High conductive water-based silver ink

• US 8,709,288 B2
• Filed: 09/08/2006
• Issued: 04/29/2014
• Est. Priority Date: 09/08/2006
• Status: Active Grant

• Current Assignee: Sun Chemical Corporation
• Original Assignee: Sun Chemical Corporation
• Inventors: Klein, Dave, Rouse, Jason Haden
• Primary Examiner(s): PEETS, MONIQUE R
• Application Number:
  US11/530,359
• Publication Number:
  US 20080182090A1
• Time in Patent Office: 2,790 Days
• Field of Search: 428/208, 252/511, 252/500, 252/514, 101/129, 101/463.1
• US Class Current: 252/500
• CPC Class Codes: C09D 11/52 Electrically conductive inks
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys
• CPC Class Codes: H05K 1/095 for polymer thick films, i.e. having a permanent organic polymeric binder
• CPC Class Codes: Y10T 428/24909 Free metal or mineral containing
• CPC Class Codes: Y10T 428/256 Heavy metal or aluminum or compound thereof

Abstract

Disclosed is a conductive composition which can be used to form an aqueous conductive ink with increased conductivity. The aqueous conductive composition contains conductive particles, preferably silver, an anionic wetting agent and a styrene-acrylic copolymer. The composition is highly conductive and requires reduced drying energy. In addition, it may be applied to low cost substrates by high speed printing processes.

Claims

1. A method of forming a conductive pattern on a substrate comprising applying a conductive composition comprising (a) metallic silver conductive particles, (b) water soluble styrene/(meth)acrylic copolymer, (c) an anionic wetting agent, (d) defoamer and (e) 10 to 80% water, the composition providing a sheet resistance of less than 0.83 ohms/sq, on the substrate and drying the composition.

2. The method of claim 1, wherein the longest dimension of said silver conductive particles is from about 100 nm to 50 micrometers.

3. The method of claim 2, wherein said longest dimension of said silver conductive particles is from about 1 to 20 micrometers.

4. The method of claim 1, wherein said styrene/(meth)acrylic copolymer is a copolymer of styrene and an alkyl (meth)acrylate, optionally partly hydrolyzed or salified.

5. The method of claim 1, wherein said copolymer to water has a ratio of about 4 to 1 to 1 to 8.

6. The method of claim 1, wherein said styrene/(meth)acrylic copolymer comprises a blend with an alkyl (meth)acrylate copolymer.

7. The conductive composition of claim 6, wherein said alkyl moieties comprise at least one of ethyl, propyl, butyl, and hexyl.

8. The method of claim 1, wherein said anionic wetting agent is selected from the group consisting of alkali sulphosuccinate, alkali sulfosuccinate, and anionic polyacrylate copolymer.

9. The method of claim 1, wherein said anionic wetting agent is selected from the group consisting of dihexyl sulphosuccinate salt, di-2-ethylhexyl sulfosuccinate salt, and dioctyl sulfosuccinate salt.

10. The method of claim 1, wherein the conductive composition further comprises at least one solvent selected from the group consisting of alcohols, amines, glycols, acetates, ethers, ketones, aldehydes, and amides.

11. The method of claim 1, wherein said silver conductive particles are about 10 to 90% of said composition, said copolymer is about 2 to 50%, said defoamer is about 0.01 to 4%, and said anionic wetting agent is about 0.01 to 6% by weight.

12. The method of claim 11, wherein said silver conductive particles are about 40 to 75% of the composition, the copolymer is about 2 to 20%, the defoamer is about 0.1 to 2%, and the anionic wetting agent is about 0.1 to 3% by weight.

13. The method of claim 12, wherein said silver conductive particles are about 50 to 70% of the composition, the copolymer is about 4 to 10%, the defoamer is about 0.2 to 1.5%, and the anionic wetting agent is about 0.5 to 2% by weight.

14. The method of claim 10, wherein the longest dimension of said silver conductive particles is from about 100 nm to 50 micrometers, said styrene/(meth)acrylic copolymer is a copolymer of styrene and an alkyl (meth)acrylate, optionally partly hydrolyzed or salified;

said anionic wetting agent is selected from the group consisting of alkali sulphosuccinate, alkali sulfosuccinate, and anionic polyacrylate copolymer;

said copolymer to water has a ratio of 4;

1 to 1;

8; and

said composition has a Zahn cup #3 viscosity in the range of about 10 to 40 seconds.

15. The method of claim 1, wherein said composition has a Zahn cup #3 viscosity in the range of about 10 to 40 seconds.

16. The method of claim 1, wherein said composition is applied by coating, spraying, painting, or printing.

17. The method of claim 1, wherein said composition is applied by screen, rotary screen, gravure, or letterpress printing.

18. The method of claim 1, wherein said composition is applied by flexographic printing.

19. The method of claim 18, wherein said composition is applied so as to realize graphics with less than about 500 micrometer spacing between adjacent lines.

20. The method of claim 18, wherein said composition is applied so as to realize graphics with less than about 300 micrometer spacing between adjacent lines.

