Heat treatable four layer anti-reflection coating

• US 8,668,990 B2
• Filed: 01/27/2011
• Issued: 03/11/2014
• Est. Priority Date: 01/27/2011
• Status: Expired due to Fees

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Guardian Industries Corporation (KOCH Industries Incorporated)
• Inventors: Broadway, David M., Krasnov, Alexey, Den Boer, Willem
• Primary Examiner(s): SAMPLE, DAVID R
• Application Number:
  US12/929,481
• Publication Number:
  US 20120196133A1
• Time in Patent Office: 1,139 Days
• Field of Search: None
• US Class Current: 428/426
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 17/3423 at least one of the coatings comprising a suboxide
• CPC Class Codes: C03C 17/3435 comprising a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 2217/73 Anti-reflective coatings with specific characteristics
• CPC Class Codes: C09D 5/006 Anti-reflective coatings
• CPC Class Codes: G02B 1/115 Multilayers

Abstract

A coated article includes a heat treatable (e.g., temperable) antireflection (AR) coating having four layers. The AR coating includes a layer adjacent the glass substrate having an index of refraction substantially matching that of the glass substrate, and having a compressive residual stress. In certain example embodiments, the coating may include the following layers from the glass substrate outwardly: stress-reducing layer/medium index layer/high index layer/low index layer. In certain example embodiments, depending on the chemical and optical properties of the high index layer and the substrate, the stress-reducing layer of the AR coating is selected to cause a net compressive residual stress and thus improve the overall performance of the antireflection coating when the coated article is heat treated.

Claims

1. A heat treated coated article comprising:

a substrate; and

a first antireflection coating supported by a first major surface of the substrate, the substrate being heat treated together with the first antireflection coating disposed thereon,

wherein the first antireflection coating comprises, in order moving away from the substrate;

a stress-reducing layer comprising a material having a compressive residual stress after heat treatment,

a medium index layer comprising silicon oxynitride,

a high index layer comprising an oxide of niobium, and

a low index layer comprising an oxide of silicon,

wherein the first antireflection coating has a net compressive residual stress after heat treatment.

2. The coated article of claim 1, wherein

the stress reducing layer comprises an oxide of silicon.

3. The coated article of claim 1, wherein

a refractive index of the stress-reducing layer differs from a refractive index of the glass substrate by no more than about 0.2.

4. The coated article of claim 1, further comprising

a second antireflective coating provided on a second major surface of the substrate, the second antireflective coating comprising the same layers as the first antireflective coating.

5. A heat treated coated article, comprising:

a glass substrate; and

an antireflection coating supported by a major surface of the substrate, the substrate being heat treated together with the antireflection coating,

wherein the antireflection coating comprises, in order moving away from the substrate;

a stress-reducing layer comprising an oxide and/or nitride of silicon,

a medium index layer comprising silicon oxynitride,

a high index layer comprising an oxide of niobium and/or an oxide of titanium, and

a low index layer comprising an oxide of silicon,

wherein the antireflection coating has a net compressive residual stress after heat treatment.

6. The coated article of claim 5, wherein

the net compressive residual stress measured after heat treatment differs from the value of σ

_Net by no more than about 15%, where σ

_Net is determined according to the equation;