Planar patterned transparent contact, devices with planar patterned transparent contacts, and/or methods of making the same

• US 8,747,959 B2
• Filed: 06/30/2011
• Issued: 06/10/2014
• Est. Priority Date: 06/30/2011
• Status: Active Grant

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Guardian Industries Corporation (KOCH Industries Incorporated)
• Inventors: Krasnov, Alexey, Imran, Muhammad, den Boer, Willem
• Primary Examiner(s): Meeks, Timothy
• Assistant Examiner(s): Agaj, Ina
• Application Number:
  US13/174,362
• Publication Number:
  US 20130004678A1
• Time in Patent Office: 1,076 Days
• Field of Search: None
• US Class Current: 427/521
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3655 the multilayer coating containing at least one conducting layer
• CPC Class Codes: C03C 2218/322 Oxidation
• CPC Class Codes: G06F 2203/04103 Manufacturing, i.e. details related to manufacturing processes specially suited for touch sensitive devices
• CPC Class Codes: G06F 3/0443 using a single layer of sensing electrodes
• CPC Class Codes: G06F 3/045 using resistive elements, e.g. a single continuous surface or two parallel surfaces put in contact
• CPC Class Codes: H01L 31/1884 Manufacture of transparent electrodes, e.g. TCO, ITO
• CPC Class Codes: H01L 33/405 Reflective materials
• CPC Class Codes: H05B 33/22 characterised by the chemical or physical composition or the arrangement of auxiliary dielectric or reflective layers
• CPC Class Codes: H10K 30/82 Transparent electrodes, e.g. indium tin oxide [ITO] electrodes
• CPC Class Codes: H10K 50/816 Multilayers, e.g. transparent multilayers
• CPC Class Codes: H10K 50/826 Multilayers, e.g. opaque multilayers
• CPC Class Codes: Y02E 10/549 Organic PV cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

Certain examples relate to improved methods for making patterned substantially transparent contact films, and contact films made by such methods. In certain cases, the contact films may be patterned and substantially planar. Thus, the contact films may be patterned without intentionally removing any material from the layers and/or film, such as may be required by photolithography. In certain example embodiments, an oxygen exchanging system comprising at least two layers may be deposited on a substrate, and the layers may be selectively exposed to heat and/or energy to facilitate the transfer of oxygen ions or atoms from the layer with a higher enthalpy of formation to a layer with a lower enthalpy of formation. In certain cases, the oxygen transfer may permit the conductivity of selective portions of the film to be changed. This advantageously may result in a planar contact film that is patterned with respect to conductivity and/or resistivity.

Claims

1. A method of making a coated article comprising a multi-layer thin-film coating supported by a substrate, the method comprising:

disposing a conductive layer on the substrate;

disposing a sub-oxidized buffer layer on the conductive layer;

disposing an over-oxidized layer on the sub-oxidized buffer layer;

selectively applying energy causing oxygen in the over-oxidized layer to migrate downward into the conductive layer to increase the resistivity of the conductive layer at one or more portions,

wherein, after selectively applying the energy, the multi-layer thin-film coating is substantially planar and patterned with respect to conductivity and/or resistivity.

2. The method of claim 1, wherein the over-oxidized layer has an enthalpy of formation that is higher than an enthalpy of formation of the conductive layer.

3. The method of claim 2, wherein the conductive layer at least initially comprises metallic Ag that is conductive, and wherein the over-oxidized layer at least initially comprises an oxide of titanium or an oxide of zirconium.

4. The method of claim 1, wherein the sub-oxidized buffer layer comprises an oxide of titanium or an oxide of zirconium.

5. The method of claim 4, wherein the sub-oxidized buffer layer is 0.5-10 nm thick.

6. The method of claim 1, wherein the substrate is a glass substrate, and the method further comprising disposing a seed layer on the glass substrate, the conductive layer being over and directly contacting the seed layer.

7. The method of claim 6, wherein the seed layer comprises zinc oxide.

8. The method of claim 1, further comprising disposing an overcoat layer comprising silicon oxide, silicon nitride and/or silicon oxynitride over the over-oxidized layer.

9. The method of claim 1, wherein following the selective application of energy, the resistivity of the conductive layer at the one or more portions is increased to at least 1 Mohm/square and wherein the resistivity of the conductive layer outside the one or more portions is less than 50 ohms/square.

10. The method of claim 1, wherein following the selective application of energy, a sheet resistance ratio of resistivity at the one or more portions of the conductive layer to areas of the conductive layer outside the one or more portions is at least about 30,000:

1.

11. The method of claim 1, wherein following the selective application of energy, a sheet resistance ratio of resistivity at the one or more portions of the conductive layer to areas of the conductive layer outside the one or more portions is at least about 100,000:

1.

12. The method of claim 1, wherein the selective application of energy is performed using a short-wave infrared or near-infrared energy source.

13. The method of claim 1, wherein the selective application of energy is performed using a YAG laser.

14. The method of claim 1, wherein the selective application of energy is performed through a heat-blocking mask interposed between a source of the energy and the coated article.

23. The method or claim 1, wherein after selectively applying the energy the multi-layer thin-film coating is substantially planar and patterned with respect to conductivity.

24. The method of claim 1, wherein after selectively applying the energy the multi-layer thin-film coating is substantially planar and patterned with respect to resistivity.

25. The method of claim 1, wherein the conductive layer at least initially comprises Ag, and the over-oxidized layer at least initially comprises an oxide of titanium.

26. The method of claim 1, wherein the over-oxidized layer at least initially comprises an oxide of zirconium.

27. The method of claim 1, wherein the sub-oxidized buffer layer comprises an oxide of titanium.

15. A method of making an electronic device, the method comprising:

providing a coated article including a glass substrate supporting a multi-layer thin-film coating, the multi-layer thin-film coating comprising, moving away from the substrate;

a seed layer comprising Zn, Sn, and/or an oxide thereof,

a layer comprising Ag that is conductive as deposited,

a sub-oxidized buffer layer, and

an over-oxidized dielectric layer;

defining a first set of portions in the layer comprising Ag that are to be conductive portions and a second set of portions in the layer comprising Ag that are to be substantially non-conductive portions;

exposing the multi-layer thin-film coating to energy, from an energy source, in areas over the second set of portions so as to cause migration of oxygen ions or atoms from the over-oxidized dielectric layer to the layer comprising Ag and pattern the layer comprising Ag with respect to conductivity and/or resistivity; and

providing the coated article having the patterned layer comprising Ag in an electronic device.

16. The method of claim 15, wherein the layer comprising Ag comprises metallic Ag, AgZr, Agin, AgSn, and/or AgTi at least prior to the exposing.

17. The method of claim 15, wherein the sub-oxidized buffer layer at least initially comprises at least one of sub-oxidized zirconium oxide, Zr, an oxide of ZrTi, an oxide of ZrAl, ITO, and/or an oxide of ZrNb at least prior to the exposing.

18. The method of claim 15, wherein the over-oxidized dielectric layer comprises ZrOx at least one of an oxide of Zr, Zr, an oxide of ZrTi, an oxide of ZrAl, ITO, and/or an oxide of ZrNb at least prior to the exposing.

19. The method of claim 15, wherein the electronic device is a touch panel device.

20. The method of claim 15, wherein the electronic device is a flat panel display device.

21. The method of claim 15, wherein the multi-layer thin-film coating varies in thickness by no more than 15% after the exposing.

22. The method of claim 21, wherein optical differences along the multi-layer thin-film coating are imperceptible to a naked human eye.