Articles containing precisely branched functional polymeric phase change materials
First Claim
Patent Images
1. A temperature regulating article comprising:
- a substrate; and
a polymeric phase change material bound to the substrate, wherein the polymeric phase change material is characterized by including a precisely branched polymer with substantially equally spaced repeating sidechains each separated by carbon segments of the backbone having at least three carbon atoms, wherein the length of the carbon segments of the backbone controls a degree of crystallization of the polymeric phase change material at a given transition temperature, wherein the polymeric phase change material includes between 20 and 200 branches per 1000 carbon atoms,wherein the polymeric phase change material has a latent heat of at least 5 Joules per gram and a transition temperature between 0°
C. and 40°
C. dependent upon the length of the carbon segments of the backbone, andwherein the sidechains are selected from the group consisting of CH3, C2H5, CnH2n+1, OCH3, and OC2H5.
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Abstract
In accordance with one aspect a temperature regulating article comprises a substrate and a polymeric phase change material bound to the substrate, wherein the polymeric phase change material is characterized by including a precisely branched polymer with substantially equally spaced repeating sidechains. In other embodiments the polymeric phase change material includes between 20 and 200 branches per 1000 carbon units, has a latent heat of at least 5 Joules per gram, and a transition temperature between 0° C. and 40° C.
155 Citations
22 Claims
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1. A temperature regulating article comprising:
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a substrate; and a polymeric phase change material bound to the substrate, wherein the polymeric phase change material is characterized by including a precisely branched polymer with substantially equally spaced repeating sidechains each separated by carbon segments of the backbone having at least three carbon atoms, wherein the length of the carbon segments of the backbone controls a degree of crystallization of the polymeric phase change material at a given transition temperature, wherein the polymeric phase change material includes between 20 and 200 branches per 1000 carbon atoms, wherein the polymeric phase change material has a latent heat of at least 5 Joules per gram and a transition temperature between 0°
C. and 40°
C. dependent upon the length of the carbon segments of the backbone, andwherein the sidechains are selected from the group consisting of CH3, C2H5, CnH2n+1, OCH3, and OC2H5. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17)
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18. A temperature regulating composition, comprising:
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a polymeric phase change material, wherein the polymeric phase change material is characterized by including a precisely branched polymer with substantially equally spaced repeating sidechains each separated by at least three carbon backbone atoms, wherein the number of carbon backbone atoms between sidechains controls a degree of crystallization of the polymeric phase change material at a given transition temperature, wherein the polymeric phase change material includes between 20 and 200 branches per 1000 carbon atoms, wherein the polymeric phase change material has a latent heat of at least 5 Joules per gram and a transition temperature between 0°
C. and 40°
C. dependent upon number of carbon backbone atoms between sidechains, andwherein the sidechains are selected from the group consisting of CH3, C2H5, CnH2n+1, OCH3, and OC2H5. - View Dependent Claims (19, 20, 21, 22)
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Specification