Lubricating oil composition for refrigerators and compressors with the composition

• US 8,703,662 B2
• Filed: 04/18/2008
• Issued: 04/22/2014
• Est. Priority Date: 04/18/2007
• Status: Active Grant

• Current Assignee: Idemitsu Kosan Company Limited
• Original Assignee: DENSO Corporation, Idemitsu Kosan Company Limited, Kabushiki Kaisha Toyota Jidoshokki
• Inventors: Kaneko, Masato, Ikeda, Harutomo, Kato, Takayuki, Hoshida, Takahiro, Inoue, Masaki, Ikejima, Shozo, Muto, Masataka, Yamashita, Masahito
• Primary Examiner(s): VASISTH, VISHAL V
• Application Number:
  US12/595,693
• Publication Number:
  US 20100147016A1
• Time in Patent Office: 2,195 Days
• Field of Search: 508/110, 624/68, 252/68
• US Class Current: 508/110
• CPC Class Codes: C10M 105/38 of polyhydroxy compounds
• CPC Class Codes: C10M 171/008 Lubricant compositions compatible with refrigerants
• CPC Class Codes: C10M 2201/0413 used as base material
• CPC Class Codes: C10M 2201/0603 used as base material
• CPC Class Codes: C10M 2207/026 with tertiary alkyl groups
• CPC Class Codes: C10M 2207/2835 used as base material
• CPC Class Codes: C10M 2209/1033 used as base material
• CPC Class Codes: C10M 2213/0623 used as base material
• CPC Class Codes: C10M 2217/0403 used as base material
• CPC Class Codes: C10M 2221/003 used as base material
• CPC Class Codes: C10N 2010/08 Groups 4 or 14
• CPC Class Codes: C10N 2010/12 Groups 6 or 16
• CPC Class Codes: C10N 2010/14 Group 7
• CPC Class Codes: C10N 2020/02 Viscosity; Viscosity index
• CPC Class Codes: C10N 2020/04 Molecular weight; Molecular weight distribution
• CPC Class Codes: C10N 2020/097 Refrigerants
• CPC Class Codes: C10N 2020/099 Containing Chlorofluorocarbons
• CPC Class Codes: C10N 2020/101 Containing Hydrofluorocarbons
• CPC Class Codes: C10N 2030/06 Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
• CPC Class Codes: C10N 2030/10 Inhibition of oxidation, e.g. anti-oxidants
• CPC Class Codes: C10N 2030/40 : Low content or no content compositions
• CPC Class Codes: F04B 39/02 : Lubrication of machines or engines in general F01M
• CPC Class Codes: F04B 39/0215 : characterised by the use of a special lubricant
• CPC Class Codes: F04B 53/18 : Lubricating

Abstract

A lubricating oil composition for refrigerators comprising a base oil which comprises as a main component a polyol ester compound obtained from a polyhydric alcohol selected from among pentaerythritol, dipentaerythritol, trimethylolpropane, and neopentyl glycol and a C₄ to C₂₀ aliphatic monocarboxylic acid and which has an acid value of 0.02 mgKOH/g or less and a hydroxyl value of 5 mgKOH/g or less. A compressor using the lubricating composition. The lubricating oil composition is applicable to such refrigerators that use a refrigerant having a specific structure, such as an unsaturated fluorinated hydrocarbon compound, and being usable in current car air conditioner systems, and has excellent compatibility with the refrigerant, good sealing properties, capability of imparting a low coefficient of friction to sliding members and, yet, excellent stability. The compressor uses the lubricating composition.

Claims

1. A lubricating oil composition/refrigerant combination, comprising

a refrigerant, which consists of a C₂ to C₃ unsaturated fluorinated hydrocarbon refrigerant, and

a base oil consisting of a polyol ester compound in an amount of at least 50% by mass, wherein the polyol ester compound is obtained from a polyhydric alcohol selected from the group consisting of pentaerythritol, dipentaerythritol, trimethylolpropane and neopentyl glycol, and a C₆ to C₂₀ aliphatic monocarboxylic acid, wherein said polyol ester compound has an acid value of 0.02 mgKOH/g or less and a hydroxyl value of 5 mgKOH/g or less,

wherein the base oil has a kinematic viscosity at 100°

C. of 4 to 30 mm²/s and a molecular weight of 500 to 3000.

2. The lubricating oil composition/refrigerant combination as defined in claim 1, wherein the base oil has a flash point of at least 200°

C.

3. The lubricating oil composition/refrigerant combination as defined in claim 1, further comprising at least one additive selected from the group consisting of an extreme pressure agent, an oiliness agent, an antioxidant, an acid scavenger, and an anti-foaming agent.

4. The lubricating oil composition/refrigerant combination as defined in claim 1, wherein the refrigerators have a sliding member made of an engineering plastic or having an organic coating film or an inorganic coating film.

5. The lubricating oil composition/refrigerant combination as defined in claim 4, wherein the organic coating film is a polytetrafluoroethylene coating film, a polyimide coating film, a polyamide-imide coating film, or a thermosetting insulating film formed from a resin coating material, wherein said resin coating material comprises a resin base material comprising a polyhydroxyether resin, a polysulfone-based resin, and a cross-linking agent.

6. The lubricating oil composition as defined in claim 4, wherein the inorganic coating film is a graphite film, a carbon film, a tin film, a chromium film, a nickel film, or a molybdenum film.

7. The lubricating oil composition/refrigerant combination as defined in claim 1, present in a hot-water supplying system or refrigeration and heating system for car air conditioners, an electric car air conditioner, a gas heat pump, an air conditioner, a refrigerator, a vending machine, or a showcase.

8. The lubricating oil composition/refrigerant combination as defined in claim 7, wherein a water content and a residual air content within each of the systems are 300 ppm by mass or less and 10 kPa or less, respectively.

9. A compressor comprising the refrigerator oil composition as defined in claim 1.

10. The compressor as defined in claim 9, wherein the compressor has a sliding member comprising an engineering plastic or an organic coating film or an inorganic coating film.

11. The compressor as defined in claim 10, wherein the engineering plastic is a polyamide resin, a polyphenylene sulfide resin, or a polyacetal resin.

12. The compressor as defined in claim 10, wherein the organic coating film is a polytetrafluoroethylene coating film, a polyimide coating film, a polyamide-imide coating film, or a thermosetting insulating film formed from a resin coating material comprising a resin base material, wherein said resin base material comprises comprising a polyhydroxyether resin, a polysulfone-based resin, and a cross-linking agent.

13. The compressor as defined in claim 10, wherein the inorganic coating film is a graphite film, a carbon film, a tin film, a chromium film, a nickel film, or a molybdenum film.

14. The lubricating oil composition/refrigerant combination as defined in claim 1, wherein the refrigerant is a fluorinated propene.

15. The lubricating oil composition/refrigerant combination as defined in claim 1, wherein the refrigerant is an isomer of pentafluoropropene, 3,3,3-trifluoropropene, or 2,3,3,3-tetrafluoropropene.

16. The lubricating oil composition for refrigerators as defined in claim 1, wherein the aliphatic monocarboxylic acid comprises 6 to 12 carbon atoms.

17. The lubricating oil composition for refrigerators as defined in claim 1, wherein the aliphatic monocarboxylic acid comprises 6 to 9 carbon atoms.