Production of high solids syrup from lignocellulosic biomass hydrolysate fermentation broth

• US 8,721,794 B2
• Filed: 04/25/2011
• Issued: 05/13/2014
• Est. Priority Date: 04/28/2010
• Status: Expired due to Fees

• Current Assignee: Sustainable Technology Corporation
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Hennessey, Susan Marie, Kasat, Rahul B.
• Primary Examiner(s): DRODGE, JOSEPH W
• Application Number:
  US13/093,118
• Publication Number:
  US 20120102823A1
• Time in Patent Office: 1,114 Days
• Field of Search: 210/632, 210/634, 210/770, 210/774, 210/805, 210/806, 159/47.1, 203/39, 203/43, 203/47, 203/98, 127/30, 127/46.1, 127/53, 127/55, 127/57, 127/29, 127/32, 127/33, 127/36, 127/37, 426/61, 426/429, 426/489, 426/658, 435/61, 435/136, 435159-165, 568/913, 568/916, 443/07, 446/05, 446/06, 424/130.1, 424/725, 424/769, 424/780
• US Class Current: 127/29
• CPC Class Codes: C10L 1/00 Liquid carbonaceous fuels
• CPC Class Codes: C10L 7/02 liquid fuels lubricating compositions C10M
• CPC Class Codes: C12P 7/10 substrate containing cellulosic material
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02P 20/582 Recycling of unreacted starting or intermediate materials

Abstract

Lignocellulosic biomass hydrolysate fermentation broth may be processed to produce a high solids syrup having relatively low viscosity that has a high energy content and may be burned in a fermentation production process. The high solids syrup was achieved through liquid/solid separation of broth or depleted broth producing a thin stillage with low suspended solids allowing evaporation to high solids while maintaining low viscosity.

Claims

1. A syrup comprising at least about 40% solids by weight and having a viscosity that is less than about 100 centipoise, and derived from stillage comprising less than about 0.1% suspended solids;

wherein the syrup is the product of evaporation of the liquid fraction from a liquid/solid separation of lignocellulosic biomass hydrolysate fermentation broth or product depleted lignocellulosic biomass hydrolysate fermentation broth.

2. The syrup of claim 1 wherein the lignocellulosic biomass hydrolysate fermentation broth comprises a target product selected from the group consisting of acids, alcohols, alkanes, alkenes, aromatics, aldehydes, ketones, biopolymers, proteins, peptides, amino acids, vitamins, antibiotics, and pharmaceuticals.

3. The syrup of claim 2 wherein the target compound is selected from the group consisting of ethanol, butanol and 1,3-propanediol.

4. The syrup of claim 1 wherein the lignocellulosic biomass hydrolysate fermentation broth is produced from biomass that is selected from the group consisting of switchgrass, waste paper, sludge from paper manufacture, corn cobs, corn husks, corn stover, grasses, wheat, wheat straw, hay, barley straw, rice straw, sugar cane bagasse, components obtained from processing of grains, trees, branches, roots, leaves, wood chips, sawdust, shrubs and bushes, vegetables, fruits, and flowers.

5. The syrup of claim 1 wherein the percent solids is at least about 45%.

6. The syrup of claim 1 wherein the percent solids is at least about 50%.

7. A process for the production of a target product comprising:

a) providing a lignocellulosic biomass hydrolysate fermentation broth comprising a target product;

b) removing the target product from the lignocellulosic biomass hydrolysate fermentation broth of (a) by distillation to produce whole stillage;

c) separating liquid and solid fractions from the whole stillage of (b) to produce a thin stillage comprising less than about 0.1% suspended solids by weight; and

d) evaporating the thin stillage of (c) to produce a syrup comprising at least about 40% solids by weight and having a viscosity that is less than about 100 centipoise.

8. The process of claim 7 wherein the target product is selected from the group consisting of ethanol, butanol and 1,3-propanediol.

9. The process of claims 7 wherein the syrup is burned without further drying.

10. The process of claim 7 wherein water from evaporating the thin stillage is recycled.

11. The process of claim 7 wherein the lignocellulosic biomass hydrolysate fermentation broth of (a) or the depleted broth or whole stillage of (b) has a pH of about 6 or lower.

12. The process of claim 7 wherein the lignocellulosic biomass hydrolysate fermentation broth of (a) or the depleted broth or whole stillage of (b) is treated with heat for between about 30 seconds and about 210 minutes at a temperature that is between about 70°

C. and about 150°

C., with time and temperature inversely related.

13. The process of claim 7 wherein the lignocellulosic biomass hydrolysate fermentation broth is produced from biomass selected from the group consisting of switchgrass, waste paper, sludge from paper manufacture, corn cobs, corn husks, corn stover, grasses, wheat, wheat straw, hay, barley straw, rice straw, sugar cane bagasse, components obtained from processing of grains, trees, branches, roots, leaves, wood chips, sawdust, shrubs and bushes, vegetables, fruits, and flowers.

14. The process of claim 7 wherein the percent solids of the syrup is at least about 45%.

15. The process of claim 7 wherein the percent solids of the syrup is at least about 50%.