Method and apparatus for sensing the presence of explosives, contraband and other molecules using nuclear quadrupole resonance

• US 8,742,753 B2
• Filed: 12/01/2010
• Issued: 06/03/2014
• Est. Priority Date: 01/29/2010
• Status: Active Grant

• Current Assignee: R.A. Miller Industries, Inc.
• Original Assignee: R.A. Miller Industries, Inc.
• Inventors: Zank, Paul A., Apostolos, John T.
• Primary Examiner(s): Hollington, Jermele M
• Assistant Examiner(s): CHAN, EMILY Y
• Application Number:
  US12/957,843
• Publication Number:
  US 20110187363A1
• Time in Patent Office: 1,280 Days
• Field of Search: 324300-322, 600407-464
• US Class Current: 324/307
• CPC Class Codes: G01N 24/084 Detection of potentially hazardous samples, e.g. toxic samples, explosives, drugs, firearms, weapons
• CPC Class Codes: G01R 33/441 Nuclear Quadrupole Resonance [NQR] Spectroscopy and Imaging

Abstract

Stimulated emissions due to nuclear quadropole resonance are detected utilizing a terminated balanced transmission line and a directional coupler for the detection of explosives, contraband, narcotics and the like that exist between the transmission lines, with either a stepped frequency generator utilized to scan between 100 KHz and 10 MHz, or wherein parallel fixed frequency sources are coupled to the transmission line, thereby to permit correlation with expected lines, with the frequency sources being low power so as to not create a safety hazard and so as not to interfere with radiation sensitive devices such as film or electronic circuits that are in the vicinity of the balanced transmission line.

Claims

1. A method for performing a nuclear quadrupole resonance measurement on a material, comprising the steps of:

placing a target material between spaced apart elements of a transmission line terminated with a load equal to the impedance of the transmission line wherein the transmission line is balanced and effectively has a Q of zero;

driving the transmission line through a directional coupler with a transmitted signal having a frequency equal to that of a spectral lines of the target material; and

,

detecting a stimulated emission caused by nuclear quadrupole resonance of the target material from a received signal at an output of the directional coupler wherein the received signal is isolated from the transmitted signal, so that interference between the transmitted signal to the transmission line and the received signal from the transmission line is minimized.

2. The method of claim 1, wherein the frequency of the transmitted signal is less than 10 MHz and greater than 100 KHz.

3. The method of claim 1, wherein the transmitted signal is swept from a lower frequency to a higher frequency in the driving step.

4. The method of claim 3, wherein the sweeping of the frequency is performed in a step wise fashion.

5. The method of claim 1, wherein the driving step includes simultaneously driving the transmission line with multiple frequencies.

6. The method of claim 5, wherein the multiple frequencies include frequencies which match the stimulated emissions from the target material.

7. The method of claim 1, wherein the transmitted signal is coded.

8. The method of claim 7, wherein the code is a PN code.

9. The method of claim 1, and further including a multiplicity of transmission lines laid out side by side with each of the transmission lines being driven by a signal that matches the spectral lines of the target material.

10. The method of claim 9, and further including a second set of transmission lines overlying the first set of transmission lines at an angle so as to provide a grid of transmission lines.

11. The method of claim 10, and further including the step of ascertaining the location of the target material by processing the outputs of the grid.

12. The method of claim 1, wherein the driving step includes driving the transmission line with a number of different frequencies matching spectral lines of more than one molecule in the target material, and further including the step of ascertaining from the stimulated emission from the target material the ratio of the components in the target material.

13. The method of claim 1, wherein the balanced transmission line is located at a portal.

14. The method of claim 1 wherein the power of the transmitted signal is between 200 milliwatts and 10 watts.

15. The method of claim 1 wherein flux density between the elements of the transmission line is equal to or greater than 1 watt per square meter.

16. A device for performing a nuclear quadrupole resonance measurement on a material, comprising:

spaced apart elements of a transmission line wherein the transmission line is terminated with a load equal to the impedance of the transmission line so that the transmission line is balanced and effectively has a Q of zero;

a frequency generator connected to the transmission line and configured to generate a transmission signal in the transmission line having a frequency equal to that of a spectral line of a target material positioned between the spaced apart elements;

a signal detector configured to detect a received signal from the transmission line indicative of a stimulated emission caused by nuclear quadrupole resonance of the target material in response to the transmission signal; and

a directional coupler connected between the transmission line and the signal detector to isolate the received signal from the transmission signal so that interference between the transmitted signal and the received signal will be minimized.

17. The device of claim 16 further comprising a power amplifier connected between the frequency generator and the transmission line to amplify the transmission signal.

18. The device of claim 16 wherein the directional coupler is coupled to the low noise amplifier to amplify the received signal.

19. The device of claim 16 further comprising a network analyzer connected to the directional coupler to correlate the received signal with a library of predetermined spectral lines of known materials.