0.081 psi pressure and 85% relative humidity for seven days, wherein said ink transfer measurement is based on 390 ⅛

-in×

⅛

-in grid squares.

17. The transparent ink-jet recording film according to claim 1 comprising an ink transfer measurement of less than about 31 squares transferred when subjected to 5.7 psi pressure and 86% relative humidity for seven days, wherein said ink transfer measurement is based on 390 ⅛

-in×

⅛

-in grid squares.

18. The transparent ink jet recording film according to claim 1 comprising an ink transfer measurement of less than about 9 squares transferred when subjected to 5.7 psi pressure and 86% relative humidity for seven days, wherein said ink transfer measurement is based on 390 ⅛

- in×

⅛

-in grid squares.