High conductive water-based silver ink

• US 8,709,289 B2
• Filed: 09/07/2007
• Issued: 04/29/2014
• Est. Priority Date: 09/08/2006
• Status: Active Grant

• Current Assignee: Sun Chemical Corporation
• Original Assignee: Sun Chemical Corporation
• Inventors: Rouse, Jason Hayden, Klein, Dave
• Primary Examiner(s): PEETS, MONIQUE R
• Application Number:
  US12/439,995
• Publication Number:
  US 20110155812A1
• Time in Patent Office: 2,426 Days
• Field of Search: 428/408, 428/328, 252/500, 252/514, 252/511, 252/513, 101/129, 101/463.1, 427/117
• US Class Current: 252/500
• CPC Class Codes: C09D 11/52 Electrically conductive inks
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys
• CPC Class Codes: H05K 1/095 for polymer thick films, i.e. having a permanent organic polymeric binder
• CPC Class Codes: Y10T 428/24909 Free metal or mineral containing
• CPC Class Codes: Y10T 428/256 Heavy metal or aluminum or compound thereof

Abstract

Disclosed is a conductive composition which can be used to form an aqueous conductive ink with increased conductivity. A film of the dry ink having a thickness of 5 microns or less has a surface roughness of less than 1.5 times the surface roughness of a cellulosic-based substrate which it coats. The aqueous conductive composition contains conductive particles, preferably silver, an anionic wetting agent and a styrene-acrylic copolymer. The composition is highly conductive and requires reduced drying energy. In addition, it may be applied to low cost substrates by high speed printing processes.

Claims

1. A conductive composition comprising:

(a) conductive particles;

(b) styrene/(meth)acrylic copolymer;

(c) an anionic wetting agent;

(d) defoamer; and

(e) 10 to 80% water,

wherein water is a primary solvent for the conductive composition.

2. The conductive composition of claim 1, which is water-based and when dry, a 5 micron or less layer on a cellulosic substrate has a ratio of surface roughness to substrate roughness of not more than 1.5.

3. The conductive composition of claim 2 having a sheet resistance of not more than 200 milliohm/square when dry and having a thickness of 5 micron or less.

4. The conductive composition of claim 2 having, when dry, a RFID antenna read range of at least 3 meters.

5. The conductive composition of claim 2, wherein the conductive particles comprise silver.

6. The conductive composition of claim 5, wherein the longest dimension of said silver particles is from about 100 nm and 50 micrometers.

7. The conductive composition of claim 6, wherein the longest dimension of said silver particles is from about 1 to 20 micrometers.

8. The conductive composition of claim 2, wherein the styrene/(meth)acrylic copolymer is a copolymer of styrene and an alkyl (meth)acrylate, optionally partly hydrolyzed or salified.

9. The conductive composition of claim 2, wherein the copolymer to water has a ratio of about 4 to 1 to 1 to 8.

10. The conductive composition of claim 2, wherein the styrene/(meth)acrylic copolymer comprises a blend with an alkyl (meth)acrylate copolymer.

11. The conductive composition of claim 10 wherein the alkyl moieties comprise at least one of ethyl, propyl, butyl, and hexyl.

12. The conductive composition of claim 2, wherein the anionic wetting agent is selected from the group consisting of alkali sulphosuccinate, alkali sulfosuccinate, and anionic polyacrylate copolymer.

13. The conductive composition of claim 2, wherein the anionic wetting agent is selected from the group consisting of dihexyl sulphosuccinate salt, di-2-ethylhexyl sulfosuccinate salt, and dioctyl sulfosuccinate salt.

14. The conductive composition of claim 2, further comprising at least one solvent selected from the group consisting of alcohols, amines, glycols, acetates, ethers, ketones, aldehydes, and amides.

15. The conductive composition of claim 5, where the silver is about 10 to 90% of the composition, the copolymer is about 2 to 50%, the defoamer is about 0.01 to 4%, and the anionic wetting agent is about 0.01 to 6% by weight.

16. The conductive composition of claim 15, where the silver is about 40 to 75% of the composition, the copolymer is about 2 to 20%, the defoamer is about 0.1 to 2%, and the anionic wetting agent is about 0.1 to 3% by weight.

17. The conductive composition of claim 16, where the silver is about 50 to 70% of the composition, the copolymer is about 4 to 10%, the defoamer is about 0.2 to 1.5%, and the anionic wetting agent is about 0.5 to 2% by weight.

18. The conductive composition of claim 17, wherein the longest dimension of said silver particles is from about 100 nm and 50 micrometers, the styrene/(meth)acrylic copolymer is a copolymer of styrene and an alkyl (meth)acrylate, optionally partly hydrolyzed or salified;

the anionic wetting agent is selected from the group consisting of alkali sulphosuccinate, alkali sulfosuccinate, and anionic polyacrylate copolymer;

the copolymer to water has a ratio of 4;

1 to 1;

8; and

the composition has a Zahn cup #3 viscosity in the range of about 10 to 40 seconds.

19. The conductive composition of claim 2, having a Zahn cup #3 viscosity in the range of about 10 to 40 seconds.

20. The conductive composition of claim 2, wherein the conductive particles are at least one member selected from the group consisting of copper, gold, nickel, carbon, graphite, silver alloys, silver coated metal, silver coated glass, silver coated mica, silver coated graphite, nickel coated carbon, and nickel coated graphite.