Processes for preparing a catalyzed carbonaceous particulate

• US 8,734,547 B2
• Filed: 12/29/2009
• Issued: 05/27/2014
• Est. Priority Date: 12/30/2008
• Status: Active Grant

• Current Assignee: Sure Champion Investments Limited
• Original Assignee: GreatPoint Energy, Inc.
• Inventors: Rappas, Alkis S., Spitz, Robert A.
• Primary Examiner(s): Warden, Jill
• Assistant Examiner(s): TAVARES, JULIE L
• Application Number:
  US12/648,469
• Publication Number:
  US 20100168495A1
• Time in Patent Office: 1,610 Days
• Field of Search: None
• US Class Current: 48/127.7
• CPC Class Codes: C10J 2300/0903 Feed preparation
• CPC Class Codes: C10J 2300/0916 Biomass
• CPC Class Codes: C10J 2300/0943 Coke
• CPC Class Codes: C10J 2300/0973 Water
• CPC Class Codes: C10J 2300/0986 Catalysts
• CPC Class Codes: C10J 2300/1807 Recycle loops, e.g. gas, solids, heating medium, water
• CPC Class Codes: C10J 2300/1853 Steam reforming, i.e. injection of steam only
• CPC Class Codes: C10J 3/00 Production of combustible gases containing carbon monoxide from solid carbonaceous fuels destructive distillation processes C10B
• CPC Class Codes: C10J 3/482 Gasifiers with stationary fluidised bed
• CPC Class Codes: C10L 3/08 Production of synthetic natural gas
• CPC Class Codes: C10L 9/08 by heat treatments, e.g. calcining
• CPC Class Codes: Y02P 20/52 using catalysts, e.g. selective catalysts

Abstract

Processes are provided for preparing a substantially free-flowing alkali metal gasification catalyst-loaded carbonaceous particulate suitable for use as a feedstock for the production of gaseous products, and in particular methane, via the catalytic gasification of the catalyst-loaded carbonaceous particulate in the presence of steam.

Claims

1. A process for preparing a substantially free-flowing alkali metal gasification catalyst-loaded carbonaceous particulate from a carbonaceous feedstock, the process comprising the steps of:

(A) providing a carbonaceous feedstock having an initial moisture content;

(B) grinding the carbonaceous feedstock;

(C) classifying the carbonaceous feedstock from step (B) to a specified particle size profile to produce a carbonaceous particulate;

(D) contacting the carbonaceous particulate with an amount of an aqueous solution comprising a concentration of an alkali metal gasification catalyst, to form an alkali metal gasification catalyst-loaded carbonaceous particulate wet cake having a specified ratio of alkali metal atoms to carbon atoms and a second moisture content; and

(E) thermally treating the alkali metal gasification catalyst-loaded carbonaceous particulate wet cake as required to reduce the second moisture content to produce the alkali metal gasification catalyst-loaded carbonaceous particulate as a substantially free-flowing particulate,

wherein;

(a) the specified particle size profile has a d5 particle size of at least about 20 microns, a d95 particle size of about 1000 microns or less, and a d50 particle size ranging from about 75 to about 350 microns;

(b) the specified ratio of alkali metal atoms to carbon atoms of step (D) is sufficient to provide an alkali metal atoms to carbon atoms ratio in the substantially free-flowing alkali metal gasification catalyst-loaded carbonaceous particulate of from about 0.01 to about 0.10;

(c) the amount of aqueous solution and the concentration of the alkali metal gasification catalyst in step (D) are sufficient to provide the specified ratio of alkali metal atoms to carbon atoms in the alkali metal gasification catalyst-loaded carbonaceous particulate wet cake,

(d) the alkali metal gasification catalyst-loaded carbonaceous particulate wet cake resulting from step (D) is substantially non-draining;

(e) the contacting in step (D) takes place at substantially atmospheric pressure, and at an elevated temperature substantially at or below the boiling point of the aqueous solution, under agitation and for a specified amount of time, each of which is in an amount sufficient in combination to allow substantially even distribution of the alkali metal gasification catalyst within the non-draining alkali metal gasification catalyst-loaded carbonaceous particulate wet cake; and

(f) the non-draining alkali metal gasification catalyst loaded carbonaceous particulate wet cake exits step (D) at a first temperature, and is passed into the thermal treating step (E) at substantially the same temperature.

2. The process according to claim 1, wherein the grinding step (B) is a dry grinding step.

3. The process according to claim 2, wherein the initial moisture content of the carbonaceous feedstock is reduced so that, when taking into account the amount of aqueous solution used in step (D), the wet cake resulting from step (D) is substantially non-draining.

4. The process according to claim 3, wherein the carbonaceous feedstock is dried concurrently with dry grinding.

5. The process according to claim 1, wherein the grinding step (B) is a wet grinding step that results in a wet ground carbonaceous feedstock.

6. The process of claim 5, where the moisture content of the wet ground carbonaceous feedstock is reduced so that, when taking into account the amount of aqueous solution used in step (D), the wet cake resulting from step (D) is substantially non-draining.

7. The process according to claim 1, wherein the carbonaceous feedstock comprises one or more of an anthracite, bituminous coal, sub-bituminous coal, lignite, petroleum coke or biomass.

8. The process according to 1, wherein the alkali metal comprises potassium, sodium or both.

9. The process according to claim 1, wherein the wet cake is non-draining.

10. The process according to claim 1, wherein the contacting of step (D) is performed at a temperature of from about 80°

C. and about 100°

C.

11. The process according to claim 1, wherein the contacting of step (D) takes place for a period of time ranging from about 5 minutes to about 60 minutes.