Method and system to reduce porosity in composite structures

• US 8,647,548 B1
• Filed: 08/31/2012
• Issued: 02/11/2014
• Est. Priority Date: 08/31/2012
• Status: Expired due to Fees

• Current Assignee: The Boeing Co.
• Original Assignee: The Boeing Co.
• Inventors: Humfeld, Keith Daniel
• Primary Examiner(s): DANIELS, MATTHEW J
• Application Number:
  US13/602,096
• Publication Number:
  US 20140060731A1
• Time in Patent Office: 529 Days
• Field of Search: 264/258, 264/137
• US Class Current: 264/137
• CPC Class Codes: B29C 70/44 using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
• CPC Class Codes: C08J 3/20 Compounding polymers with additives, e.g. colouring
• CPC Class Codes: C08J 5/243 using carbon fibres
• CPC Class Codes: C08J 5/249 characterised by the additives used in the prepolymer mixture
• CPC Class Codes: Y02T 50/40 Weight reduction

Abstract

In an embodiment of the disclosure, there is provided a method to reduce porosity in a composite structure. The method adds an additive to a resin material to form an additive-resin mixture. The method combines the additive-resin mixture with reinforcement fibers to form a composite prepreg material, and in turn, a composite structure. The method heat cures the composite structure in a heating apparatus under a vacuum device at the resin cure temperature, heats the composite structure to an increased temperature above the additive phase transition temperature, and maintains the increased temperature for a time period sufficient. The method reduces the increased temperature back down to the resin cure temperature to allow the additive gas to undergo a phase transition to a condense phase, resulting in a substantially reduced vacuum pressure, resulting in a reduction in a porosity of the composite structure.

Claims

1. A method to reduce porosity in a composite structure, the method comprising:

adding an additive to a resin material to form an additive-resin mixture, the additive comprising a phase transition material having an additive phase transition temperature greater than a resin cure temperature of the resin material;

combining the additive-resin mixture with a plurality of reinforcement fibers to form a composite prepreg material;

forming the composite prepreg material into a composite structure;

heat curing the composite structure in a heating apparatus under a vacuum device at an effective vacuum pressure for an effective time period at the resin cure temperature sufficient to decrease a viscosity of the resin material;

heating the composite structure to an increased temperature above the additive phase transition temperature and above the resin cure temperature and maintaining the increased temperature for a time period sufficient for the additive to undergo a phase transition and to form an additive gas that substantially displaces one or more gases out of the composite structure;

reducing the increased temperature back down to the resin cure temperature to allow the additive gas to undergo a phase transition to a condensed phase, resulting in a substantially reduced vacuum pressure in the composite structure, and resulting in a reduction in porosity of the composite structure; and

,

cooling the composite structure.

2. The method of claim 1 wherein the adding the additive to the resin material further comprises adding an additive selected from the group consisting of alkanes having nine or more carbon atoms with a boiling point at one atmosphere pressure at a temperature in a range of from about 250°

F. (degrees Fahrenheit) to about 950°

F.;

phenylpropenes with a boiling point at one atmosphere at a temperature in a range of from about 392°

F. to about 500°

F.; and

polycyclic aromatic hydrocarbons with a boiling point at one atmosphere pressure at a temperature in a range from about 422°

F. to about 980°

F.; and

triacylglycerides.

3. The method of claim 1 wherein the adding the additive to the resin material further comprises adding the additive in an amount of 0.01 volume percent to about 1.5 volume percent based on a total volume of the additive-resin mixture.

4. The method of claim 1 wherein the adding the additive to the resin material further comprises adding the additive to a resin material selected from the group consisting of epoxy resins, epoxy amine resins, polyimide resins, bismaleimide resins, phenolic resins, silicone resins, and a combination thereof.

5. The method of claim 1 wherein the forming the composite prepreg material into the composite structure further comprises laying up the composite prepreg material via a forming process comprising a manual layup or an automated layup with a layup machine.

6. The method of claim 1 wherein the heat curing the composite structure further comprises heat curing the composite structure in a heating apparatus comprising an autoclave or an oven.

7. The method of claim 1 wherein the heat curing the composite structure further comprises heat curing the composite structure under a vacuum device comprising a hermetically sealed flexible vacuum bag.

8. The method of claim 1 wherein the heating the composite structure to the increased temperature further comprises heating the composite structure to an increased temperature in a range of from about 5 degrees Fahrenheit to about 20 degrees Fahrenheit above the resin cure temperature and the additive phase transition temperature.

9. The method of claim 1 wherein the heating the composite structure to the increased temperature above the additive phase transition temperature further comprises maintaining the increased temperature for a time period in a range of from about one minute to about fifteen minutes.

10. The method of claim 1 wherein the heating the composite structure to the increased temperature above the additive phase transition temperature further comprises forming the additive gas that substantially displaces one or more gases, the one or more gases comprising entrapped air and volatiles including absorbed moisture, dissolved water, and resin outgases.

11. A method to reduce a porosity in an aircraft composite part, the method comprising:

adding an additive to a resin material to form an additive-resin mixture, the additive comprising a phase transition material having an additive phase transition temperature greater than a resin cure temperature of the resin material;

combining the additive-resin mixture with a plurality of reinforcement carbon fibers to form a composite prepreg material;

laying up the composite prepreg material via a forming process comprising a manual layup or an automated layup;

surrounding the aircraft composite part under a vacuum bag under a vacuum pressure;

heat curing in a heating apparatus comprising an autoclave or an oven, the aircraft composite part surrounded under the vacuum bag at an effective vacuum pressure, for an effective time period, to the resin cure temperature sufficient to decrease a viscosity of the resin material;

maintaining the resin cure temperature for an effective resin cure time period;

heating the aircraft composite part to an increased temperature in a range of from about 5 degrees Fahrenheit to about 20 degrees Fahrenheit above the additive phase transition temperature and above the resin cure temperature;

maintaining the increased temperature for a time period sufficient for the additive to undergo a liquid to gas phase transition and to form an additive gas that substantially displaces one or more gases out of the aircraft composite part;

reducing the increased temperature back down to the resin cure temperature to allow the additive gas to undergo a phase transition to a condensed phase, resulting in a substantially reduced vacuum pressure in the aircraft composite part, and resulting in a reduction in a porosity of the aircraft composite part;

cooling the aircraft composite part; and

,

removing the cooled aircraft composite part out of the autoclave.

12. The method of claim 11 wherein adding the additive to the resin material further comprises adding an additive selected from the group consisting of alkanes having nine or more carbon atoms with a boiling point at one atmosphere pressure at a temperature in a range of from about 250°

F. (degrees Fahrenheit) to about 950°

F.;

phenylpropenes with a boiling point at one atmosphere at a temperature in a range of from about 392°

F. to about 500°

F.; and

polycyclic aromatic hydrocarbons with a boiling point at one atmosphere pressure at a temperature in a range from about 422°

F. to about 980°

F.; and

triacylglycerides.

13. The method of claim 11 wherein the adding the additive to the resin material further comprises adding the additive to a resin material selected from the group consisting of epoxy resins, epoxy amine resins, polyimide resins, bismaleimide resins, phenolic resins, silicone resins, and a combination thereof.