Method and system for low energy carbon dioxide removal

• US 8,741,247 B2
• Filed: 07/27/2012
• Issued: 06/03/2014
• Est. Priority Date: 03/27/2012
• Status: Active Grant

• Current Assignee: General Electric Technology GmbH (GE Vernova, Inc.)
• Original Assignee: Alstom Technology Ltd. (Alstom SA)
• Inventors: Bedell, Stephen Alan
• Primary Examiner(s): VANOY, TIMOTHY C
• Application Number:
  US13/560,346
• Publication Number:
  US 20130259784A1
• Time in Patent Office: 676 Days
• Field of Search: 423/228, 422/168, 252/184, 252/189
• US Class Current: 423/228
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A system and method for removing carbon dioxide from a gas stream. One aspect of the method includes introducing a carbon dioxide containing gas stream to an absorber; contacting the gas stream with an amine-containing solvent; absorbing, with the amine-containing solvent, the carbon dioxide from the gas stream, thereby removing the carbon dioxide from the gas stream; and forming a precipitate with the amine-containing solvent and the carbon dioxide.

Claims

1. A method for removing carbon dioxide from a gas stream in a substantially isothermal absorber, the method comprising:

introducing a carbon dioxide containing gas stream to an absorber;

contacting the gas stream with an amine-containing solvent;

absorbing the carbon dioxide from the gas stream with the amine-containing solvent, thereby removing the carbon dioxide from the gas stream in an exothermic reaction; and

forming a precipitate with the amine-containing solvent and the carbon dioxide, the formation of the precipitate is an endothermic reaction such that the endothermicity of the reaction reduces the exothermicity of the absorption of the carbon dioxide.

2. A method according to claim 1, wherein the formation of the precipitate is an endothermic reaction such that the endothermicity of the reaction is substantially equal to the exothermicity of the absorption of the carbon dioxide thereby resulting in a substantially isothermal absorber.

3. A method according to claim 1, wherein the amine-containing solvent comprises an amine compound that reacts with carbon dioxide and has a positive heat of crystallization, the amine compound selected from the group consisting of diamines, triamines, cyclic amines, amino acids, and a combination thereof.

4. A method according to claim 3, wherein the amine compound forms a bicarbonate salt or a carbamate salt.

5. A method according to claim 3, wherein the amine-containing solvent comprises 2-amino-2-methyl-1-propanol in an aqueous solution.

6. A method according to claim 1, further comprising:

adjusting a degree of precipitation by lowering the temperature of the absorber to a temperature between about 5°

C. to about 50°

C.

7. A method according to claim 1, further comprising:

adjusting a degree of precipitation by combining the amine-containing solvent with a co-solvent.

8. A method according to claim 7, wherein the co-solvent is selected from the group consisting of ethanol, methanol and acetone.

9. A method according to claim 1, further comprising:

adjusting a degree of precipitation by increasing a concentration of carbon dioxide present in the absorber.

10. A method according to claim 1, further comprising:

removing the precipitate from the absorber as a slurry; and

providing at least a portion of the slurry to a regeneration system for separating the carbon dioxide from the amine-containing solvent.

11. A method for regulating an amount of heat generated in an absorber, the method comprising:

introducing a carbon dioxide containing gas stream to an absorber;

contacting the carbon dioxide containing gas stream with an amine-containing solvent, thereby removing carbon dioxide from the gas stream and forming a precipitate between the carbon dioxide and the amine-containing solvent; and

adjusting the degree of precipitation formation by at least one of decreasing a temperature of the absorber, combining a co-solvent with the amine-containing solvent, or increasing a concentration of carbon dioxide present in the absorber, wherein the degree of precipitation formation regulates an amount of heat generated in the absorber.

12. A method according to claim 11, wherein the amine-containing solvent comprises an amine that reacts with carbon dioxide, the amine selected from the group consisting of diamines, triamines, cyclic amines, amino acids, and a combination thereof.

13. A method according to claim 12, wherein the amine forms a bicarbonate salt or a carbamate salt.

14. A method according to claim 12, wherein the amine-containing solvent comprises 2-amino-2-methyl-1-propanol in an aqueous solution.

15. A method according to claim 11, wherein the amine-containing solvent comprises a positive heat of crystallization such that when the precipitate is formed, the precipitates absorbs heat generated during the removal of carbon dioxide from the gas stream.

16. A method according to claim 11, wherein when the temperature of the absorber is decreased to a temperature between about 5°

C. to about 50°

C.