Out coupling layer containing particle polymer composite

• US 8,723,209 B2
• Filed: 08/15/2012
• Issued: 05/13/2014
• Est. Priority Date: 04/27/2012
• Status: Active Grant

• Current Assignee: Universal Display Corporation
• Original Assignee: Universal Display Corporation
• Inventors: Xia, Chuanjun, Ma, Ruiqing
• Primary Examiner(s): Maldonado, Julio J
• Assistant Examiner(s): BACHNER, ROBERT G
• Application Number:
  US13/586,724
• Publication Number:
  US 20130285088A1
• Time in Patent Office: 636 Days
• Field of Search: 977890-901, 438480-490, 257/E51.001
• US Class Current: 257/98
• CPC Class Codes: H10K 2102/331 Nanoparticles used in non-emissive layers, e.g. in packaging layer
• CPC Class Codes: H10K 50/854 comprising scattering means
• CPC Class Codes: H10K 50/858 comprising refractive means, e.g. lenses

Abstract

Light emitting devices comprising an optical layer comprising metal oxide particles having a polymer covalently bonded thereto and a light emitting layer, which is in optical communication with the optical layer are provided. Methods of fabricating a light emitting devices comprising: depositing an optical layer comprising metal oxide particles having a polymer covalently bonded thereto; and depositing a light emitting layer, which is in optical communication with the optical layer are also provided.

Claims

1. A method of fabricating a light emitting device, comprising:

depositing an optical layer comprising metal oxide particles having a polymer covalently bonded thereto; and

depositing a light emitting layer, which is in optical communication with the optical layer.

2. The method of claim 1, wherein the optical layer comprises a scattering layer.

3. The method of claim 2, wherein the scattering layer comprises scattering centers dispersed in a polymer matrix.

4. The method of claim 3, wherein the scattering centers comprise metal oxide particles.

5. The method of claim 4, wherein metal oxide particles are selected from the group consisting of indium tin oxide (ITO), SnO₂, Sb₂O₃, TiO₂, ZrO₂, Ta₂O₅, HfO₂, Nb₂O₃, MgO, ZnO, and In₂O₃.

6. The method of claim 4, wherein metal oxide particles are selected from the group consisting of TiO₂, ZrO₂, and SnO₂.

7. The method of claim 3, wherein the scattering centers have a particle size that ranges from λ

min/4n to 4*λ

max/n, wherein λ

min is the minimum wavelength of light emitted by the light emitting layer, λ

max is the maximum wavelength of light emitted by the light emitting layer, and n is the index of refraction of the optical layer.

8. The method of claim 3, wherein the scattering centers comprise a first set of scattering centers and a second set of scattering centers, wherein the scattering centers in the first set of scattering centers have an average particle size of greater than 50 nm, and wherein the scattering centers in the second set of scattering centers have an average particle size of less than 50 nm.

9. The method of claim 1, wherein the optical layer is solution deposited from a solution comprising:

metal oxide particles having a polymer covalently bonded thereto, and

a solvent in which the polymer is soluble.

10. The method of claim 9, wherein the metal oxide particles having a polymer covalently bonded thereto are formed by:

covalently bonding an initiator to the metal oxide particles to form an initiator bound metal oxide particles;

reacting the initiator bound metal oxide particles in solution with monomers, wherein the reaction is initiated by the initiator that is bound to the metal oxide particles.

11. The method of claim 9, wherein the metal oxide particles having a polymer covalently bonded thereto are formed by:

forming polymers that comprise reactive groups;

reacting the polymers in solution with the metal oxide particles, wherein the metal oxide particles have organic compounds bound to their surface and the reactive groups of the polymers react with the organic compounds to covalently bind the polymers to the metal oxide particles.

12. The method of claim 1, wherein the method comprises depositing, in order over a substrate:

the optical layer;

a first electrode;

a light emitting layer comprising a small molecule light emitting material; and

a second electrode;

wherein the first electrode is at least partially transparent.

13. The method of claim 12, wherein the method further comprises depositing a planarization layer after depositing the optical layer and before depositing the first electrode.

14. The method of claim 13, wherein the planarization layer is composed of:

a polymer having a first refractive index and a first volume share; and

particles having a second refractive index and a second volume share; and

wherein the refractive index of the planarization layer is within 10% of the sum of the first refractive index multiplied by the first volume share and the second refractive index multiplied by the second volume share.

15. The method of claim 12, wherein the method further comprises depositing a barrier layer after depositing the second electrode and before depositing the optical layer.

16. A light emitting device, comprising:

an optical layer comprising metal oxide particles having a polymer covalently bonded thereto; and

a light emitting layer, which is in optical communication with the optical layer.

17. A light emitting device fabricated by the process of:

depositing an optical layer comprising metal oxide particles having a polymer covalently bonded thereto;

depositing a light emitting layer, which is in optical communication with the optical layer.