Multivariate management of entrained air and rheology in cementitious mixes

• US 8,764,273 B2
• Filed: 06/11/2013
• Issued: 07/01/2014
• Est. Priority Date: 12/12/2011
• Status: Active Grant

• Current Assignee: Verifi, LLC (Compagnie De Saint-Gobain S.A.)
• Original Assignee: W R Grace & Company - CONN (Standard Industries Holdings, Inc.)
• Inventors: Koehler, Eric, Roberts, Mark F.
• Primary Examiner(s): MARCANTONI, PAUL D
• Application Number:
  US13/915,251
• Publication Number:
  US 20130272084A1
• Time in Patent Office: 385 Days
• Field of Search: 106/713, 366/8, 366/16, 366/17, 366/29, 700/239, 700/265
• US Class Current: 366/8
• CPC Class Codes: B28C 5/08 using driven mechanical means affecting the mixing B28C5/40, B28C5/42, B28C5/48 take precedence; in combination with the action of a fluid B28C5/38
• CPC Class Codes: B28C 5/422 Controlling or measuring devices B28C5/4227 takes precedence
• CPC Class Codes: B28C 7/024 by measuring properties of the mixture, e.g. moisture, electrical resistivity, density
• CPC Class Codes: B28C 7/026 by measuring data of the driving system, e.g. rotational speed, torque, consumed power
• CPC Class Codes: B29C 35/0272 using lost heating elements, i.e. heating means incorporated and remaining in the formed article for preforms with internal stresses B29C61/0625; joining using lost heating elements B29C65/34; making electrically conductive articles B29C70/882
• CPC Class Codes: B29C 70/882 partly or totally electrically conductive, e.g. for EMI shielding conductive floors or floor coverings H05F3/025; EMI shielding in general H05K9/00
• CPC Class Codes: C04B 2103/304 Air-entrainers
• CPC Class Codes: C04B 2103/308 Slump-loss preventing agents
• CPC Class Codes: C04B 2103/408 Dispersants
• CPC Class Codes: C04B 2103/50 Defoamers, air detrainers
• CPC Class Codes: C04B 24/2641 Polyacrylates; Polymethacrylates
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 40/0028 Aspects relating to the mixing step of the mortar preparation
• CPC Class Codes: C04B 40/0032 Controlling the process of mixing, e.g. adding ingredients in a quantity depending on a measured or desired value B28C7/00 takes precedence

Abstract

The invention relates to a method and system for monitoring and adjusting both air content and rheology (e.g., slump, slump flow) properties of a hydratable concrete mix contained within a concrete mixer. The system simultaneously tracks dosage of both rheology-modifying admixture (e.g., polycarboxylate polymer cement dispersant) and air control agent or “ACA” (e.g., air entraining agent) by reference to at least four nominal dose response (“NDR”) curves or profiles, which at least four NDR profiles are based on the respective behaviors of each of the ACA and rheology-modifying agent on air content and rheology.

Claims

1. A mixing apparatus for monitoring and adjusting slump and air content in a cementitious mix, comprising:

(a) a concrete mixer drum for containing a concrete mix comprising hydratable cement, aggregates, and water for hydrating said cement, the concrete mix having a total volume, when mixed uniformly within the concrete mixer drum, of 1.0 to 15.0 cubic yards;

(b) a computer processing unit and computer-processing unit-accessible memory, the computer processing unit programmed for inputting and storing into the computer processing unit-accessible memory concrete performance ranges relative to;

a target slump or target slump range; and

a target air content or target air content range wherein a concrete air content or air content range is within a range of 1% to 10%;

(c) the computer processing unit being further programmed for mixing a concrete mix contained in the concrete mixer drum and for obtaining at least one slump value in current time and at least one air content value in current time;

(d) the computer processing unit being further programmed for comparing the at least one slump value in current time against the slump target or slump target range and the at least one air content value in current time against the target air content or target air content range until detection of a non-conformance event, wherein the at least one slump value in current time does not conform with the target slump or target slump range and/or the at least one air content value in current time does not conform with the target air content or target air content range; and

(e) the computer processing unit being further programmed for introducing into the concrete mix contained in said concrete mixer drum, one of at least two compositionally different additives comprising;

at least one chemical admixture for modifying air content in the concrete mix, wherein the at least one chemical admixture for modifying air content in the concrete mix comprises at least one air entraining admixture, at least one air detraining admixture, or mixture of at least one air entraining admixture and at least one air detraining admixture; and

at least one cement dispersant for modifying slump of the concrete mix, said at least one cement dispersant comprising at least one polymeric dispersant, water, or a mixture of said at least one polymeric dispersant and water;

the computer processing unit being further programmed for introducing of the at least one chemical admixture for modifying air content in the concrete mix and/or at least one cement dispersant being achieved by computer processor unit-controlled valve system in accordance with the computer processor unit-accessed memory, the aforementioned memory having at least four sets of data correlations comprising the effect of;

(i) the cement dispersant on slump of the concrete mix;

(ii) the at least one chemical admixture for modifying air content in the concrete mix on air content;

(iii) the at least one chemical admixture for modifying air content in the concrete mix on the slump of the concrete mix; and

(iv) the cement dispersant on air content of the concrete mix.

2. The mixing apparatus of claim 1 wherein the at least one chemical admixture for modifying air content in the concrete mix is an air entraining agent.

