Hydromethanation of a carbonaceous feedstock

• US 8,748,687 B2
• Filed: 08/17/2011
• Issued: 06/10/2014
• Est. Priority Date: 08/18/2010
• Status: Active Grant

• Current Assignee: Sure Champion Investments Limited
• Original Assignee: GreatPoint Energy, Inc.
• Inventors: Sirdeshpande, Avinash
• Primary Examiner(s): Bullock, In Suk
• Assistant Examiner(s): LOUIE, PHILIP Y
• Application Number:
  US13/211,476
• Publication Number:
  US 20120046510A1
• Time in Patent Office: 1,028 Days
• Field of Search: 585/733
• US Class Current: 585/733
• CPC Class Codes: C10J 2300/0956 Air or oxygen enriched air
• CPC Class Codes: C10J 2300/0959 Oxygen
• CPC Class Codes: C10J 2300/0973 Water
• CPC Class Codes: C10J 2300/0976 as steam
• CPC Class Codes: C10J 2300/0986 Catalysts
• CPC Class Codes: C10J 2300/169 with water treatments
• CPC Class Codes: C10J 3/463 in stationary fluidised beds
• CPC Class Codes: C10K 1/101 with water only
• CPC Class Codes: C10K 3/04 reducing the carbon monoxide content , e.g. water-gas shift [WGS]
• CPC Class Codes: C10L 3/08 Production of synthetic natural gas
• CPC Class Codes: Y02P 20/10 Process efficiency

Abstract

The present invention relates to a steam-integrated and heat-integrated process for preparing gaseous products, and in particular methane and/or other value added gaseous products such as hydrogen, via the hydromethanation of non-gaseous carbonaceous feedstocks in the presence of steam, carbon monoxide, hydrogen, oxygen and a hydromethanation catalyst.

Claims

1. A process for generating a methane-enriched raw product gas stream from a non-gaseous carbonaceous material, the process comprising the steps of:

(a) supplying to a hydromethanation reactor

(1) a carbonaceous feedstock derived from the non-gaseous carbonaceous material,

(2) a hydromethanation catalyst,

(3) a superheated steam stream and

(4) an oxygen-rich gas stream comprising steam,

wherein the hydromethanation reactor comprises a fluidized bed having a upper portion above a lower portion, and wherein the superheated steam stream and the oxygen-rich gas stream are introduced into the lower portion of the fluidized bed;

(b) reacting a portion of the carbonaceous feedstock in the hydromethanation reactor in the presence of hydromethanation catalyst, carbon monoxide, hydrogen and steam, at a target operating temperature at least about 1000°

F. (about 538°

C.) to about 1500°

F. (about 816°

C.), to produce a methane-enriched raw gas and a solid by-product char, wherein the methane-enriched raw gas comprises methane, carbon monoxide, hydrogen, carbon dioxide, hydrogen sulfide, steam, heat energy and entrained fines, and wherein the methane-enriched raw product stream comprises at least 50 mol % methane plus carbon dioxide (based on the moles of methane, carbon dioxide, carbon monoxide and hydrogen in the methane-enriched raw product stream);

(c) reacting a portion of the carbonaceous feedstock with oxygen to produce carbon monoxide, hydrogen and heat energy; and

(d) withdrawing the methane-enriched raw gas from the hydromethanation reactor as the methane-enriched raw product gas stream,

wherein;

(i) the reaction of step (b) predominates in the upper portion of the fluidized bed;

(ii) the reaction of step (c) predominates in the lower portion of the fluidized bed;

(iii) the reaction of step (b) has a syngas demand, a heat demand and a steam demand;

(iv) the syngas demand and the heat demand are substantially satisfied by the reaction of step (c);

(v) the steam demand is substantially satisfied by steam in the superheated steam stream and the oxygen-rich gas stream, and steam generated from the carbonaceous feedstock; and

(vi) the superheated steam stream, the oxygen-rich gas stream, the carbonaceous feedstock and the hydromethanation catalyst are introduced into the hydromethanation reactor at a temperature below the target operating temperature of the reaction of step (b).

