Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same

• US 8,709,653 B2
• Filed: 03/08/2005
• Issued: 04/29/2014
• Est. Priority Date: 03/08/2004
• Status: Active Grant

• Current Assignee: Samsung SDI Company Limited
• Original Assignee: Samsung SDI Company Limited
• Inventors: Lee, Sang-Min, Jeong, Goo-Jin, Kim, Sung-Soo, Nitta, Yoshiaki
• Primary Examiner(s): Conley, Helen O
• Application Number:
  US11/077,377
• Publication Number:
  US 20050233213A1
• Time in Patent Office: 3,339 Days
• Field of Search: 429/209, 429/218.1
• US Class Current: 429/218.1
• CPC Class Codes: C01B 35/12 Borates C01B35/1063 takes precedence
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 4/0402 Methods of deposition of the material
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 4/139 Processes of manufacture
• CPC Class Codes: H01M 4/362 Composites
• CPC Class Codes: H01M 4/485 of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy H01M4/505, H01M4/525 take precedence
• CPC Class Codes: H01M 4/587 for inserting or intercalating light metals
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

The present invention relates to a negative active material for a rechargeable lithium battery, which includes a silicon-based composite having a silicon oxide of the form SiO_X where x≦1.5 and at least one element selected from the group consisting of B, P, Li, Ge, Al, and V, and a carbonaceous material. The negative active material of the present invention can improve the cycle-life and high-rate charge/discharge characteristics of a rechargeable lithium battery.

Claims

1. A negative active material for a rechargeable lithium battery, comprising:

a silicon-based composite core of a uniform phase comprising;

a silicon oxide of the form SiO_x where x≦

1.5, and one or more elements selected from the group consisting of B, P, Al, and V, wherein the one or more elements are included in a range of 6.2 wt% to 50 wt % based on the total weight of the silicon-based composite core; and

a carbonaceous material coating layer on the surface of the silicon-based composite core.

2. The negative active material according to claim 1, where x is between 0.5 and 1.5.

3. The negative active material according to claim 1, wherein the one or more elements selected from the group consisting of B, P, Al, and V are provided in an amount from 10 wt % to 30 wt % with respect to the total weight of the silicon-based composite core.

4. The negative active material according to claim 1, wherein the silicon oxide is doped with the one or more elements selected from the group consisting of B, P, Al, and V.

5. The negative active material according to claim 1, wherein the carbonaceous material is crystalline carbon or amorphous carbon.

6. The negative active material according to claim 1, wherein the silicon-based composite core further comprises Si, SiO₂, or mixtures thereof.

7. The negative active material according to claim 1, wherein the silicon-based composite core and the carbonaceous material are provided in a weight ratio between 10:

90 and 90;

10.

8. The negative active material according to claim 1, wherein the silicon-based composite core and the carbonaceous material are provided in a weight ratio between 30:

70 and 70;

30.

9. The negative active material according to claim 1, wherein the negative active material has an amorphorization degree of over 50% and the amorphorization degree is calculated based on an X-ray diffraction peak by the following Calculation Formula:

Amorphorization degree (%)=((Main XRD peak intensity of the silicon-based composite core after carrying out a quenching treatment)/(Main XRD peak intensity of the silicon-based composite core before carrying out the quenching treatment))×

100.

10. The negative active material according to claim 1, wherein the negative active material has a Li diffusion rate of over 10⁻

8 cm²/sec based on a Galvanostatic Intermittent Titration Technique (GITT) method.

11. A rechargeable lithium battery, comprising:

a negative electrode including a negative active material comprising a carbonaceous material coating layer and a silicon-based composite core of a uniform phase comprising;

a silicon oxide of the form SiO_x where x≦

1.5 and one or more elements selected from the group consisting of B, P, Al, and V, wherein the one or more elements are included in a range of 6.2 wt% to 50 wt % based on the total weight of the silicon-based composite core, wherein the carbonaceous material coating layer is on the surface of the silicon-based composite core;

a positive electrode including a positive active material capable of reversibly intercalating/deintercalating lithium; and

an electrolyte.