Surface treated bioerodible metal endoprostheses
First Claim
1. An endoprosthesis comprising an expandable tubular body defined by a plurality of struts, the expandable tubular body comprising a bioerodible metal having at least a first surface region and a second surface region, the first and second surface regions having different surface oxide compositions, wherein the second surface region comprises a sulfide of the bioerodible metal.
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Accused Products
Abstract
An endoprosthesis includes an expandable tubular body defined by a plurality of struts. In some embodiments, the expandable tubular body includes a bioerodible metal that has at least a first surface region and a second surface region. The first and second surface regions can have different surface oxide compositions. In some embodiments, the first portion has a thermally altered microstructure and the second portion has a wrought microstructure. The thermally altered microstructure can be a cast microstructure comprising dendritic grains. The first portion forms at least a portion of an outer surface of the expandable tubular body. In some embodiments, the expandable tubular body includes iron or a bioerodible iron alloy and at least one surface of the expandable tubular body includes a substantially uniform coating of iron(III) oxide.
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Citations
24 Claims
- 1. An endoprosthesis comprising an expandable tubular body defined by a plurality of struts, the expandable tubular body comprising a bioerodible metal having at least a first surface region and a second surface region, the first and second surface regions having different surface oxide compositions, wherein the second surface region comprises a sulfide of the bioerodible metal.
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9. An endoprosthesis comprising an expandable tubular body defined by a plurality of struts, the expandable tubular body comprising a bioerodible metal having at least a first surface region and a second surface region, the first and second surface regions having different surface oxide compositions, wherein the bioerodible metal is iron or an alloy thereof, wherein the second surface region comprises ferric oxide (iron(III) oxide), wherein the first surface region comprises hematite.
- 13. An endoprosthesis comprising an expandable tubular body defined by a plurality of struts, the expandable tubular body comprising a bioerodible metal having at least a first portion and a second portion, the first portion having a thermally altered microstructure, the second portion having a wrought microstructure, the first portion forming at least a portion of an outer surface of the expandable tubular body, wherein the tubular body comprises a continuous body of the second portion with a plurality of first portions each having a cast microstructure comprising dendritic grains, wherein each first portion defines at least a portion of the outer surface of the expandable tubular member.
- 21. An endoprosthesis comprising an expandable tubular body defined by a plurality of struts, the struts comprising one or more surfaces, the expandable tubular body comprising iron or a bioerodible iron alloy, at least one surface of the expandable tubular body comprising a substantially uniform coating of iron(III) oxide, wherein the coating of ferric oxide encapsulates the expandable tubular body.
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23. An endoprosthesis comprising an expandable tubular body defined by a plurality of struts, the expandable tubular body comprising iron or a bioerodible iron alloy, at least one surface of the expandable tubular body comprising a substantially uniform coating of iron(III) oxide, wherein the expandable tubular body comprises an alloy consisting essentially of iron and about 2.3 weight percent manganese.
Specification