Nanoparticle additives and lubricant formulations containing the nanoparticle additives

• US 8,741,821 B2
• Filed: 01/03/2007
• Issued: 06/03/2014
• Est. Priority Date: 01/03/2007
• Status: Active Grant

• Current Assignee: Afton Chemical Corporation
• Original Assignee: Afton Chemical Corporation
• Inventors: Jao, Tze-Chi, Devlin, Mark T., Aradi, Allen A.
• Primary Examiner(s): Goloboy, James
• Assistant Examiner(s): HINES, LATOSHA D
• Application Number:
  US11/619,470
• Publication Number:
  US 20080161213A1
• Time in Patent Office: 2,708 Days
• Field of Search: 508/165, 508/154, 423/263, 977/773
• US Class Current: 508/165
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C01F 17/235 Cerium oxides or hydroxides
• CPC Class Codes: C01P 2004/03 obtained by SEM
• CPC Class Codes: C01P 2004/32 Spheres
• CPC Class Codes: C01P 2004/64 Nanometer sized, i.e. from 1-100 nanometer
• CPC Class Codes: C10M 125/10 Metal oxides, hydroxides, carbonates or bicarbonates
• CPC Class Codes: C10M 125/22 Compounds containing sulfur, selenium or tellurium
• CPC Class Codes: C10M 2201/062 Oxides; Hydroxides; Carbonates or bicarbonates
• CPC Class Codes: C10M 2201/065 Sulfides; Selenides; Tellurides
• CPC Class Codes: C10M 2207/289 containing free hydroxy groups
• CPC Class Codes: C10N 2010/00 Metal present as such or in compounds
• CPC Class Codes: C10N 2020/06 Particles of special shape or size
• CPC Class Codes: C10N 2040/04 Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
• CPC Class Codes: C10N 2040/06 Instruments or other precision apparatus, e.g. damping fluids
• CPC Class Codes: C10N 2040/25 Internal-combustion engines
• CPC Class Codes: C10N 2040/253 Small diesel engines
• CPC Class Codes: C10N 2040/255 Gasoline engines
• CPC Class Codes: C10N 2050/015 Dispersions of solid lubricants

Abstract

A method for reducing a friction coefficient adjacent a lubricated surface, and a lubricant composition for reducing a friction coefficient between lubricated surfaces. The method includes providing an amount of metal-containing dispersed in a fully formulated lubricant composition containing a base oil of lubricating viscosity, wherein the nanoparticles have an average particles size ranging from about 1 to about 10 nanometers. The lubricant composition containing the metal-containing nanoparticles is applied to a surface to be lubricated.

Claims

1. A method for reducing a friction coefficient adjacent a lubricated surface of a vehicle, comprising providing self-dispersing metal-containing nanoparticles, wherein said nanoparticles are dispersed without the use of an additional dispersing agent, the nanoparticles being dispersed in a lubricant composition containing a base oil of lubricating viscosity, wherein the lubricant composition comprises from about 0.1 to about 5 wt.% of the self-dispersing nanoparticles based on a total weight of the lubricant composition, and providing the lubricant composition containing the self-dispersing metal-containing nanoparticles selected from the group consisting of oxide and sulfide nanoparticles to a component of a vehicle selected from the group consisting of an engine crankcase and an engine drive train, and operating the vehicle wherein the self-dispersing nanoparticles are represented by the formula (A_a)_m(B_b)_nX_x, wherein each of A, B is selected from a metal, X is selected from the group consisting of oxygen and sulfur, subscripts a, b, and x represent compositional stoichiometry, and each of m and n is greater than or equal to zero with the proviso that at least one of m and n is greater than zero, and wherein the self-dispersing nanoparticles are derived from one or more metal organic compounds in the presence of a fatty amine and fatty acid in the substantial absence of water and the nanoparticles, as made, are self-dispersing without the need for a separate coating step and have an average particles size ranging from about 1 to about 10 nanometers.

2. The method of claim 1, wherein the lubricated surface comprises an engine drive train.

3. The method of claim 1, wherein the lubricated surface comprises an internal surface or component of an internal combustion engine.

4. The method of claim 1, wherein the lubricated surface comprises an internal surface or component of a compression ignition engine.

5. The method of claim 1, wherein the amount of metal-containing nanoparticles in the lubricant composition ranges from about 0.1 to about 2 percent by weight.

6. The method of claim 1, wherein each of A and B is selected from the group consisting of metals from Groups 1A, 2A, 3A, 4A, 5A, and 6A of the Periodic Table, transition metals, lanthanides, actinides, and mixtures thereof.

7. The method of claim 1, wherein the metal-containing nanoparticles comprise cerium oxide nanoparticles having a spherical shape.

