Transparent electrochromic system

• US 8,736,944 B2
• Filed: 07/19/2010
• Issued: 05/27/2014
• Est. Priority Date: 07/28/2009
• Status: Active Grant

• Current Assignee: Essilor International SA
• Original Assignee: Essilor International SA
• Inventors: Biver, Claudine, Cano, Jean-Paul, Duluard, Sandrine, Saugey, Anthony
• Primary Examiner(s): PINKNEY, DAWAYNE
• Application Number:
  US13/386,878
• Publication Number:
  US 20120120477A1
• Time in Patent Office: 1,408 Days
• Field of Search: 349182-186, 359265-275, 359/277, 359245-247, 359/254, 359/242, 345/49, 345/105, 250/70, 348/814, 348/817
• US Class Current: 359/275
• CPC Class Codes: G02F 1/133377 Cells with plural compartments or having plurality of liquid crystal microcells partitioned by walls, e.g. one microcell per pixel
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: G02F 2001/15145 the electrochromic layer comprises a mixture of anodic and cathodic compounds
• CPC Class Codes: G02F 2001/1557 Side by side arrangements of working and counter electrodes

Abstract

A transparent electrochromic system includes a cellular structure, two power supply electrodes together supported on a single wall, and at least one additional electrode. The additional electrode can be used as a reference electrode or as a polarization electrode. The additional electrode can also form a condenser with a fourth electrode that is added to the system, in order to control a migration of certain electroactive substances responsible for coloring and decoloring the system. The operation of the system can thus be improved.

Claims

1. A transparent electrochromic system, allowing clear vision across said system, and comprising:

parallel first and second outer walls, the system being transparent for a viewing direction across the outer walls between two opposite sides;

a network of internal walls placed between the outer walls, said internal walls extending perpendicularly to said outer walls and defining a set of cells juxtaposed in parallel to said outer walls;

portions of liquid and/or gel contained respectively in the cells;

first and second electroactive substances distributed in the portions of liquid and/or gel, with respective electrical redox potentials that are different, at least some of the first and second electroactive substances having a variable optical effect between an oxidized form and a reduced form of said substances;

two transparent power supply electrodes carried together by the first outer wall, and configured to be connected respectively to two power supply terminals of a variable electrical power supply unit, each of said power supply electrodes being in direct electrical contact with the portions of liquid and/or gel contained in at least some of the cells for transferring electrons to or from at least some of the electroactive substances, in an inverse way between said first and second electroactive substances at a given time; and

a first additional transparent electrode without direct electrical contact with said power supply electrodes inside the electrochromic system, said first additional transparent electrode being parallel to said power supply electrodes inside at least some of the cells.

2. The system as claimed in claim 1, further comprising, for at least some of the cells, an electrically insulating film placed between the first additional transparent electrode and the portion of liquid and/or gel contained in each of said cells, so as to prevent contact between said portion of liquid and/or gel and the first additional transparent electrode.

3. The system as claimed in claim 1, in which the first additional transparent electrode is carried by the second outer wall.

4. The system as claimed in claim 3, in which the first additional transparent electrode extends continuously between two adjacent cells along directions parallel to the outer walls.

5. The system as claimed in claim 4, in which the first additional transparent electrode extends without interruption facing at least a portion of all of the cells.

6. The system as claimed in claim 4, in which the first additional transparent electrode has an opening aligned with a central portion of at least some of the cells, along a direction perpendicular to the outer walls.

7. The system as claimed in claim 1, in which the first additional transparent electrode is carried by the first outer wall, and is placed between said two power supply electrodes along a direction parallel to said first outer wall.

8. The system as claimed in claim 7, in which the first additional transparent electrode and the power supply electrodes have identical constituent materials.

9. The system as claimed in claim 7, in which the first additional transparent electrode extends continuously between two adjacent cells, and is located between the internal wall separating said adjacent cells and the first outer wall.

10. The system as claimed in claim 9, in which the first additional transparent electrode has projections on each side of the internal wall separating said adjacent cells, said projections having extensions greater than 2 μ

m perpendicular to said internal wall.

11. The system as claimed in claim 7, further comprising portions of an insulating and transparent material carried by the first outer wall, between the first additional transparent electrode and each of the power supply electrodes, so that the system substantially has the same optical thickness along a direction perpendicular to the outer walls, across said portions of insulating and transparent material.

12. The system as claimed in claim 7, further comprising quantities of an absorbing material carried by the first outer wall, said quantities of absorbing material being located between said first additional transparent electrode and each of the power supply electrodes.

13. The system as claimed in claim 2, in which the first additional transparent electrode is carried by the first outer wall and is placed between said first outer wall and said two power supply electrodes, along a direction perpendicular to the first outer wall, the insulating film further being placed between said first additional transparent electrode and each of said power supply electrodes.

14. The system as claimed in claim 1, further comprising a second additional transparent electrode carried by the first outer wall, which said first additional transparent electrode is carried by the second outer wall.

15. The system as claimed in claim 14, further comprising, for at least some of the cells, an electrically insulating film placed between the second additional transparent electrode and the portion of liquid and/or gel contained in each of said cells, so as to prevent contact between said portion of liquid and/or gel and said second additional transparent electrode.

16. The system as claimed in claim 1, in which the portions of liquid and/or gel contained in at least some of the cells are each in direct electrical contact with the two power supply electrodes inside the corresponding cells.

17. The system as claimed in claim 1, in which the two power supply electrodes are placed so that each portion of liquid and/or gel contained in a cell is in direct electrical contact with only one of said power supply electrodes, and so that each cell electrically supplied by one of the two power supply electrodes is adjacent to at least one other cell electrically supplied by the other power supply electrode, and the system further comprising an ionic bridge connecting said adjacent cells.

18. The system as claimed in claim 17, in which the first additional transparent electrode is carried by the second outer wall and at least some of the internal walls extend to the first additional transparent electrode, along a direction perpendicular to the outer walls, so that said internal walls prevent electroactive species which are located close to said first additional transparent electrode from passing from a cell to an adjacent cell.

19. The system as claimed in claim 1, further comprising an electrical power supply unit having first, second, and third output terminals, said first and second output terminals being connected electrically and respectively to the two power supply electrodes to generate an electrical current flowing in the system, said third output terminal of the electrical power supply unit being connected to the first additional transparent electrode, and the power supply unit being suitable for variably controlling at least one electrical voltage present between one of said power supply electrodes and the first additional transparent electrode.

20. The system as claimed in claim 14, further comprising:

an electrical power supply unit having two electrical current output terminals connected respectively to the two power supply electrodes of the system, and

an electric polarization unit having two electrical voltage output terminals connected respectively to the first additional transparent electrode and to said second additional transparent electrode.

21. The system as claimed in claim 1, forming a glazing, an aircraft window, an ophthalmic lens, a helmet visor, a mask glass, or a wafer configured to be applied to an ophthalmic lens, a helmet visor or a mask glass.

22. A method for using a transparent electrochromic system as claimed in claim 1, whereby an electrical voltage is applied between the first additional transparent electrode and at least one of the power supply electrodes, so that said first additional transparent electrode has an electrical potential lying outside an interval bounded by respective electrical potentials of said power supply electrodes.