21. The method of claim 1, wherein said composition is applied in an amount such that after drying the dried composition has a volume resistivity of about 120 micro-ohms.cm or lower.

22. The method of claim 21, wherein said composition is applied in an amount such that after drying the dried composition has a volume resistivity of about 60 micro-ohms.cm or lower.

23. The method of claim 1, wherein said composition is applied on said substrate in the form of an antenna.

24. The method of claim 1, wherein said composition is applied on said substrate in the form of an RFID antenna.

25. The method of claim 24, wherein said composition is applied on said substrate in the form of the RFID antenna designed to operate in the frequency range of at least 800 MHz.

26. The method of claim 25, wherein the RFID integrated circuit chip is applied to said RFID antenna via direct chip attachment, RFID strap attachment, or through space contact.

27. The method of claim 26, wherein said RFID integrated circuit chip is EPC Class 1 UHF RFID compliant.

28. The method of claim 1, wherein said composition is applied on said substrate to form a printed circuit.

29. The method of claim 1, wherein said substrate is a cellulosic substrate.

30. The method of claim 29, wherein said cellulosic substrate is selected from the group consisting of coated paper, uncoated paper, thermal transfer paper, direct thermal paper, coated cardboard, uncoated cardboard, a primed uncoated cardboard, kraft paper, fluted paper, and mottled paper.

31. The method of claim 1, wherein said substrate is a plastic.

32. The method of claim 30, wherein said substrate is selected from the group consisting of a polyester, polyethylene, polypropylene, polyamide, polyimide, polyetherimide, polyurethane, polycarbonate, cellulosic ester (e.g. cellulose acetate etc.), polystyrene and styrenic copolymers.

33. The method of claim 1, wherein said substrate is a metal-oxide coated plastic.

34. A method of forming a conductive pattern on a substrate comprising applying a conductive composition consisting essentially of (a) metallic silver conductive particles, (b) water soluble styrene/(meth)acrylic copolymer, (c) an anionic surfactant, (d) defoamer and (e) 10 to 80% water, the composition providing a sheet resistance of less than 0.83 ohms/sq, on the substrate and drying the composition.

35. The method of claim 34, wherein the longest dimension of said silver conductive particles is from about 100 nm to 50 micrometers, said styrene/(meth)acrylic copolymer is a copolymer of styrene and an alkyl (meth)acrylate, optionally partly hydrolyzed or salified;

said anionic surfactant is selected from the group consisting of alkali sulphosuccinate, alkali sulfosuccinate, and anionic polyacrylate copolymer;

said copolymer to water has a ratio of 4;

1 to 1;

8;

said composition has a Zahn cup #3 viscosity in the range of about 10 to 40 seconds; and

wherein said silver particles are about 50 to 70% of said composition, said copolymer is about 4 to 10%, said defoamer is about 0.2 to 1.5%, said anionic surfactant is about 0.5 to 2% by weight, said water is about 20 to 65%, and said composition provides the sheet resistance of less than 0.38 ohms/sq.

36. The method of claim 35, wherein said silver conductive particles are about 40 to 75% of the composition, said copolymer is about 2 to 20%, said defoamer is about 0.1 to 2%, said anionic surfactant is about 0.1 to 3% by weight, said water is about 25 to 35%, and said composition provides the sheet resistance of less than 0.18 ohms/sq.

37. A method of forming a conductive pattern on a substrate comprising applying a conductive composition consisting of (a) metallic conductive particles, (b) water soluble styrene/(meth)acrylic copolymer, (c) an anionic surfactant, (d) defoamer, (e) 10 to 80% water, and optionally another solvent, the composition providing a sheet resistance of less than 0.83 ohms/sq, on the substrate and drying the composition.

38. The method of claim 37, wherein said metallic conductive particles are silver and the longest dimension of said silver conductive particles is from about 100 nm to 50 micrometers, said styrene/(meth)acrylic copolymer is a copolymer of styrene and an alkyl (meth)acrylate, optionally partly hydrolyzed or salified;

said anionic surfactant is selected from the group consisting of alkali sulphosuccinate, alkali sulfosuccinate, and anionic polyacrylate copolymer;

said copolymer to water has a ratio of 4;

1 to 1;

8;

said composition has a Zahn cup #3 viscosity in the range of about 10 to 40 seconds; and

wherein the silver conductive particles is are about 50 to 70% of said composition, said copolymer is about 4 to 10%, said defoamer is about 0.2 to 1.5%, said anionic surfactant is about 0.5 to 2% by weight, said water is about 20 to 65%, and said composition provides the sheet resistance of less than 0.38 ohms/sq.

39. The method of claim 38, wherein said silver conductive particles are about 40 to 75% of the composition, said copolymer is about 2 to 20%, said defoamer is about 0.1 to 2%, said anionic surfactant is about 0.1 to 3% by weight, said water is about 25 to 35%, and the composition provides the sheet resistance of less than 0.18 ohms/sq.