3. The mixing apparatus of claim 1 wherein the at least one chemical admixture for modifying air content in the concrete mix is an air detraining agent.

4. The mixing apparatus of claim 1 wherein the at least one chemical admixture for modifying air content in the concrete mix comprises both an air entraining agent and an air detraining agent.

5. The mixing apparatus of claim 1 wherein said at least one cement dispersant is a polycarboxylate polymer.

6. The mixing apparatus of claim 1 wherein the four sets of correlations identified in (i), (ii), (iii), and (iv) are based on an average or mean value calculated from at least two nominal dosage response curves.

7. The mixing apparatus of claim 1 wherein the four sets of correlations identified in (i), (ii), (iii), and (iv) are based on an average or mean value calculated from a plurality of nominal dosage response curves.

8. The mixing apparatus of claim 7 wherein, in the nominal dosage response curves, the at least four sets of data correlations involve at least one non-homogeneous parameter selected from the group consisting of concrete mix design, concrete mix ingredient source, temperature, degree of hydration, water/cement ratio, and aggregate amount.

9. The mixing apparatus of claim 8 wherein, in the nominal dosage response curves, the at least four sets of data correlations involve at least two non-homogeneous parameters selected from the group consisting of concrete mix design, concrete mix ingredient source, concrete temperature, degree of hydration, water/cement ratio, and aggregate amount.

10. The mixing apparatus of claim 1 wherein the changes in air content and slump of the concrete mix as affected by doses of chemical admixture for modifying air content in the concrete mix and cement dispersant administered during a concrete mix delivery operation are incorporated into the nominal dose response curves and scaling factors whereby the nominal dose response curves and scaling factors are modified;

and subsequent air and slump changes in the same or a subsequent concrete mix delivery operation are effected based on the modified nominal dose response curves or the modified scaling factors.

11. The mixing apparatus of claim 10 wherein the computer processor unit communicates wirelessly with computer processor unit-accessible database memory having data relative to the changes in air content and slump of concrete mixes as affected by doses of chemical admixture for modifying air content in the concrete mix and cement dispersant administered during concrete mix delivery operation and incorporated into the nominal dose response curves and scaling factors whereby the nominal dose response curves and scaling factors are modified, as well as data relative to air and slump changes in the same or a subsequent concrete mix delivery operations as effected based on the modified nominal dose response curves or modified scaling factors.

12. The mixing apparatus of claim 11 wherein the computer processor unit-accessible database memory stores information on one or more of concrete mix design, concrete mix ingredient source, concrete temperature, water/cement ratio, and time since batching for each data point relative to the changes in air content and slump of concrete mixes as affected by doses of chemical admixture for modifying air content in the concrete mix and cement dispersant administered during concrete mix delivery operation.

13. The mixing apparatus of claim 12 where one or more of concrete mix design, concrete mix ingredient source, concrete temperature, water/cement ratio, and time since batching are used to select the nominal dose response curve or scaling factor.

14. The mixing apparatus of claim 1 wherein the cement dispersant comprises water and a water reducing admixture.

15. The mixing apparatus of claim 14 wherein water is the cement dispersant added after ingredients are loaded into the mixing drum until reaching the target slump or target slump range and the target air content or target air content range, and water reducing admixture or superplasticizer is the cement dispersant used to maintain the at least one slump value in current time and the at least one air content value in current time in the target slump or target slump range and target air content or target air content range.

16. The mixing apparatus of claim 1 wherein the computer processing unit is further programmed, after adding additive into the concrete mix, to rotate the mixing drum containing the concrete mix a number of revolutions that is based on the identity of the cement dispersant and/or the chemical admixture for modifying air content in the concrete mix added prior to discharging the concrete mix or resuming monitoring of the concrete slump.

17. The mixing apparatus of claim 1 wherein the computer processing unit is programmed to repeat the following steps until the concrete is discharged from the mixer:

mixing a concrete mix contained in the concrete mixer drum and for obtaining at least one slump value in current time and at least one air content value in current time;

comparing the at least one slump value in current time against the slump target or slump target range and the at least one air content value in current time against the target air content or target air content range until detection of a non-conformance event, wherein the at least one slump value in current time does not conform with the target slump or target slump range and/or the at least one air content value in current time does not conform with the target air content or target air content range; and

introducing into the concrete mix contained in the concrete mixer drum, one of at least two compositionally different additives comprising;

at least one chemical admixture for modifying air content in the concrete mix, wherein the at least one chemical admixture for modifying air content in the concrete mix comprises at least one air entraining admixture, at least one air detraining admixture, or mixture of at least one air entraining admixture and at least one air detraining admixture; and

at least one cement dispersant for modifying slump of the concrete mix, said at least one cement dispersant comprising at least one polymeric dispersant, water, or a mixture of said at least one polymeric dispersant and water; and

introducing the at least one chemical admixture for modifying air content in the concrete mix and/or at least one cement dispersant being achieved by computer processor unit-controlled valve system in accordance with the computer processor unit accessed memory, the aforementioned memory having at least four sets of data correlations comprising the effect of;

(i) the cement dispersant on slump of the concrete mix;

(ii) the at least one chemical admixture for modifying air content in the concrete mix on air content;

(iii) the at least one chemical admixture for modifying air content in the concrete mix on the slump of the concrete mix; and

(iv) the cement dispersant on air content of the concrete mix.