Azeotrope-like compositions of tetrafluoropropene and hydrofluorocarbons

• US 8,741,829 B2
• Filed: 03/26/2012
• Issued: 06/03/2014
• Est. Priority Date: 04/29/2004
• Status: Expired due to Term

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Singh, Rajiv R., Pham, Hang T., Knopeck, Gary
• Primary Examiner(s): WEBB, GREGORY E
• Application Number:
  US13/429,806
• Publication Number:
  US 20120187331A1
• Time in Patent Office: 799 Days
• Field of Search: 510/408, 510/412, 252/67
• US Class Current: 510/408
• CPC Class Codes: A01N 29/02 Acyclic compounds or compounds containing halogen attached to an aliphatic side-chain of a cycloaliphatic ring system
• CPC Class Codes: C09K 2205/122 Halogenated hydrocarbons
• CPC Class Codes: C09K 2205/126 Unsaturated fluorinated hydrocarbons
• CPC Class Codes: C09K 2205/22 All components of a mixture being fluoro compounds
• CPC Class Codes: C09K 2205/32 The mixture being azeotropic
• CPC Class Codes: C09K 2205/34 The mixture being non-azeotropic
• CPC Class Codes: C09K 2205/40 Replacement mixtures
• CPC Class Codes: C09K 23/017 Mixtures of compounds
• CPC Class Codes: C09K 3/30 for aerosols aerosol containers B65D83/14
• CPC Class Codes: C09K 5/045 containing only fluorine as halogen
• CPC Class Codes: C11D 7/5018 Halogenated solvents
• CPC Class Codes: C11D 7/505 Mixtures of (hydro)fluorocarbons
• CPC Class Codes: F25B 1/00 Compression machines, plants or systems with non-reversible cycle F25B3/00, F25B5/00, F25B6/00, F25B7/00, F25B9/00 take precedence
• CPC Class Codes: F25B 31/002 Lubrication

Abstract

Provided are azeotrope-like compositions comprising tetrafluoropropene and hydrofluorocarbons and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, and aerosol propellants.

Claims

1. A heat transfer composition comprising:

(1) an azeotrope-like composition; and

(2) at least one lubricant selected from the group consisting of mineral oil, silicone oil, polyalkyl benzenes (PABs), polyol esters (POEs), polyalkylene glycols (PAGs), polyalkylene glycol esters (PAG esters), polyvinyl ethers (PVEs), poly(alpha-olefins) (PAOs), and combinations of these,

wherein said azeotrope-like composition comprises trans-1,3,3,3-tetrafluoropropene (transHFO-1234ze) and 1,1,1,2-tetrafluoroethane (HFC-134a) in amounts effective to form an azeotrope-like composition.

2. The heat transfer composition of claim 1, wherein said lubricant comprises at least one POE.

3. The heat transfer composition of claim 1, wherein said lubricant is selected from the group consisting of PAGs, PAG esters, and combinations of these.

4. The heat transfer composition of claim 1, wherein said lubricant(s) together are present in an amount of from about 5 to about 50% by weight of the heat transfer composition.

5. The heat transfer composition of claim 1, wherein said azeotrope-like composition has a boiling point of from about −

26°

C. to about −

23°

C. at a pressure of about 14 psia.

6. The heat transfer composition of claim 1, wherein said azeotrope-like composition comprises from greater than zero to about 75 weight percent transHFO-1234ze and from about 25 to less than 100 weight percent of HFC-134a.

7. The heat transfer composition of claim 1, wherein said azeotrope-like composition comprises from greater than zero to about 60 weight percent transHFO-1234ze and from about 40 to about 90 weight percent of HFC-134a.

8. The heat transfer composition of claim 1, wherein said azeotrope-like composition comprises from about 1 to about 40 weight percent transfer HFO-1234ze and from about 60 to about 99 weight percent of HFC-134a.

9. The heat transfer composition of claim 1, wherein said azeotrope-like composition comprises from about 5 to about 35 weight percent trans-HFO-1234ze and from about 65 to about 95 weight percent of HFC-134a.

10. A refrigeration system comprising the heat transfer composition of claim 1 wherein said system is selected from the group consisting of automotive air conditioning systems, residential air conditioning systems, commercial air conditioning systems, residential refrigerator systems, residential freezer systems, commercial refrigerator systems, commercial freezer systems, chiller air conditioning systems, chiller refrigeration systems, heat pump systems, and combinations of two or more of these.

11. The refrigeration system of claim 10, wherein said lubricant comprises at least one POE.

12. The refrigeration system of claim 10, wherein said lubricant is selected from the group consisting of PAGs and PAG esters.

13. The refrigeration system of claim 10, wherein said lubricant(s) together are present in an amount of from about 5 to about 50% by weight of the heat transfer composition.

14. The refrigeration system of claim 10, wherein said azeotrope-like composition has a boiling point of from about −

26°

C. to about −

23°

C. at a pressure of about 14 psia.

15. The refrigeration system of claim 10, wherein said azeotrope-like composition comprises from greater than zero to about 75 weight percent transHFO-1234ze and from about 25 to less than 100 weight percent of HFC-134a.

16. The refrigeration system of claim 10, wherein said azeotrope-like composition comprises from greater than zero to about 60 weight percent transHFO-1234ze and from about 40 to about 90 weight percent of HFC-134a.

17. The refrigeration system of claim 10, wherein said azeotrope-like composition comprises from about 1 to about 40 weight percent transfer HFO-1234ze and from about 60 to about 99 weight percent of HFC-134a.

18. The refrigeration system of claim 10, wherein said azeotrope-like composition comprises from about 5 to about 35 weight percent trans-HFO-1234ze and from about 65 to about 95 weight percent of HFC-134a.