Polyacrylic acid (salt) -based water-absorbent resin and a method for producing it

• US 8,648,161 B2
• Filed: 02/08/2010
• Issued: 02/11/2014
• Est. Priority Date: 02/06/2009
• Status: Active Grant

• Current Assignee: Nippon Shokubai Company Limited
• Original Assignee: Nippon Shokubai Company Limited
• Inventors: Fujino, Shinichi, Ishizaki, Kunihiko, Nagasawa, Eri, Matsumoto, Satoshi
• Primary Examiner(s): Heincer, Liam
• Assistant Examiner(s): LACAP, MARILOU U
• Application Number:
  US13/148,356
• Publication Number:
  US 20110306732A1
• Time in Patent Office: 1,464 Days
• Field of Search: 524/556, 525/385, 526/241, 526/317.1, 528/503, 528/502.R
• US Class Current: 526/317.1
• CPC Class Codes: C08F 2/44 Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
• CPC Class Codes: C08F 220/06 Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof

Abstract

The purpose of the present invention is to improve the water absorption of a water-absorbent resin without sacrificing the productivity, production cost, safety, and so on. Provided is a sustainable and renewable water-absorbent resin with excellent whiteness, which is suitable for mass consumption as disposal diapers or the like, and which can dispense with excessive purification of raw material acrylic acid. Also provided is a process for the production of a water-absorbent resin, which comprises: a step of preparing acrylic monomers; a step of polymerizing the monomers; and a step of drying the obtained aqueous gel, wherein the monomers at the time of polymerization contain at least 400 ppm of propionic acid.

Claims

1. A method for producing a polyacrylic acid (salt)-based water-absorbent resin, the method comprising:

a preparation step in which a monomer is prepared from acrylic acid containing propionic acid;

a polymerization step in which the monomer is polymerized; and

a drying step in which the obtained hydrogel is dried, wherein

Fe on the basis of Fe₂O₃ in the monomer is 0.002 to 2 ppm by mass;

a plurality of acrylic acids having different propionic acid amounts of 1.1 to 50 times by mass with respect to the other acrylic acid are mixed to prepare the monomer;

a plurality of acrylic acids obtained by different production processes of at least one selected from plant, installation site, raw material, oxide type, and refining type are mixed to prepare the monomer;

and propionic acid is removed from polyacrylic acid (salt) during polymerization or after polymerization.

2. The method as disclosed in claim 1, wherein 3-hydroxypropionic acid (salt) in the monomer is 2000 ppm or lower.

3. The method as disclosed in claim 1, wherein a flow conductivity SFC to an 0.69 mass % aqueous sodium chloride solution, is 10×

10<sup>−

7</sup>×

cm³×

s×

g<sup>−

1</sup> or higher.

4. The method as disclosed in claim 1, wherein the plurality of acrylic acids are used, and one or some of acrylic acid is/are obtained from a non-fossil raw material and the other(s) is/are obtained from a fossil raw material.

5. The method as disclosed in claim 1, wherein a highest temperature for the polymerization is 100 to 150°

C. and the propionic acid is removed during polymerization.

6. The method as disclosed in claim 1, wherein the propionic acid is evaporated by a hot air drying with a drying temperature of 165 to 230°

C. and to drying time of 15 minutes or more in the drying step of hydrogel.

7. The method as disclosed in claim 1, wherein the drying step is azeotropic dehydration in a hydrophobic organic solvent by which the propionic acid is removed after polymerization.

8. The method as disclosed in claim 1, wherein the mixing ratio of different acrylic acids is 1:

99 to 99;

1.

9. The method as disclosed in claim 1, wherein at least a portion of propionic acid is evaporated in the drying step and thereafter and further trapped with acrylic acid and acetic acid.

10. The method as disclosed in claim 1, wherein one or some of acrylic acid containing 400 ppm or more of propionic acid are used to prepare the monomer.

11. The method as disclosed in claim 1, wherein propionic acid is evaporated so as to keep the residual propionic acid in the water-absorbent resin to 2000 ppm or lower in the polymerization step or in the drying step.

12. The method as disclosed in claim 1, wherein the method further comprises a surface-crosslinking step in which preferably the water absorbent resin is surface-crosslinked by using a surface treatment agent containing propanediol or lactic acid after the polymerization step.

13. The method as disclosed in claim 11, wherein a basic substance is added 1.1 to 1000 times by mass with respect to propionic acid after the drying step.

14. The method as disclosed in claim 1, wherein the acrylic acid contains acetic acid in an amount less than that of propionic acid.