Fuel cell system

• US 8,658,322 B2
• Filed: 02/22/2006
• Issued: 02/25/2014
• Est. Priority Date: 03/09/2005
• Status: Active Grant

• Current Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Original Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Inventors: Kitamura, Nobuyuki
• Primary Examiner(s): Gilliam, Barbara
• Assistant Examiner(s): CARRICO, ROBERT SCOTT
• Application Number:
  US11/884,555
• Publication Number:
  US 20080166609A1
• Time in Patent Office: 2,925 Days
• Field of Search: 429408-409, 429413-414, 429428-436, 429512-513, 429/535
• US Class Current: 429/413
• CPC Class Codes: H01M 8/04291 Arrangements for managing water in solid electrolyte fuel cell systems H01M8/04119 takes precedence
• CPC Class Codes: H01M 8/04529 of the electrolyte
• CPC Class Codes: H01M 8/04559 of fuel cell stacks
• CPC Class Codes: H01M 8/04589 of fuel cell stacks
• CPC Class Codes: H01M 8/04649 of fuel cell stacks
• CPC Class Codes: H01M 8/04731 of other components of a fuel cell or fuel cell stacks
• CPC Class Codes: H01M 8/04753 of fuel cell reactants
• CPC Class Codes: H01M 8/0485 of the electrolyte
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

In a fuel cell system including a stack of polymer electrolyte fuel cells, the wet state of electrolyte membranes in the fuel cell stack is detected according to a variation in measurement value of an alternating current impedance (AC impedance) of the fuel cell stack. In an adequate level of water content of the electrolyte membranes, the measurement value of the AC impedance is substantially constant and has a very little variation. In an excess level of water content of the electrolyte membranes, the measurement value of the AC impedance has a significant variation. The AC impedance of the fuel cell stack is determinable by frequency analysis of high-frequency noise generated by an inverter included in the fuel cell system.

Claims

1. A fuel cell system, comprising:

a fuel cell that has a solid polymer electrolyte membrane;

a measurement module configured to measure values of an alternating current impedance of the fuel cell in time series while the fuel cell system is in operation;

a computation module configured to compute a variance from the measured values of the alternating current impedance; and

a detection module configured to detect a wet state of the electrolyte membrane, based on the variance.

2. The fuel cell system in accordance with claim 1, wherein the detection module detects an excess water content of the electrolyte membrane when the computed variance is not less than a predetermined level.

3. The fuel cell system in accordance with claim 1, wherein the detection module is configured to detect the wet state of the electrolyte membrane, based on the time series of the measured alternating current impedance as well as the computed variance, and

the detection module is configured to detect an insufficient water content of the electrolyte membrane when the computed variance is less than a predetermined level and the measured alternating current impedance increases.

4. The fuel cell system in accordance with claim 1, the fuel cell system further having:

a water content regulation module configured to regulate a water content of the electrolyte membrane according to a result of the detection.

5. The fuel cell system in accordance with claim 4, wherein the water content regulation module reduces the water content of the electrolyte membrane during operation stop of the fuel cell system to decrease the variance below the predetermined level and increase the measured alternating current impedance to a specific range that is higher than a level of the alternating current impedance in an ordinary operation state.

6. The fuel cell system in accordance with claim 1, the fuel cell system further having:

an output controller configured to control an output of the fuel cell,

wherein the measurement module performs frequency analysis of high-frequency noise generated by the output controller to determine the alternating current impedance.

7. A detection method applied to a fuel cell having a solid polymer electrolyte membrane to detect a wet state of the electrolyte membrane, the detection method comprising:

(a) measuring values of an alternating current impedance of the fuel cell in time series while the fuel cell is in operation;

(b) computing a variance from the measured values of the alternating current impedance; and

(c) detecting the wet state of the electrolyte membrane, based on the variance.

8. A control method of a fuel cell system that includes a fuel cell having a solid polymer electrolyte membrane, the control method comprising:

(a) measuring values of an alternating current impedance of the fuel cell in time series while the fuel cell system is in operation;

(b) computing a variance from the measured values of the alternating current impedance;

(c) detecting a wet state of the electrolyte membrane, based on the variance; and

(d) regulating a water content of the electrolyte membrane according to a result of the detection.

9. The control method of the fuel cell system in accordance with claim 8, wherein the fuel cell system further includes an output controller configured to control an output of the fuel cell, and

the measuring step (a) performs frequency analysis of high-frequency noise generated by the output controller to determine the alternating current impedance.