2. The process of claim 1, wherein the syngas demand and the heat demand are satisfied by the reaction of step (c).

3. The process of claim 1, wherein the steam demand is satisfied by steam in the superheated steam stream and the oxygen-rich gas stream, and steam generated from the carbonaceous feedstock.

4. The process of claim 1, wherein the superheated steam stream is fed to the hydromethanation reactor at a temperature of from about 500°

F. (about 260°

C.) to about 950°

F. (about 510°

C.).

5. The process of claim 1, wherein the superheated steam stream and the oxygen-rich stream are combined for feeding into the lower section of the fluidized bed of the hydromethanation reactor, and the temperature of the combined stream is from about from about 500°

F. (about 260°

C.) to about 900°

F. (about 482°

C.).

6. The process of claim 1, wherein the methane-enriched raw product stream comprises at least about 15 mol % methane (based on the moles of methane, carbon dioxide, carbon monoxide and hydrogen in the methane-enriched raw product stream).

7. The process of claim 1, wherein the methane-enriched raw product stream is introduced into a first heat exchanger unit to recover heat energy and generate a cooled methane-enriched raw product stream.

8. The process of claim 7, wherein the heat energy recovered in the first heat exchanger unit is used to generate a first process steam stream, and superheat the first process steam stream for use as all or a part of the superheated steam stream for introduction into the hydromethanation reactor.

9. The process of claim 7, wherein at least a portion of the carbon monoxide in the cooled methane-enriched raw product stream is steam shifted to generate heat energy and a hydrogen-enriched raw product stream.

10. The process of claim 9, wherein heat energy is recovered from the steam shifting, and at least a portion of the recovered heat energy is utilized to preheat boiler feed water for use in generating process steam.

11. The process of claim 9, wherein the hydrogen-enriched raw product stream is substantially dehydrated to generate a dehydrated hydrogen-enriched raw product stream.

12. The process of claim 11, wherein a substantial portion of the carbon dioxide and a substantial portion of the hydrogen sulfide are removed from the dehydrated hydrogen-enriched raw product stream to produce a sweetened gas stream comprising a substantial portion of the hydrogen, carbon monoxide (if present in the dehydrated hydrogen-enriched raw product stream) and methane from the dehydrated hydrogen-enriched raw product stream.

13. The process of claim 12, wherein a portion of hydrogen from the sweetened gas stream is separated to produce a hydrogen product stream and a hydrogen-depleted sweetened gas stream comprising methane, hydrogen and carbon monoxide.

14. The process of claim 12, wherein carbon monoxide and hydrogen present in the sweetened gas stream (or hydrogen-depleted sweetened gas stream, if present) are reacted in a catalytic methanator in the presence of a methanation catalyst to produce heat energy and a methane-enriched sweetened gas stream.

15. The process of claim 14, wherein methane-enriched sweetened gas stream is recovered as a methane product stream.

16. The process of claim 15, wherein the methane product stream is a pipeline-quality natural gas.

17. The process of claim 14, wherein heat energy from the catalytic methanation is recovered and at least a portion of the recovered heat energy is utilized to generate and superheat a second process steam stream.

18. The process of claim 17, wherein the superheated steam stream substantially comprises steam from the first process steam stream and the second process steam stream.

19. The process of claim 1, wherein the process is steam neutral or steam positive.

20. The process of claim 1, wherein there is no fuel-fired superheater used to superheat the steam fed to the hydromethanation reactor during steady-state operation of the process.

21. The process of claim 1, wherein the oxygen-rich gas stream comprises molecular oxygen and is supplied to the hydromethanation reactor such that the amount of molecular oxygen ranges from about 0.10 to about 0.6 pounds per pound of carbonaceous feedstock supplied to the hydromethanation reactor.