Integrated hydromethanation fuel cell power generation

• US 8,652,696 B2
• Filed: 03/03/2011
• Issued: 02/18/2014
• Est. Priority Date: 03/08/2010
• Status: Active Grant

• Current Assignee: Sure Champion Investments Limited
• Original Assignee: GreatPoint Energy, Inc.
• Inventors: Sirdeshpande, Avinash
• Primary Examiner(s): Cano, Milton I
• Assistant Examiner(s): LYLES-IRVING, CARMEN V
• Application Number:
  US13/039,995
• Publication Number:
  US 20110217602A1
• Time in Patent Office: 1,083 Days
• Field of Search: None
• US Class Current: 429/425
• CPC Class Codes: H01M 2008/1293 Fuel cells with solid oxide electrolytes
• CPC Class Codes: H01M 8/04014 Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
• CPC Class Codes: H01M 8/04089 of gaseous reactants
• CPC Class Codes: H01M 8/0612 from carbon-containing material
• CPC Class Codes: H01M 8/0662 Treatment of gaseous reactants or gaseous residues, e.g. cleaning
• CPC Class Codes: H01M 8/0668 Removal of carbon monoxide or carbon dioxide
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

The present invention relates to processes and apparatuses for generating electrical power from certain non-gaseous carbonaceous feedstocks through the integration of catalytic hydromethanation technology with fuel cell technology.

Claims

1. A process for generating electrical power from a non-gaseous carbonaceous material, the process comprising the steps of:

(a) introducing into a hydromethanation reactor (1) a carbonaceous feedstock derived from the non-gaseous carbonaceous material, (2) a hydromethanation catalyst, and (3) a superheated hydromethanation gas feed stream comprising steam, hydrogen and carbon monoxide;

(b) reacting the carbonaceous feedstock in the hydromethanation reactor in the presence of carbon monoxide, hydrogen, steam and hydromethanation catalyst to produce a methane-enriched raw product;

(c) withdrawing a methane-enriched product stream from the hydromethanation reactor, wherein the methane-enriched raw product stream comprises methane, carbon monoxide, hydrogen, carbon dioxide, hydrogen sulfide, steam and heat energy, and wherein the methane-enriched raw product stream comprises at least 50 tool % methane plus carbon dioxide based on the moles of methane, carbon dioxide, carbon monoxide and hydrogen in the methane-enriched raw product stream;

(d) recovering a portion of the heat energy from the methane-enriched raw product stream;

(e) removing at least a substantial portion of the carbon dioxide and at least a substantial portion of the hydrogen sulfide from the methane-enriched raw product stream to produce an acid gas-depleted raw product stream;

(f) separating the acid gas-depleted raw product stream into a recycle feed stream and a fuel cell feed stream;

(g) introducing into a fuel cell (1) an oxygen-containing gas stream and (2) a fuel mixture, the fuel cell comprising an anode section and a cathode section separated by an electrolyte section, the oxygen-containing gas stream being introduced into the cathode section and the fuel mixture being introduced into the anode section, the fuel mixture comprising at least methane and hydrogen from the fuel cell feed stream;

(h) electrochemically reacting in the fuel cell oxygen from the oxygen-containing gas stream with the fuel mixture to generate electrical power and heat energy;

(i) withdrawing from the fuel cell (1) an oxygen-depleted cathode exhaust stream and (2) an anode exhaust stream, wherein both the oxygen-depleted cathode exhaust stream and the anode exhaust stream comprise heat energy, and wherein the anode exhaust stream further comprises methane, hydrogen, carbon monoxide, carbon dioxide and steam;

(j) recovering a portion of the heat energy from the anode exhaust stream to produce a cooled anode exhaust stream;

(k) removing at least a substantial portion of the carbon dioxide from the cooled anode exhaust stream to generate a carbon dioxide-depleted anode exhaust stream;

(l) generating carbon monoxide and hydrogen from at least a portion of methane in the recycle feed stream to generate a syngas recycle stream;

(m) combusting at least a portion of the carbon dioxide-depleted anode exhaust stream to generate heat energy; and

(n) superheating the syngas recycle stream with at least a portion of the heat energy from step (m) to generate the superheated hydromethanation gas feed stream.

2. The process of claim 1, wherein the methane-enriched raw product stream comprises at least about 20 mol % methane based on the moles of methane, carbon dioxide, carbon monoxide and hydrogen in the methane-enriched raw product stream.

3. The process of claim 1, wherein the carbonaceous feedstock is loaded with hydromethanation catalyst prior to being supplied to the hydromethanation reactor.

4. The process of claim 1, wherein the hydromethanation catalyst comprises an alkali metal.

5. The process of claim 1, wherein a char by-product is generated in step (b), and is continuously or periodically withdrawn from the hydromethanation reactor.

6. The process of claim 5, wherein the hydromethanation catalyst comprises an alkali metal, the char by-product comprises an alkali metal content from the hydromethanation catalyst, at least a portion of the char by-product is treated to recover at least a portion of the alkali metal content, and at least a portion of the recovered alkali metal content is recycled for use as hydromethanation catalyst.

7. The process of claim 6, wherein the carbonaceous feedstock is impregnated with hydromethanation catalyst prior to being supplied to the hydromethanation reactor, and the hydromethanation catalyst used to impregnate the carbonaceous feedstock comprises recycled hydromethanation catalyst and a make-up hydromethanation catalyst.

8. The process of claim 1, wherein an oxygen-rich gas stream is fed into the hydromethanation reactor, and the amount of oxygen provided is varied as a process control to assist control of the temperature in the hydromethanation reactor.

9. The process of claim 1, which is a continuous process in which steps (a), (b), (c), (d), (e), (f), (g), (h), (i), (j), (k), (l), (m) and (n) are operated in a continuous manner.

10. The process of claim 1, wherein step (l) comprises the step of passing at least a portion of the recycle feed stream through a syngas generator to generate hydrogen, carbon monoxide and heat energy from methane in the recycle feed stream.

11. The process of claim 10, wherein the syngas generator utilizes non-catalytic partial oxidation process or an autothermal reforming process, and wherein an oxygen-rich gas stream is fed into the syngas generator along with the recycle feed stream.

12. The process of claim 1, wherein step (b) has a syngas demand, a steam demand and a heat demand, and the superheated hydromethanation gas feed stream comprises hydrogen, carbon monoxide, steam and heat energy sufficient to at least substantially satisfy the syngas demand, steam demand and heat demand.

13. The process of claim 1, wherein step (e) occurs in a first acid gas removal unit, step (k) occurs in a second acid gas removal unit, and the first acid gas removal unit and the second acid gas removal unit utilize a common absorber.

14. The process of claim 1, wherein at least a portion of the heat energy is recovered from the oxygen-depleted cathode exhaust stream, and at least a portion of the heat energy recovered from the oxygen-depleted cathode exhaust stream is used to preheat the oxygen-containing gas stream.

15. The process of claim 1, wherein at least a portion of the heat energy recovered from the anode exhaust stream is used to preheat the fuel mixture.