End cap voltage control of ion traps

• US 8,704,168 B2
• Filed: 12/17/2012
• Issued: 04/22/2014
• Est. Priority Date: 12/10/2007
• Status: Active Grant

• Current Assignee: Astrotech Technologies, Inc. (Astrotech Corporation)
• Original Assignee: 1st Detect Corporation (Astrotech Corporation)
• Inventors: Rafferty, David
• Primary Examiner(s): Maskell, Michael
• Application Number:
  US13/717,169
• Publication Number:
  US 20130099137A1
• Time in Patent Office: 491 Days
• Field of Search: 250/281, 250/282, 250290-292
• US Class Current: 250/283
• CPC Class Codes: H01J 49/26 Mass spectrometers or separator tubes
• CPC Class Codes: H01J 49/424 Three-dimensional ion traps, i.e. comprising end-cap and ring electrodes

Abstract

An ion trap for a mass spectrometer has a conductive central electrode with an aperture extending from a first open end to a second open end. A conductive first electrode end cap is disposed proximate to the first open end thereby forming a first intrinsic capacitance between the first end cap and the central electrode. A conductive second electrode end cap is disposed proximate to the second open end thereby forming a second intrinsic capacitance between the second end cap and the central electrode. A first circuit couples the second end cap to a reference potential. A signal source generating an AC trap signal is coupled to the central electrode. An excitation signal is impressed on the second end cap in response to a voltage division of the trap signal by the first intrinsic capacitance and the first circuit.

Claims

1. An ion trap comprising:

a conductive ring-shaped central electrode having a first aperture extending from a first open end to a second open end;

a signal source generating a trap signal having at least an alternating current (AC) component between a first and second terminal, wherein the first terminal is coupled to the central electrode and the second terminal is coupled to a source reference voltage potential;

a conductive first electrode end cap disposed adjacent to the first open end of the central electrode and coupled to a first reference voltage potential, wherein a first intrinsic capacitance is formed between a surface of the first electrode end cap and a surface of the first open end of the central electrode; and

a conductive second electrode end cap disposed adjacent to the second open end of the central electrode and coupled to a second reference voltage potential with a first electrical circuit means for impressing a fractional part of the trap signal on the conductive second electrode end cap,

wherein a second intrinsic capacitance is formed between a surface of the second electrode end cap and a surface of the second open end of the central electrode, and

wherein the fractional part of the trap signal is impressed on the second electrode end cap as an excitation voltage in response to a voltage division of the trap signal by the second intrinsic capacitance and an impedance of the first electrical circuit means.

2. The ion trap of claim 1, wherein the first electrical circuit means comprises a capacitor in parallel with a resistor.

3. The ion trap of claim 2, wherein an impedance of the resistor is greater than one fourth of an impedance of the capacitor at a frequency of the trap signal.

4. The ion trap of claim 1, wherein the source reference voltage potential is ground or zero volts.

5. The ion trap of claim 2, wherein the capacitor is a variable capacitor adjustable to optimize an operating characteristic of the ion trap.

8. The ion trap of claim 1, wherein the ion trap is a mass analyzer, and wherein, the first reference voltage potential, the second reference voltage potential, or both are an adjustable DC voltage.

9. The ion trap of claim 1, wherein the first and second reference voltage potentials are generated by corresponding DC voltage sources.

10. The ion trap of claim 1, wherein the ion trap is configured to impress the fractional part of the trap signal only on the conductive second electrode end cap.

11. The ion trap of claim 1, wherein the ion trap is configured to receive a resonance ejection signal.

12. The ion trap of claim 1, wherein the amplitude of the fractional part of the trap signal is substantially independent of the frequency of the trap signal.

13. The ion trap of claim 1, wherein the phase difference between the fractional part of the trap signal and the trap signal is substantially independent of the frequency of the trap signal.

14. The ion trap of claim 1, wherein a fractional part of the trap signal is also impressed on the conductive first electrode end cap.

15. The ion trap of claim 1, further comprising a second electrical circuit coupled between the conductive first electrode end cap and the first reference voltage potential, wherein a fractional part of the trap signal is impressed on the conductive first electrode end cap in response to a voltage division of the trap signal by the first intrinsic capacitance and an impedance of the second electrical circuit.

16. The ion trap of claim 1, wherein the excitation voltage is generated by a parasitic signal that is formed from the trap signal applied to the central electrode.

17. The ion trap of claim 2, where the resistor has a resistance greater than the impedance of the capacitor in a frequency range of operation of the signal source in generating the trap signal.

6. An ion trap comprising:

a central electrode having an aperture;

a first end cap electrode having an aperture;

a second end cap electrode having an aperture;

an electronic signal source that generates a trap signal applied to the central electrode;

a passive circuit means for impressing a fractional part of the trap signal on the first end cap electrode;

an electrical connection between said first end cap electrode and said passive circuit means; and

an electrical connection between said passive circuit means and a voltage potential, wherein said first end cap electrode, connected to said voltage potential via said passive circuit means, bears an excitation voltage due to capacitive coupling between said electronic signal source and said passive circuit means.

7. The ion trap of claim 6, further comprising a switching circuit that electrically connects and disconnects said first end cap electrode to said passive circuit means.

18. The ion trap of claim 6, wherein the ion trap is configured to receive a resonance ejection signal.

19. The ion trap of claim 6, wherein the amplitude of the fractional part of the trap signal is substantially independent of the frequency of the trap signal.

20. The ion trap of claim 6, wherein the phase difference between the fractional part of the trap signal and the trap signal is substantially independent of the frequency of the trap signal.

21. The ion trap of claim 6, wherein a fractional part of the trap signal is also impressed on the conductive second electrode end cap.

22. The ion trap of claim 6, wherein the excitation voltage is generated by a parasitic signal that is formed from the trap signal applied to the central electrode.

23. The ion trap of claim 6, further comprising:

a second passive circuit means for impressing a fractional part of the trap signal on the second end cap electrode;

an electrical connection between said the second end cap electrode and the second passive circuit means; and

an electrical connection between the second passive circuit means and a second voltage potential, wherein the second end cap electrode, connected to the second voltage potential via the second passive circuit means, bears an excitation voltage due to capacitive coupling between the electronic signal source and the second passive circuit means.

24. The ion trap of claim 23, wherein the first and second reference voltage potentials are generated by corresponding DC voltage sources.

25. The ion trap of claim 23, wherein the ion trap is a mass analyzer, and wherein the voltage potential, the second voltage potential, or both are an adjustable DC voltage.