Enhanced carbon nanotube

• US 8,673,258 B2
• Filed: 08/14/2008
• Issued: 03/18/2014
• Est. Priority Date: 08/14/2008
• Status: Active Grant

• Current Assignee: Seoul National University R&DB Foundation (Seoul National University)
• Original Assignee: Seoul National University R&DB Foundation (Seoul National University)
• Inventors: Kim, Yong Hyup, Jang, Eui Yun
• Primary Examiner(s): LEE, REBECCA Y
• Application Number:
  US12/192,024
• Publication Number:
  US 20100040529A1
• Time in Patent Office: 2,042 Days
• Field of Search: 205/78, 423/447.2
• US Class Current: 423/447.2
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: C01B 32/174 Derivatisation; Solubilisation; Dispersion in solvents
• CPC Class Codes: Y10T 428/2918 including free carbon or carbide or therewith [not as steel]

Abstract

Techniques for manufacturing an enhanced carbon nanotube (CNT) assembly are provided. In one embodiment, a method of manufacturing an enhanced CNT assembly comprises preparing a metal tip, preparing a CNT plus transition-metal colloidal solution, forming a CNT plus transition-metal composite assembly by using the prepared metal tip and CNT plus transition-metal colloidal solution, and growing the CNT plus transition-metal composite assembly.

Claims

1. A method of manufacturing an enhanced carbon nanotube (CNT) assembly, comprising:

forming a CNT composite assembly comprising CNTs and particles of a transition metal, wherein forming the CNT composite assembly comprises;

providing a solution of CNTs plus transition-metal colloidal solution and dipping a metal tip into the solution;

adhering carbon nanotubes to the metal tip; and

withdrawing the metal tip from the CNT plus transition-metal colloidal solution so that the CNT composite assembly extends from the metal tip to CNT plus transition-metal colloidal solution, wherein the CNT composite assembly is formed without applying a voltage between the metal tip and the CNT colloidal solution; and

growing the CNT composite assembly, wherein growing the CNT composite assembly comprises a process selected from the group consisting of chemical vapor deposition, laser ablation and arc discharge,

wherein the growth of the CNT composite assembly is facilitated by the particles of the transition metal.

2. The method of claim 1, further comprising:

maintaining the metal tip immersed in the CNT plus transition-metal colloidal solution for a predetermined time.

3. The method of claim 1, wherein withdrawing the metal tip from the CNT plus transition-metal colloidal solution comprises withdrawing the metal tip from the CNT plus transition-metal colloidal solution at a predetermined withdrawal velocity.

4. The method of claim 1, wherein the enhanced CNT assembly has a form selected from the group consisting of a rope, a ribbon, a film, a fiber and a strand.

5. The method of claim 1, wherein growing the CNT composite assembly comprises growing the CNT composite assembly using a chemical vapor deposition method.

6. The method of claim 1, wherein the metal tip comprises a metal select from the group consisting of tungsten, a tungsten alloy, platinum, and a platinum alloy.

7. The method of claim 1, wherein the metal tip has an apex with a conical shape.

8. The method of claim 1, wherein the metal tip is obtained by electrochemical etching.

9. The method of claim 1, wherein the transition metal is selected from the group consisting of Ni, Co, and Fe.

10. The method of claim 3, where the predetermined withdrawal velocity is about 3 mm/min.

11. The method of claim 1, wherein the particles of the transition metal are evenly distributed on the CNTs in the CNT composite assembly.

12. The method of claim 1, wherein the CNT composite assembly has a diameter of about 10 μ

m after withdrawing the metal tip.

13. The method of claim 1, wherein growing the CNT composite assembly comprises laser ablation.

14. The method of claim 1, wherein growing the CNT composite assembly comprises arc discharge.

15. The method of claim 1, wherein growing the CNT composite assembly comprises:

disposing the CNT composite assembly in a reaction vessel after withdrawing the metal tip; and

exposing the CNT composite assembly in the reaction vessel to a carbon-containing gas to yield new carbon nanotubes on the CNT composite assembly, wherein the particles of transition metal in the CNT composite assembly catalyze growth of the new carbon nanotubes from the carbon-containing gas.

16. A method of forming a CNT assembly consisting of:

providing a solution of CNTs plus transition-metal colloidal solution and dipping a metal tip into the solution;

adhering carbon nanotubes to the metal tip; and

withdrawing the metal tip from the CNT plus transition-metal colloidal solution so that the CNT composite assembly extends from the metal tip to CNT plus transition-metal colloidal solution.

17. A method of manufacturing an enhanced carbon nanotube (CNT) assembly, comprising:

forming a CNT composite assembly comprising CNTs and particles of a transition metal, wherein forming the CNT composite assembly consists of;

providing a solution of CNTs plus transition-metal colloidal solution and dipping a metal tip into the solution;

adhering carbon nanotubes to the metal tip; and

withdrawing the metal tip from the CNT plus transition-metal colloidal solution so that the CNT composite assembly extends from the metal tip to CNT plus transition-metal colloidal solution; and

growing the CNT composite assembly, wherein growing the CNT composite assembly comprises a process selected from the group consisting of chemical vapor deposition, laser ablation and arc discharge,

wherein the growth of the CNT composite assembly is facilitated by the particles of the transition metal.