Carbon material for lithium ion secondary battery
First Claim
1. A carbon material for lithium ion secondary battery having a surface functional group amount O/C, a surface functional group amount Cl/C, and a surface functional group amount S165/C, wherein the surface functional group amount O/C value represented by the following formula 1 is from 1 to 4% and a sum (Cl/C+S165/C) of the surface functional group amount Cl/C value represented by the following formula 2 and the surface functional group amount S165/C value represented by the following formula 3 is from 0.05 to 0.5%:
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O/C value (%)=O atom concentration determined based on the peak area of the spectrum of O1s in X-ray photoelectron spectroscopy (XPS) analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×
100
Formula 1;
Cl/C value (%)=Cl atom concentration determined based on the peak area of the spectrum of Cl2p in XPS analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×
100
Formula 2;
S165/C value (%)=S165 atom concentration based on the peak area of the peak near 165 eV in the spectrum corresponding to S2p in XPS analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×
100
Formula 3.
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Abstract
To provide a negative electrode material capable of giving a lithium ion secondary battery that is sufficiently small in the charge/discharge irreversible capacity observed at the initial cycle stage, has excellent high-temperature storage characteristics, and reduced in the gas generation at the initial cycle stage as well as during high-temperature storage.
A carbon material for lithium ion secondary battery, wherein the surface functional group amount O/C value represented by the following formula 1 is from 1 to 4% and the sum (Cl/C+S165/C) of the surface functional group amount Cl/C value represented by the following formula 2 and the surface functional group amount S165/C value represented by the following formula 3 is from 0.05 to 0.5%:
O/C value (%)=O atom concentration determined based on the peak area of the spectrum of O1s in X-ray photoelectron spectroscopy (XPS) analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×100 Formula 1:
Cl/C value (%)=Cl atom concentration determined based on the peak area of the spectrum of Cl2p in XPS analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×100 Formula 2:
S165/C value (%)=S165 atom concentration based on the peak area of the peak near 165 eV in the spectrum corresponding to S2p in XPS analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×100 Formula 3.
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Citations
7 Claims
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1. A carbon material for lithium ion secondary battery having a surface functional group amount O/C, a surface functional group amount Cl/C, and a surface functional group amount S165/C, wherein the surface functional group amount O/C value represented by the following formula 1 is from 1 to 4% and a sum (Cl/C+S165/C) of the surface functional group amount Cl/C value represented by the following formula 2 and the surface functional group amount S165/C value represented by the following formula 3 is from 0.05 to 0.5%:
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O/C value (%)=O atom concentration determined based on the peak area of the spectrum of O1s in X-ray photoelectron spectroscopy (XPS) analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×
100
Formula 1;
Cl/C value (%)=Cl atom concentration determined based on the peak area of the spectrum of Cl2p in XPS analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×
100
Formula 2;
S165/C value (%)=S165 atom concentration based on the peak area of the peak near 165 eV in the spectrum corresponding to S2p in XPS analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×
100
Formula 3. - View Dependent Claims (2, 3, 4, 5, 6, 7)
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Specification