Methods for treating hydrocarbon formations

• US 8,701,768 B2
• Filed: 04/08/2011
• Issued: 04/22/2014
• Est. Priority Date: 04/09/2010
• Status: Expired due to Fees

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Marino, Marian, Beer, Gary Lee, Pollard, Richard, Roes, Augustinus Wilhelmus Maria
• Primary Examiner(s): HUTCHINS, CATHLEEN R
• Application Number:
  US13/083,272
• Publication Number:
  US 20110247820A1
• Time in Patent Office: 1,110 Days
• Field of Search: 166/252.1, 166/302, 166/305.1, 166/60
• US Class Current: 166/302
• CPC Class Codes: E21B 43/24 using heat, e.g. steam injection

Abstract

Systems and methods for treating a subsurface formation are described herein. Some method include providing heat to a section of the formation from a plurality of heaters located in the formation, allowing the heat to transfer from the heaters to heat a portion of the section to a selected temperature to generate an in situ deasphalting fluid in the section, contacting at least a portion of the in situ deasphalting fluid with hydrocarbons in the section to remove at least some asphaltenes from the hydrocarbons in the section, and producing at least a portion of the deasphalted hydrocarbons from the formation. The in situ deasphalting fluid may include hydrocarbons having a boiling range distribution between 35° C. and 260° C. at 0.101 MPa. A majority of the hydrocarbons in the section may have a boiling point greater than 260° C. at 0.101 MPa.

Claims

1. A method of treating a hydrocarbon formation, comprising:

providing heat to a section of the formation from a plurality of heaters located in the formation;

allowing the heat to transfer from the heaters to heat a portion of the section to a selected temperature to generate an in situ deasphalting fluid in the section, wherein the in situ deasphalting fluid comprises hydrocarbons having a boiling range distribution between 35°

C. and 260°

C. at 0.101 MPa;

contacting at least a portion of the in situ deasphalting fluid with hydrocarbons in the section to remove at least some asphaltenes from the hydrocarbons in the section, wherein a majority of the hydrocarbons in the section have a boiling point greater than 260°

C. at 0.101 MPa, wherein sufficient in situ deasphalting fluid is generated such that at least a 5;

1 volume ratio of in situ deasphalting fluid to heavy hydrocarbons in the section is maintained; and

producing at least a portion of the deasphalted hydrocarbons from the formation.

2. The method of claim 1, wherein the in situ deasphalting fluid is generated by pyrolyzing at least a portion of heavy hydrocarbons in the section.

3. The method of claim 1, further comprising controlling a pressure of the section such that the in situ deasphalting fluid is present as a liquid in the section.

4. The method of claim 1, wherein a P-value of the deasphalted hydrocarbons is at least 1.

5. The method of claim 1, wherein providing heat to a section of the formation comprises:

providing heat to a first section of the formation with one or more heaters in the first section;

heating first hydrocarbons in the first section such that at least some of the first hydrocarbons are mobilized;

providing heat to a second section with one or more second heaters in the second section to further heat the second section after heating the first section for a period of time.

6. A method of treating a hydrocarbon formation, comprising:

providing heat to a first section of the formation from a plurality of heaters located in the formation;

allowing the heat to transfer from the heaters to heat a portion of the first section to a selected temperature to generate an in situ deasphalting fluid in the first section, wherein the in situ deasphalting fluid comprises hydrocarbons having a boiling range distribution between 35°

C. and 260°

C. at 0.101 MPa;

changing a volume ratio of naphtha/kerosene to heavy hydrocarbons in a second section by contacting at least a portion of the generated in situ deasphalting fluid with heavy hydrocarbons in the second section; and

producing at least a portion of the deasphalted hydrocarbons from the formation.

7. The method of claim 6, wherein the producing at least a portion of the deasphalted hydrocarbons comprises producing the deasphalted hydrocarbons from the second section.

