Oxide material, electrophotographic photoreceptor, process cartridge, and image forming device

• US 8,709,688 B2
• Filed: 04/23/2013
• Issued: 04/29/2014
• Est. Priority Date: 09/24/2009
• Status: Active Grant

• Current Assignee: Fujifilm Business Innovation Corp. (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Xerox Company Limited (Xerox Holdings Corp.)
• Inventors: Yagi, Shigeru, Iwanaga, Takeshi
• Primary Examiner(s): FRASER, STEWART A
• Application Number:
  US13/868,466
• Publication Number:
  US 20130236212A1
• Time in Patent Office: 371 Days
• Field of Search: 430/56, 430/58.08, 430/59.1, 430/66, 430/69, 430/58.05
• US Class Current: 430/56
• CPC Class Codes: G03G 2215/00957 Compositions
• CPC Class Codes: G03G 5/08 characterised by the photoconductive material being inorganic
• CPC Class Codes: G03G 5/082 and not being incorporated in a bonding material, e.g. vacuum deposited
• CPC Class Codes: G03G 5/08207 Selenium-based
• CPC Class Codes: G03G 5/153 Charge-receiving layers combined with additional photo- or thermo-sensitive, but not photoconductive, layers, e.g. silver-salt layers

Abstract

An oxide material including gallium, zinc and oxygen, a ratio of the number of atoms of zinc to the number of atoms of gallium (number of atoms of zinc/number of atoms of gallium) being from about 0.01 to about 0.6 and a ratio of the number of atoms of oxygen to the sum of the number of atoms of gallium and the number of atoms of zinc (number of atoms of oxygen/(number of atoms of gallium+number of atoms of zinc)) being from about 1.0 to about 1.6, is disclosed. An electrophotographic photoreceptor including a layer which includes the oxide material is also disclosed. An electrophotographic photoreceptor including a substrate; and a photosensitive layer including gallium, oxygen and zinc is also disclosed.

Claims

1. An electrophotographic photoreceptor, comprising:

a substrate; and

a photosensitive layer including an oxide material comprising gallium, oxygen and zinc, a ratio of the number of atoms of zinc to the number of atoms of gallium (number of atoms of zinc/number of atoms of gallium) being from 0.01 to 0.4 and a ratio of the number of atoms of oxygen to the number of atoms of gallium and the number of atoms of zinc (number of atoms of oxygen/(number of atoms of gallium +number of atoms of zinc)) being from 1.0 to 1.6.

2. The electrophotographic photoreceptor of claim 1, wherein the content of gallium in the photosensitive layer is larger than the content of zinc in the photosensitive layer in terms of a ratio of the number of atoms.

3. The electrophotographic photoreceptor of claim 2, wherein the photosensitive layer includes a charge generating layer and a charge transport layer, the charge transport layer including gallium, oxygen and zinc.

4. The electrophotographic photoreceptor of claim 3, wherein the charge generating layer includes an organic charge generating material.

5. The electrophotographic photoreceptor of claim 3, further comprising a charge injection layer between the charge generating layer and the charge transport layer, the charge injection layer including gallium, oxygen and zinc, and a ratio of the content of zinc to the content of gallium in the charge injection layer, in terms of a ratio of the number of atoms, being higher than the ratio of the content of zinc to the content of gallium in the charge transport layer in terms of a ratio of the number of atoms.

6. The electrophotographic photoreceptor of claim 3, further comprising a charge injection layer between the charge generating layer and the charge transport layer, the charge injection layer including gallium, oxygen and zinc, and a ratio of the content of oxygen to the sum of the content gallium and the content of zinc in the charge injection layer, in terms of a ratio of the number of atoms, being lower than the ratio of the content oxygen to the sum of the content gallium and the content of zinc in the charge transport layer in terms of a ratio of the number of atoms.

7. A process cartridge comprising:

the electrophotographic photoreceptor of claim 1; and

at least one selected from the group consisting of a charging device, a developing device and a cleaning device.

8. An image forming device comprising:

the electrophotographic photoreceptor of claim 1;

a charging device that charges the electrophotographic photoreceptor;

a latent image forming device that forms a latent image on the surface of the charged electrophotographic photoreceptor;

a developing device that develops the latent image formed on the surface of the electrophotographic photoreceptor with a developer including a toner; and

a transfer device that transfers the toner image formed on the surface of the electrophotographic photoreceptor to a recording medium.

9. An electrophotographic photoreceptor, comprising:

a substrate; and

a photosensitive layer including a charge generating layer and a charge transport layer, the charge transport layer including gallium, oxygen and zinc,

wherein the content of gallium in the photosensitive layer is larger than the content of zinc in the photosensitive layer in terms of a ratio of the number of atoms, and

further comprising a charge injection layer between the charge generating layer and the charge transport layer, the charge injection layer including gallium, oxygen and zinc, and a ratio of the content of zinc to the content of gallium in the charge injection layer, in terms of a ratio of the number of atoms, being higher than the ratio of the content of zinc to the content of gallium in the charge transport layer in terms of a ratio of the number of atoms.

10. The electrophotographic photoreceptor of claim 9, wherein the charge generating layer includes an organic charge generating material.

11. A process cartridge comprising:

the electrophotographic photoreceptor of claim 9; and

at least one selected from the group consisting of a charging device, a developing device and a cleaning device.

12. An image forming device comprising:

the electrophotographic photoreceptor of claim 9;

a charging device that charges the electrophotographic photoreceptor;

a latent image forming device that forms a latent image on the surface of the charged electrophotographic photoreceptor;

a developing device that develops the latent image formed on the surface of the electrophotographic photoreceptor with a developer including a toner; and

a transfer device that transfers the toner image formed on the surface of the electrophotographic photoreceptor to a recording medium.

13. An electrophotographic photoreceptor, comprising:

a substrate; and

a photosensitive layer including a charge generating layer and a charge transport layer, the charge transport layer including gallium, oxygen and zinc,

wherein the content of gallium in the photosensitive layer is larger than the content of zinc in the photosensitive layer in terms of a ratio of the number of atoms, and.

further comprising a charge injection layer between the charge generating layer and the charge transport layer, the charge injection layer including gallium, oxygen and zinc, and a ratio of the content of oxygen to the sum of the content gallium and the content of zinc in the charge injection layer, in terms of a ratio of the number of atoms, being lower than the ratio of the content oxygen to the sum of the content gallium and the content of zinc in the charge transport layer in terms of a ratio of the number of atoms.

14. The electrophotographic photoreceptor of claim 13, wherein the charge generating layer includes an organic charge generating material.

15. A process cartridge comprising:

the electrophotographic photoreceptor of claim 13; and

at least one selected from the group consisting of a charging device, a developing device and a cleaning device.

16. An image forming device comprising:

the electrophotographic photoreceptor of claim 13;

a charging device that charges the electrophotographic photoreceptor;

a latent image forming device that forms a latent image on the surface of the charged electrophotographic photoreceptor;

a developing device that develops the latent image formed on the surface of the electrophotographic photoreceptor with a developer including a toner; and

a transfer device that transfers the toner image formed on the surface of the electrophotographic photoreceptor to a recording medium.