8. A method of reducing a friction coefficient of an engine lubricant composition during operation of an engine containing the lubricant composition, comprising providing a crankcase of the engine with a lubricant composition comprising a base oil of lubricating viscosity and self-dispersing metal-containing nanoparticles, wherein said nanoparticles are dispersed without the use of an additional dispersing agent, the nanoparticles being provided in an amount ranging from about 0.1 to about 5 wt.% based on a total weight of the lubricant composition, said amount being sufficient to reduce the friction coefficient to below a friction coefficient of a lubricant composition devoid of the self-dispersing metal-containing nanoparticles, and operating the engine, wherein the nanoparticles have an average particle size ranging from about 1 to about 10 nanometers, and wherein the nanoparticles are selected from the group consisting of oxide and sulfide nanoparticles represented by the formula (A_a)_m(B_b)_nX_x, wherein each of A, B is selected from a metal, X is selected from the group consisting of oxygen and sulfur, subscripts a, b, and x represent compositional stoichiometry, and each of m and n is greater than or equal to zero with the proviso that at least one of m and n is greater than zero, and wherein the self-dispersing nanoparticles are derived from one or more metal organic compounds in the presence of a fatty amine and fatty acid in the substantial absence of water and the nanoparticles are self-dispersing, as made, without the need for a separate coating step.

9. The method of claim 8, wherein the engine comprises a heavy duty diesel engine.

10. The method of claim 8, wherein the amount of metal-containing nanoparticles in the lubricant composition ranges from about 0.1 to about 2 percent by weight.

11. The method of claim 9, wherein each of A and B is selected from the group consisting of metals from Groups 1A, 2A, 3A, 4A, 5A, and 6A of the Periodic Table, transition metals, lanthanides, actinides, and mixtures thereof.

12. A method of for reducing wear between moving parts of a vehicle using a lubricating oil, the method comprising providing a lubricant composition containing a base oil, and an oil additive package including a wear reducing agent to a vehicle component selected from the group consisting of an engine crankcase and an vehicle drive train and operating the vehicle, wherein the wear reducing agent comprises self-dispersing metal-containing nanoparticles, wherein said nanoparticles are dispersed without the use of an additional dispersing agent, the nanoparticles being selected from the group consisting of oxide nanoparticles and sulfide nanoparticles represented by the formula (A_a)_m(B_b)_nX_x, wherein each of A, B is selected from a metal, X is selected from the group consisting of oxygen and sulfur, subscripts a, b, and x represent compositional stoichiometry, and each of m and n is greater than or equal to zero with the proviso that at least one of m and n is greater than zero, wherein the self-dispersing nanoparticles are derived from one or more metal organic compounds in the presence of a fatty amine and fatty acid in the substantial absence of water and the nanoparticles are self-dispersing, as made, without the need for a separate coating step, and wherein the amount of nanoparticles in the lubricant composition ranges up to about 5 percent by weight of the total lubricant composition.

13. The method of claim 12, wherein the moving parts comprise moving parts of an engine.

14. The method of claim 13, wherein the engine is selected from the group consisting of a compression ignition engine and a spark ignition engine.

15. The method of claim 13, wherein the engine includes an internal combustion engine having a crankcase and wherein the lubricating oil comprises a crankcase oil present in the crankcase of the engine.

16. The method of claim 12, wherein the lubricating oil comprises a drive train lubricant present in a drive train of a vehicle containing the engine.

17. The method of claim 12, wherein the wear reducing agent is present in the lubricant composition in an amount ranging from about 0.1 to about 5 percent by weight.

18. The method of claim 12, wherein the wear reducing agent has an average particle size ranging from about 1 to about 10 nanometers.

19. A lubricant composition for a vehicle crankcase or a vehicle drive train comprising:

a base oil of lubricating viscosity; and

a boundary friction reducing amount of self-dispersing metal-containing nanoparticles, wherein said nanoparticles are dispersed without the use of an additional dispersing agent, the nanoparticles being dispersed in the base oil, said amount ranging from about 0.1 to about 5 wt.% based on a total weight of the lubricant composition, wherein the nanoparticles have an average particles size ranging from about 1 to about 10 nanometers and are represented by the formula (A_a)_m(B_b)_nX_x, wherein each of A, B is selected from a metal, X is selected from the group consisting of oxygen and sulfur, subscripts a, b, and x represent compositional stoichiometry, and each of m and n is greater than or equal to zero with the proviso that at least one of m and n is greater than zero and x is greater than zero, wherein the self-dispersing nanoparticles are derived from one or more metal organic compounds in the presence of a fatty amine and fatty acid in the substantial absence of water and the nanoparticles are self-dispersing, as made, without the need for a separate coating step, and wherein the metal-containing nanoparticles are effective to reduce a boundary friction coefficient between lubricated metal surfaces to below a boundary friction coefficient between the lubricated metal surfaces of a lubricant composition devoid of the metal-containing nanoparticles.

20. The lubricant composition of claim 19, wherein the amount of metal-containing nanoparticles dispersed in the base oil ranges from about 0.1 to about 2 percent by weight.

21. The lubricant composition of claim 19, wherein the metal-containing nanoparticles comprises cerium-oxide nanoparticles having a spherical shape.