Identification of objects using plasmon resonant particles

• US 8,759,116 B2
• Filed: 10/17/2012
• Issued: 06/24/2014
• Est. Priority Date: 02/20/1997
• Status: Expired due to Fees

• Current Assignee: Regents of the University of California (University of California)
• Original Assignee: Regents of the University of California (University of California)
• Inventors: Schultz, David A., Mock, Jack J., Smith, David R., Schultz, Sheldon, Silva, Thomas J.
• Primary Examiner(s): LAM, ANN Y
• Application Number:
  US13/654,005
• Publication Number:
  US 20130038868A1
• Time in Patent Office: 615 Days
• Field of Search: None
• US Class Current: 436/525
• CPC Class Codes: B01J 2219/0054 Means for coding or tagging the apparatus or the reagents
• CPC Class Codes: B01J 2219/00648 by the use of solid beads
• CPC Class Codes: B01J 2219/00659 Two-dimensional arrays
• CPC Class Codes: B01J 2219/00707 separated from the reactor apparatus
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C12Q 1/6816 characterised by the detection means C12Q1/6804 takes precedence
• CPC Class Codes: C12Q 1/6825 Nucleic acid detection involving sensors
• CPC Class Codes: C40B 70/00 Tags or labels specially adapted for combinatorial chemistry or libraries, e.g. fluorescent tags or bar codes
• CPC Class Codes: G01N 21/554 detecting the surface plasmon resonance of nanostructured metals, e.g. localised surface plasmon resonance
• CPC Class Codes: G01N 21/648 using evanescent coupling or surface plasmon coupling for the excitation of fluorescence
• CPC Class Codes: G01N 21/658 enhancement Raman, e.g. surface plasmons
• CPC Class Codes: G06K 19/06084 the marking being based on nanoparticles or microbeads
• CPC Class Codes: G06K 7/1408 the method being specifically adapted for the type of code
• CPC Class Codes: Y10S 436/805 Optical property

Abstract

A method and apparatus for identifying an object having a pattern of plasmon resonant particles (PREs) distributed in or on the object are disclosed. In the method, a field containing the pattern is illuminated, and one or more spectral emission characteristics of the light-scattering particles in the field are detected. From this data, an image of positions and spectral characteristic values in the field is constructed, allowing PREs with a selected spectral signature to be discriminated from other light-scattering entities, to provide information about the field. The image may be compared to a database of reference images to identify or validate the object.

Claims

1. A method for identifying an object, comprising:

depositing a pattern of plasmon resonant entities (PREs) on at least a portion of a surface of the object;

illuminating the pattern with a light source adapted to excite plasmon resonance in the PREs;

microscopically detecting an emission pattern corresponding to the pattern of PREs;

generating an image corresponding to the detected emission pattern;

comparing the image with one or more reference images stored within an image database, wherein the one or more reference images are associated with one or more potential identities of the object; and

if the image matches a reference image within the image database, generating a report comprising an identity of the object, and if the image fails to match any reference image within the image database, generating a report indicating a failure to identify.

2. The method of claim 1, wherein, after the step of depositing, the pattern is stored within the image database in association with data that identifies the object, and wherein, if the image matches the stored pattern, the report comprises an authentication indication.

3. The method of claim 1, wherein the object comprises an item subject to forgery.

4. The method of claim 1, wherein the object comprises currency.

5. The method of claim 1, wherein the object comprises a credit card.

6. The method of claim 1, wherein the object comprises an identification document.

7. The method of claim 1, wherein the pattern is random.

8. The method of claim 1, wherein the pattern is pre-defined.

9. The method of claim 1, further comprising, after the step of depositing, coating the PREs with a protective layer.

10. The method of claim 1, further comprising, incorporating a data storage medium within the object, wherein the data storage medium has data stored therein corresponding to a coded version of the pattern.

11. The method of claim 1, wherein the step of comparing comprises using a computer adapted for pattern recognition.

12. A method for authenticating an object, comprising:

depositing an array of plasmon resonant entities (PREs) on a surface of the object to define a pattern;

exciting plasmon resonance in the PREs to generate an emission pattern corresponding to the pattern;

microscopically observing the emission pattern to generate an image;

comparing the image with one or more reference images stored within an image database, wherein the one or more reference images are associated with one or more potential identities of the object; and

if the image matches a reference image within the image database, generating a report comprising an identity of the object, and if the image fails to match any reference image within the image database, generating a report indicating a failure to identify.

13. The method of claim 12, wherein, after the step of depositing, the pattern is stored within the image database in association with data that identifies the object, and wherein, if the image matches the stored pattern, the report comprises an authentication indication.

14. The method of claim 12, wherein the object comprises an item subject to forgery.

15. The method of claim 12, wherein the object comprises currency.

16. The method of claim 12, wherein the object comprises a credit card.

17. The method of claim 12, wherein the object comprises an identification document.

18. The method of claim 12, wherein the pattern is random.

19. The method of claim 12, wherein the pattern is pre-defined.

20. The method of claim 12, further comprising, after the step of depositing, coating the PREs with a protective layer.

21. The method of claim 12, further comprising, incorporating a data storage medium within the object, wherein the data storage medium has data stored therein corresponding to a coded version of the pattern.

22. A method for authenticating an object, comprising:

applying a film comprising a pre-defined pattern of plasmon resonant entities (PREs) to a surface of an authentic object;

storing reference data within a data storage medium, the reference data comprising the pre-defined pattern associated with information describing the authentic object;

exciting plasmon resonance in the PREs to generate an emission pattern corresponding to the pre-defined pattern; and

comparing the emission pattern with the reference data; and

if the emission pattern matches the reference data, generating a report indicating that the object is authentic, and if the emission pattern fails to match the reference data, generating a report indicating that the object is not authentic.

23. The method of claim 22, wherein the object comprises an item subject to forgery selected from the group consisting of currency, credit cards, and identification documents.

24. The method of claim 22, further comprising, incorporating a data storage medium within the object, wherein the data storage medium has data stored therein corresponding to a coded version of the pattern.