Variable transmittance element, optical system, and optical apparatus utilizing electrochromic material

• US 8,730,554 B2
• Filed: 10/11/2012
• Issued: 05/20/2014
• Est. Priority Date: 10/12/2011
• Status: Active Grant

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Ushigome, Reona
• Primary Examiner(s): CHOI, WILLIAM C
• Application Number:
  US13/649,192
• Publication Number:
  US 20130094073A1
• Time in Patent Office: 586 Days
• Field of Search: 359265-275
• US Class Current: 359/275
• CPC Class Codes: G02F 1/1524 Transition metal compounds
• CPC Class Codes: G02F 1/157 Structural association of cells with optical devices, e.g. reflectors or illuminating devices

Abstract

A variable transmittance element includes two substrates, two transparent electrode layers held between the two substrates, an electrochromic layer held between the two transparent electrode layers and having transmittance that is reversibly changed by electric control, and a first dielectric layer provided between one of the two substrates and one of the two transparent electrode layers closest to the one of the two substrates and configured to reduce reflections. The first dielectric layer is a multilayer film made by alternately laminating two or more layers each having a high refractive index and two or more layers each having a low refractive index, a refractive index difference for a wavelength of 550 nm between the layer having the high refractive index and the layer having the low refractive index being 0.2 or more.

Claims

1. A variable transmittance element comprising:

two substrates;

two transparent electrode layers held between the two substrates;

an electrochromic layer held between the two transparent electrode layers and having transmittance that is reversibly changed by electric control; and

a first dielectric layer provided between one of the two substrates and one of the two transparent electrode layers closest to the one of the two substrates and configured to reduce reflections,

wherein the first dielectric layer is a multilayer film made by alternately laminating two or more layers each having a high refractive index and two or more layers each having a low refractive index, a refractive index difference for a wavelength of 550 nm between the layer having the high refractive index and the layer having the low refractive index being 0.2 or more.

2. The variable transmittance element according to claim 1, wherein another first dielectric layer is located between the other of the two substrates and the other of the two transparent electrode layers closest to the other of the two substrates.

3. The variable transmittance element according to claim 1, wherein the layer having the high refractive index has a refractive index equal to or higher than 1.6.

4. The variable transmittance element according to claim 1, wherein the layer having the low refractive index has a refractive index equal to or lower than 1.7.

5. The variable transmittance element according to claim 1, wherein one of the layers having the high refractive index is physically thinner than a neighboring one of the layers having the low refractive index.

6. The variable transmittance element according to claim 1, wherein a film thickness of the transparent electrode layer is located between 10 nm and 300 nm.

7. The variable transmittance element according to claim 1, further comprising a second dielectric layer located between the electrochromic layer and one of the two transparent electrode layers closest to the electrochromic layer and configured to reduce reflections, a refractive index difference for the wavelength of 550 nm being 0.3 or more between the electrochromic layer and the transparent electrode layer.

8. The variable transmittance element according to claim 7, wherein a refractive index of the second dielectric layer for the wavelength of 550 nm is located between refractive indexes for the wavelength of 550 nm of both sides of the second dielectric layer.

9. The variable transmittance element according to claim 7, wherein the second dielectric layer is made of a conductive material.

10. The variable transmittance element according to claim 9, wherein the second dielectric layer satisfies the following expression:

0<

Σ

_iρ

_id_i≦

100 Ω

cm²

where ρ

_i is electric resistivity [Ω

cm] of an i-th second dielectric layer between the transparent electrode layers, and d_i is a film thickness [cm] of an i-th antireflective layer between the transparent electrode layers.

11. The variable transmittance element according to claim 7, wherein the second dielectric layer is a single layer.

12. The variable transmittance element according to claim 7, wherein the second dielectric layer is made of the same composition as that of the electrochromic layer.

13. The variable transmittance element according to claim 7, wherein the following expression is satisfied:

1/6<

nd/λ

₀<

1/3

where n is a refractive index for a wavelength λ

₀, d is a film thickness of the second dielectric layer, and λ

₀ is 550 nm.

14. The variable transmittance element according to claim 7, wherein each of the electrochromic layer and the second dielectric layer is made of titanium oxide.

15. The variable transmittance element according to claim 1, further comprising:

an electrolyte layer that is transparent in a visible range and held between the two transparent electrode layers; and

a second dielectric layer located between the electrochromic layer and the electrolyte layer and configured to reduce reflections.

16. The variable transmittance element according to claim 1, wherein the electrochromic layer is made of an organic material, which contains an electrochromic site having an electrochromic characteristic and an aromatic ring that is directly combined with the electrochromic site, and

wherein the electrochromic site forms one conjugate plane, and an atom of the aromatic ring which neighbors an atom united with the electrochromic site may have a substituent having a volume equal to or larger than a methyl group.

17. The variable transmittance element according to claim 1, wherein transmittance of the variable transmittance element in a decolored state satisfies the following expression:

0.9<

T(λ

_v±

20 nm)/T(λ

_v)<

1.1

where T(λ

_v) denotes the transmittance of the variable transmittance element for a wavelength λ

_v, and λ

_v is an arbitrary wavelength contained in a visible wavelength band between 420 and 680 nm.

18. The variable transmittance element according to claim 1, wherein the variable transmittance element has reflectance of 5% or less in a decolored state in a whole visible range and satisfy the following expression:

0.5<

R(λ

_v±

20 nm)/R(λ

_v)<

2.0

where R(λ

_v) is the reflectance of the variable transmittance element for a wavelength λ

_v, and λ

_v is an arbitrary wavelength contained in a visible wavelength band between 420 and 680 nm.

19. An optical system comprising a variable transmittance element according to claim 1.

20. An optical apparatus comprising an optical system according to claim 19.