Process for CO 2 capture using carbonates and biocatalysts with absorption of CO 2 and desorption of ion-rich solution

• US 8,722,391 B2
• Filed: 08/04/2010
• Issued: 05/13/2014
• Est. Priority Date: 08/04/2009
• Status: Active Grant

• Current Assignee: Saipem SPA (Saipem)
• Original Assignee: CO2 Solutions Inc.
• Inventors: Fradette, Sylvie, Gingras, Julie, Carley, Jonathan, Kelly, Glenn R., Ceperkovic, Olivera
• Primary Examiner(s): GITOMER, RALPH J
• Application Number:
  US13/388,871
• Publication Number:
  US 20120129246A1
• Time in Patent Office: 1,378 Days
• Field of Search: 435/266
• US Class Current: 435/266
• CPC Class Codes: B01D 2251/206 Ammonium compounds
• CPC Class Codes: B01D 2251/304 of sodium
• CPC Class Codes: B01D 2251/306 of potassium
• CPC Class Codes: B01D 2251/606 Carbonates
• CPC Class Codes: B01D 2252/20494 Amino acids, their salts or derivatives
• CPC Class Codes: B01D 2252/205 Other organic compounds not covered by B01D2252/00 - B01D2252/20494
• CPC Class Codes: B01D 2252/602 Activators, promoting agents, catalytic agents or enzymes
• CPC Class Codes: B01D 2255/804 Enzymatic
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/84 Biological processes
• CPC Class Codes: B01D 53/96 Regeneration, reactivation or recycling of reactants
• CPC Class Codes: C12N 9/88 Lyases (4.)
• CPC Class Codes: C12Y 402/01001 Carbonate dehydratase (4.2.1.1), i.e. carbonic anhydrase
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02P 20/59 Biological synthesis; Biological purification

Abstract

A formulation and process for capturing CO₂ use an absorption mixture containing water, biocatalysts and a carbonate compound. The process includes contacting a CO₂-containing gas with the absorption mixture to enable dissolution and transformation of CO₂ into bicarbonate and hydrogen ions, thereby producing a CO₂-depleted gas and an ion-rich solution, followed by subjecting the ion-rich solution to desorption. The biocatalyst improves absorption of the mixture comprising carbonate compounds and the carbonate compound promotes release of the bicarbonate ions from the ion-rich solution during desorption, producing a CO₂ gas stream and an ion-depleted solution.

Claims

1. A process for capturing CO₂ from a CO₂-containing gas comprising:

contacting the CO₂-containing gas with an absorption mixture comprising water, carbonic anhydrase and a carbonate compound to enable dissolution and transformation of CO₂ into bicarbonate and hydrogen ions, thereby producing a CO₂-depleted gas and an ion-rich solution, the carbonate compound being selected and used in a sufficient amount in the absorption mixture such that the ion-rich solution contains bicarbonate precipitates; and

subjecting the ion-rich solution to desorption wherein the carbonate compound promotes release of the bicarbonate ions from the ion-rich solution producing a CO₂ gas stream and an ion-depleted solution.

2. The process of claim 1, comprising removing the carbonic anhydrase from the ion-rich solution prior to subjecting the ion-rich solution to the desorption.

3. The process of claim 1, comprising removing the carbonic anhydrase from the ion-rich solution after subjecting the ion-rich solution to the desorption.

4. The process of claim 2, comprising recycling the ion-lean solution to form at least a part of the absorption mixture for re-contacting the CO₂-containing gas.

5. The process of claim 2, comprising adding an amount of carbonic anhydrase into the ion-depleted solution to convert the solution into at least part of the absorption mixture for recycling to contact the CO₂-containing gas.

6. The process of claim 1, comprising removing the bicarbonate precipitates from the absorption mixture prior to subjecting the ion-rich solution to the desorption.

7. The process of claim 1, wherein the bicarbonate precipitates remain in the ion-rich solution upon subjecting the ion-rich solution to the desorption, thereby converting into part of the CO₂ gas stream.

8. The process of claim 1, wherein the bicarbonate precipitates are composed of bicarbonate species comprising potassium bicarbonate, sodium bicarbonate, ammonium bicarbonate, or a mixture thereof.

9. The process of claim 1, wherein the carbonate compound comprises potassium carbonate, sodium carbonate or ammonium carbonate, or a combination thereof.

10. The process of claim 1, wherein the absorption mixture comprises an additional absorption compound, comprising piperidine, piperazine and derivatives thereof which are substituted by at least one alkanol group, alkanolamines, monoethanolamine (MEA), 2-amino-2-methyl-1-propanol (AMP), 2-(2-aminoethylamino)ethanol (AEE), 2-amino-2-hydroxymethyl-1,3-propanediol (Tris), amino acids, potassium or sodium salts of amino acids, glycine, proline, arginine, histidine, lysine, aspartic acid, glutamic acid, methionine, serine, threonine, glutamine, cysteine, asparagine, leucine, isoleucine, alanine, tyrosine, tryptophan, phenylalanine, and derivatives, taurine, N,cyclohexyl 1,3-propanediamine, N-secondary butyl glycine, N-methyl N-secondary butyl glycine, diethylglycine, dimethylglycine, sarcosine, methyl taurine, methyl-α

-aminopropionic acid, N-(β

-ethoxy)taurine, N-(β

-aminoethy)taurine, N-methyl alanine, 6-aminohexanoic acid, or a combination thereof.

11. The process of claim 1, wherein contacting the absorption mixture with the CO₂-containing gas is performed in an absorption stage comprising at least one reactor selected from a packed tower, a vertical or horizontal spray scrubber, a fluidized bed reactor or a series of reactors comprising the same.

12. The process of claim 1, wherein a sufficient level of CO₂ loading is provided when producing the ion-rich solution to promote the precipitation of bicarbonate precipitates.

13. The process of claim 1, wherein the carbonate compound and carbonic anhydrase are provided in concentrations to achieve a maximum range of relative CO₂ transfer rate, with respect to a CO₂ transfer rate without carbonic anhydrase.

14. The process of claim 1, wherein the carbonate compound is provided in the absorption mixture in a concentration of at least about 0.1 M.

15. The process of claim 1, wherein the carbonate compound is provided in the absorption mixture in a concentration at or below saturation thereof.

16. The process of claim 1, wherein the carbonate compound comprises potassium carbonate and is provided in the absorption mixture in a concentration up to the solubility limit at a temperature range between about 40°

C. and about 70°

C.

17. The process of claim 1, wherein the carbonate compound comprises ammonium carbonate and is provided in the absorption mixture in a concentration up to the solubility limit at a temperature range between about 10°

C. and about 70°

C.

18. The process of claim 1, wherein the carbonate compound comprises sodium carbonate and is provided in the absorption mixture in a concentration up to the solubility limit at a temperature range between about 40°

C. and about 70°

C.

19. The process of claim 1, wherein the carbonic anhydrase is provided free in the water;

dissolved in the water;

immobilized on the surface of supports that are mixed in the water and are flowable therewith;

entrapped or immobilized by or in porous supports that are mixed in the water and are flowable therewith;

as cross-linked aggregates or crystals;

or a combination thereof.

20. The process of claim 1, wherein the carbonic anhydrase is supported by micro-particles that are carried with the water.