8. The method of claim 6, wherein the first section of the formation is above the second section of the formation.

9. The method of claim 6, wherein the first section is substantially above the second section.

10. The method of claim 6, further comprising providing heat to the second section of the formation from a plurality of heaters located in the formation after the first section has been heated for a period of time.

11. The method of claim 6, wherein the produced deasphalted hydrocarbons comprise heavy hydrocarbons, wherein a H/C ratio of the heavy hydrocarbons is higher than a H/C ratio of heavy hydrocarbons produced from the formation prior to changing the volume ratio of naphtha/kerosene to heavy hydrocarbons in the second section.

12. The method of claim 6, further comprising producing from the first section hydrocarbons having a boiling range distribution below 35°

C.

13. The method of claim 6, wherein the produced deasphalted hydrocarbons comprise asphaltenes having a high H/C ratio.

14. A method of treating a hydrocarbon formation, comprising:

providing heat to a first section of a hydrocarbon layer in the formation from a plurality of heaters located in the first section of the formation;

allowing the heat to transfer from the heaters to the first section of the formation;

generating an in situ deasphalting fluid comprising hydrocarbons having a boiling range distribution between 35°

C. and 260°

C. at 0.101 MPa in the first section by heating hydrocarbons in the first section, wherein a majority of the hydrocarbons in the first section having a boiling point greater than 260°

C.;

mobilizing at least a portion of the in situ deasphalting fluid through an upper portion of the first section to an upper portion of a second section of the formation;

contacting the in situ deasphalting fluid with hydrocarbons in the upper portion of the second section to remove at least a portion of the asphaltenes from the hydrocarbon in the upper portion of the second section, wherein a temperature of upper portion of the second section is less than the temperature of the upper portion of the first section;

producing at least a portion of the deasphalted hydrocarbons from the formation.

15. The method of claim 14, wherein allowing heat to transfer raises the average temperature in a portion of the first section to a pyrolysis temperature.

16. The method of claim 14, wherein allowing heat to transfer heats the first section to an average temperature of about 230°

C.

17. The method of claim 14, wherein allowing heat to transfer raises the average temperature in a portion of the first section to a pyrolysis temperature and wherein generating the in situ deasphalting fluid comprises pyrolyzing at least a portion of heavy hydrocarbons in the first section to form the in situ deasphalting fluid.

18. The method of claim 14, further comprising controlling temperature and pressure in the first section to mobilize at least a portion of the in situ deasphalting fluid from a lower portion of the first section to the upper portion of the first section.

19. The method of claim 14, wherein a pressure in the second section of the formation is controlled such that substantially all of the in situ deasphalting fluid is present as a liquid.

20. The method of claim 14, wherein the majority of the asphaltenes removed from the hydrocarbons remain in the second section.

21. The method of claim 14, wherein the deasphalted hydrocarbons are produced from the second section of the formation.

22. The method of claim 14, wherein the deasphalted hydrocarbons are produced from a third section of the formation.

23. The method of claim 14, wherein the deasphalted hydrocarbons are produced from a third section of the formation substantially adjacent the second section of the formation.

24. The method of claim 14, wherein the produced deasphalted hydrocarbons are suitable for transportation.

25. The method of claim 14, wherein the produced deasphalted hydrocarbons have a P-value of at least 1.

26. The method of claim 14, further comprising producing at least some hydrocarbons from a portion lower than the upper portion of the second section, and allowing at least a portion of the in situ deasphalting fluid to drain to the lower portion of the second section.

27. The method of claim 14, further comprising producing at least some hydrocarbons from a portion lower than the upper portion of the second section, allowing at least a portion of the in situ deasphalting fluid to drain to the lower portion of the second section, contacting at least a portion of the in situ deasphalting fluid with hydrocarbons in the lower portion of the second section to remove asphaltenes from the hydrocarbons in the lower portion of the second section, and producing deasphalted hydrocarbons from the lower portion of the second section.

28. The method of claim 14, wherein the generated in situ deasphalting fluid comprises hydrocarbons having a boiling range distribution between 38°

C. and 200°

C. at 0.101 MPa.