Stimuli-responsive product

• US 8,683,798 B2
• Filed: 01/13/2011
• Issued: 04/01/2014
• Est. Priority Date: 01/15/2010
• Status: Active Grant

• Current Assignee: Syracuse University
• Original Assignee: Syracuse University
• Inventors: Mather, Patrick, Luo, Xiaofan
• Primary Examiner(s): Denion, Thomas
• Assistant Examiner(s): KEBEA, JESSICA L
• Application Number:
  US13/006,024
• Publication Number:
  US 20110173971A1
• Time in Patent Office: 1,174 Days
• Field of Search: 605/28
• US Class Current: 60/528
• CPC Class Codes: B29C 70/882 partly or totally electrically conductive, e.g. for EMI shielding conductive floors or floor coverings H05F3/025; EMI shielding in general H05K9/00
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites

Abstract

Embodiments of a product such as a stimuli-responsive product can comprise a shape memory component and a nanofiber component that forms a fibrous microstructure or network. The resulting product can be responsive to stimuli, such as electrical stimuli, in a manner that cause the product to deform, deflect, and rebound. In one embodiment, the product can comprise an epoxy and a continuous non-woven nanofiber, the combination of which provides a product with enhanced actuation speed.

Claims

1. A product responsive to a stimuli, said product comprising:

a first component comprising a shape-memory material; and

a second component comprising a non-woven mat of carbonized polymer nanofibers forming a fiber network disposed in the shape memory material.

2. A product according to claim 1, wherein the shape-memory material comprises epoxy.

3. A product according to claim 1, wherein the nanofibers are electrically conductive.

4. A product according to claim 1, wherein the carbonized polymer comprises carbonized poly(acrylonitrile).

5. A product according to claim 1, wherein the first component and the second component form a composition in which the first component is at least about 90 vol. % of the total volume of the composition.

6. A product according to claim 1, wherein the first component comprises one or more of acrylic and methacrylic cross-linked networks, styrene-acrylic copolymer networks, styrene, methacrylic networks, polycaprolactone networks, poly(glycolide-co-lactide) (PLGA) copolymer network, and combinations thereof.

7. A product according to claim 1, wherein the nanofibers have an average diameter that is less that about 500 rim.

8. A product according to claim 1, wherein the nanofibers comprise a polymer selected from the group consisting of poly(alkyl thiophene), poly(acetylene), poly(pyrrole), and combinations thereof.

9. A product according to claim 1, wherein said product changes from a first shape to a second shape in response to application of the stimuli and changes from the second shape to the first shape in response to removal of the stimuli.

10. A product according to claim 1, wherein the nanofibers are configured to generate heat.

11. A product according to claim 10, further comprising a first electrode and a second electrode, wherein each of the first electrode and the second electrode are in electrical communication with the fiber network so as to conduct an electrical signal stimuli between the first electrode and the second electrode via the network.

12. A product according to claim 11, wherein in response to the electrical stimuli the nanofibers are configured to increase the temperature of said product in excess of a transition temperature of the shape-memory material.

13. A product according to claim 12, wherein the fiber network is configured to raise the temperature of said product past the glass transition temperature in less than 10 s.

14. A product according to claim 1, wherein the resistivity of the fiber network does not exceed about 10 Ohm-cm.

15. A product according to claim 1, wherein the conductivity of the fiber network is at least about 0.1 S/cm.

16. A shape-memory product, comprising:

a matrix comprising a shape memory material;

a filler combined with the matrix, the filler comprising a non-woven mat of carbonized polymer nanofibers; and

a pair of electrodes in electrical communication with the fiber network, wherein the nanofibers are configured to conduct an electrical signal between the electrodes via the fiber network.

17. A shape-memory product according to claim 16 wherein the nanofibers comprise carbonized poly(acrylonitrile).

18. A shape-memory product according to claim 16, wherein the shape-memory material comprises epoxy.

19. A method, comprising:

forming a filler component comprising a non-woven mat of carbonized polymer nanofibers;

infiltrating the filler component with a matrix component comprising a shape memory polymer; and

curing the matrix component.

20. A method according to claim 19, wherein the nanofibers comprise carbonized poly(acrylonitrile).