Gas sensor

• US 8,691,066 B2
• Filed: 08/12/2004
• Issued: 04/08/2014
• Est. Priority Date: 08/13/2003
• Status: Active Grant

• Current Assignee: City Technology Ltd. (Honeywell International Inc.)
• Original Assignee: City Technology Ltd. (Honeywell International Inc.)
• Inventors: Collins, Graham
• Primary Examiner(s): DINH, BACH T
• Application Number:
  US10/566,867
• Publication Number:
  US 20070181423A1
• Time in Patent Office: 3,526 Days
• Field of Search: 204421-432, 439271-274, 439587-588
• US Class Current: 204/432
• CPC Class Codes: G01N 27/404 Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid , e.g. Clark-type oxygen sensors
• CPC Class Codes: G01N 33/0011 Sample conditioning in general G01N1/28

Abstract

A current collector wire (1) is over-moulded with a seal (2) made from a thermoplastic elastomer (Santoprene 64) having a (64) Shore A hardness rating. In a three electrode carbon monoxide sensor three current collector wire (1a, 1b, 1c) and seal (2a, 2b, 2c) combinations are inserted into the body (3) through receiving apertures (12a, 12b, 12c) in a side wall of the body, so that the current collectors protrude through connection apertures (12a, 12b and 12c). The outside diameters of the seals and the bores of the apertures are dimensioned to provide an interference fit of the one in the other. The seals are pressed home into receiving apertures in the body (3) to provide compression of the seals against both current collectors and the aperture bores resultant from the interference. Gold-plated phosphor bronze clips (8) are attached which locate on and are retained by barbs on the housing, thereby trapping the current collector wires and providing electrical contact to external circuitry.

Claims

1. A current collector and a seal combination for an electrochemical sensor comprising:

a housing, a relatively flat reference, sensing, and counter electrodes within the housing, the relatively flat reference, sensing and counter electrodes are stacked vertically and centered about a common vertical axis and in contact with a liquid electrolyte;

a plurality of connection apertures arranged in a horizontal row extending along a wall of the housing directly adjacent corresponding edges of the reference, sensing and counter electrodes,

the current collector and seal combination further comprising;

a plurality of relatively straight, flexible, metal current collectors, each of the plurality of current collectors extending through a respective connection aperture of the plurality of connection apertures to the vertically stacked reference, sensing and counter electrodes with an end of each current collector trapped against and in direct contact with the reference, sensing and counter electrodes;

a compliant seal of a thermoplastic elastomeric material over-molded directly onto each of the flexible metal current collectors, the compliant seal is inserted into one of the connection apertures, the current collector extending through the compliant seal;

the compliant seal being in contact with the current collector substantially throughout its length along the current collector; and

an arrangement being such that compressive stress induced in the compliant seal by reaction from the connection aperture urges the compliant seal into distributed sealing contact with the current collector substantially through a length of the compliant seal.

2. The current collector and seal combination of claim 1, wherein the length of the compliant seal is longer than its outer diameter or other major cross-sectional dimension.

3. The current collector and seal combination of claim 2, wherein a ratio of the length of the compliant seal to the outer diameter is of an order of at least 3:

1.

4. The current collector and seal combination of claim 1, claim 2 or claim 3, wherein a ratio of the length and/or the outer diameter of the compliant seal to a diameter of the current collector is at least of an order of 10:

1.

5. The current collector and seal combination of claim 1, claim 2, or claim 3, wherein a ratio of the length of the compliant seal to a diameter of the current collector is at least of an order of 30:

1.

6. The current collector and seal combination of claim 1, wherein the compliant seal is injection moulded as an over-moulding onto the current collector.

7. The current collector and seal combination of claim 1, wherein the compliant seal is molded with a central through-bore for threading of the current collector through the compliant seal.

8. The current collector and the seal combination of claim 1, wherein the compliant seal is molded with a slot, nick or notch, for introduction of the current collector into the compliant seal.

9. The current collector and seal combination of claim 1, wherein the compliant seal is moulded as two complementary halves having a central groove for receiving the current collector.

10. The current collector and seal combination of claim 1, wherein the compliant seal has one or more ridges extending around its outer circumference.

11. The current collector and seal combination of claim 1, wherein the compliant seal has a cylindrical body and a larger diameter outer end boss.

12. The current collector and seal combination of claim 1, wherein the compliant seal has a tapered nose.

13. An electrochemical gas sensor having:

a housing having at least one wall and a plurality of connection apertures arranged in a horizontal row extending along and through the wall, the connection apertures having bores directly adjacent corresponding edges of a relatively flat reference, sensing and counter electrodes,

the relatively flat reference, sensing and counter electrodes are stacked vertically and centered about a common vertical axis in the housing,

a liquid electrolyte contained in the housing in chemical contact with the electrodes, and

a plurality of current collectors in electrical contact with respective ones of the respective electrodes;

the plurality of current collectors and respective electrodes are characterized in that;

the plurality of current collectors in combination with a corresponding plurality of compliant seals are arranged in accordance with the current collector and seal combination of claim 1;

wherein the current collectors extend within the compliant seals through respective ones of the connection apertures from the electrodes to outside the housing; and

the compliant seals are in compression against both the current collectors and at least part of the bores of the connection apertures,

wherein the current collectors provide means for electrical contact outside the housing and the connection apertures are sealed.

14. The electrochemical sensor of claim 13, wherein the compliant seal is an interference fit in the aperture.

15. The electrochemical sensor of claim 13, wherein the compliant seals have cylindrical bodies and larger diameter outer end bosses and the connection apertures have a complementary shape.

16. The electrochemical sensor of claim 13 including metallic end caps clipped to the housing and captivate the current collectors, thereby providing electrical connections for the electrochemical sensor.

17. An electrochemical gas sensor having:

a housing having at least one wall and a plurality of connection apertures arranged in a horizontal row extending along and through the wall, the connection apertures having bores directly adjacent corresponding edges of a relatively flat reference, sensing and counter electrodes,

a relatively flat reference, sensing and counter electrodes are stacked vertically and centered about a common axis in the housing,

a liquid electrolyte contained in the housing in chemical contact with the electrodes, and

a plurality of current collectors in electrical contact with respective ones of the respective electrodes;

the plurality of current collectors and respective electrodes are characterized in that;

the plurality of current collectors in combination with a corresponding plurality of compliant seals are arranged in accordance with the current collector and seal combination of claim 1,

wherein the current collectors extending through respective ones of the connection apertures from the electrodes to outside the housing;

the compliant seals are in compression against both the current collectors and at least part of the bores of the connection apertures;

whereby the current collectors provide means for electrical contact outside the housing and the connection apertures are sealed;

the current collectors are preliminarily located in the connection apertures;

the compliant seals are back-fillings of sealing material into the connection apertures; and

the back-fillings are compressed by end caps.

18. The electrochemical sensor of claim 17, wherein the end caps are metallic, clipped to the housing, and captivate the current collectors, thereby providing electrical connections for the electrochemical sensor.

19. The electrochemical sensor of claim 13, or claim 17, wherein an elastic moduli of the housing and of the compliant seal differ by at least two orders of magnitude, the housing being stiffer and the compliant seal being more compliant.