Cantilevered probe detector with piezoelectric element

• US 8,713,711 B2
• Filed: 03/15/2013
• Issued: 04/29/2014
• Est. Priority Date: 10/01/2004
• Status: Active Grant

• Current Assignee: Board of Regents Nevada System of Higher Education (State of Nevada)
• Original Assignee: Board of Regents Nevada System of Higher Education (State of Nevada)
• Inventors: Adams, Jesse D., Sulchek, Todd A., Feigin, Stuart C.
• Primary Examiner(s): Berman, Jack
• Assistant Examiner(s): SAHU, MEENAKSHI S
• Application Number:
  US13/833,410
• Publication Number:
  US 20140079093A1
• Time in Patent Office: 410 Days
• Field of Search: 250/234, 250/288, 422/50, 422/82.01, 422/68.01, 436/183, 436/164, 850/7, 850/9, 850/10, 850/56, 850/57, 850/59
• US Class Current: 850/56
• CPC Class Codes: G01N 2291/0257 with a layer containing at least one organic compound
• CPC Class Codes: G01N 25/00 Investigating or analyzing materials by the use of thermal means G01N3/00 - G01N23/00 take precedence
• CPC Class Codes: G01N 27/007 by investigating the electric dipolar moment measuring piezoelectric properties G01R29/22
• CPC Class Codes: G01N 29/022 Fluid sensors based on microsensors, e.g. quartz crystal-microbalance [QCM], surface acoustic wave [SAW] devices, tuning forks, cantilevers, flexural plate wave [FPW] devices microdevices per se B81B
• CPC Class Codes: G01N 29/036 by measuring frequency or resonance of acoustic waves
• CPC Class Codes: G01N 33/0031 comprising two or more sensors, e.g. a sensor array electrochemical electrode arrays G01N27/27
• CPC Class Codes: G01N 33/0057 for warfare agents or explosives properties of explosives G01N33/227
• CPC Class Codes: G01N 33/227 Explosives, e.g. combustive properties thereof detecting explosives in air G01N33/0057

Abstract

A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

Claims

1. A method for analyzing one or more chemical species samples, the method comprising:

exposing a sensor probe in a chemical analysis system to one or more chemical species samples, the sensor probe comprising an integral resistive heater, a temperature sensing element, and a surface for contacting the one or more chemical species samples;

heating the sensor probe to cause a change with the one or more chemical species samples;

analyzing responses received from the sensor probe after interaction of the sensor probe with the heated one or more chemical species samples;

detecting, identifying, and/or characterizing the one or more chemical species samples based on analyzing the responses from the sensor probe.

2. The method of claim 1 wherein the sensor probe is a cantilever.

3. The method of claim 1 wherein the integral resistive heater and the temperature sensing element are unitary.

4. The method of claim 1 wherein at least one response received from the sensor probe includes a temperature shift response received from the temperature sensing element.

5. The method of claim 1 wherein analyzing responses received from the sensor probe includes comparing the sensor probe response to a response from a reference probe.

6. The method of claim 5 wherein the reference probe is isolated from exposure to the one or more chemical species samples.

7. The method of claim 5 wherein comparing the responses from the sensor probe and the reference probe comprises an indication of an exothermic or endothermic reaction during heating of the one or more chemical species samples.

8. The method of claim 1 wherein the one or more chemical species samples comprises any of the following, either singly or in combination including derivatives thereof:

mercury, hydrogen, an alcohol, water vapor, an explosive material, a chemical element, a chemical compound, an organic material, an inorganic material, a gaseous substance, a liquid, a biological material, a DNA strand, a bioactive agent, or a toxin.

9. The method of claim 1 wherein one or more additional sensor probes, together with the sensor probe, form an array of sensor probes;

and wherein the additional sensor probes interact with the one or more chemical species samples.

10. The method of claim 9 wherein the sensor probes that form the array are connected in parallel.

11. The method of claim 9 wherein the sensor probes that form the array are connected in series.

12. The method of claim 9 wherein the sensor probes that form the array are connected in a matrix form of rows and columns.

13. The method of claim 1 wherein the response received from the sensor probe comprises an indication of an exothermic or endothermic reaction during heating of the one or more chemical species samples.

14. The method of claim 1 wherein heating the sensor probe includes heating the sensor probe across a temperature range to cause a change with the one or more chemical species samples.

15. The method of claim 1 wherein the sensor probe defines one of a rectangular-shaped cantilever, pointed cantilever, V-shaped cantilever, triangular-shaped cantilever, dual-arm cantilever, or balanced cantilever.

16. The method of claim 1 wherein the sensor probe includes a piezoelectric element, and the method further comprising:

exciting the piezoelectric element of the sensor probe with a drive voltage;

detecting a shifted response from the sensor probe as a result of a mass loading of the one or more chemical species samples on the sensor probe; and

based on the shifted response, determining a mass of the one or more chemical species samples accumulated on the sensor probe.

17. The method of claim 16 wherein the mass of the one or more chemical species samples is determined throughout the analysis to measure changes in mass.

18. A chemical sensor system for analyzing one or more chemical species samples, the system comprising:

a sensor probe having a surface that contacts one or more chemical species samples, a temperature sensing element, and an integral resistive heater that heats the sensor probe so as to cause a change with the one or more chemical species samples;

wherein the system is configured to analyze responses received from the sensor probe after interaction of the sensor probe with the heated one or more chemical species samples and wherein the system is further configured to detect, identify, and/or characterize the one or more chemical species samples based on analysis of the responses received from the sensor probe.

19. The system of claim 18 wherein one or more additional sensor probes, together with the sensor probe, form an array of sensor probes,

wherein the additional sensor probes interact with the one or more chemical species samples, and

wherein the sensor probes that form the array are connected in a matrix form of rows and columns.

20. The system of claim 18 wherein the sensor probe is heated across a temperature range so as to cause a change with the one or more chemical species samples.