Method of promoting adhesion and bonding of structures and structures produced thereby

• US 8,764,929 B2
• Filed: 03/22/2011
• Issued: 07/01/2014
• Est. Priority Date: 03/22/2011
• Status: Active Grant

• Current Assignee: The Boeing Co.
• Original Assignee: The Boeing Co.
• Inventors: Dan-Jumbo, Eugene A., Baldwin, Joel P.
• Primary Examiner(s): Dunn, Tom
• Assistant Examiner(s): Hoover, Matthew
• Application Number:
  US13/069,373
• Publication Number:
  US 20120244360A1
• Time in Patent Office: 1,197 Days
• Field of Search: 156/60, 156/281, 156/285, 156/286, 295/92, 294/28, 294/60
• US Class Current: 156/285
• CPC Class Codes: C09J 2463/00 Presence of epoxy resin
• CPC Class Codes: C09J 2479/08 polyimide
• CPC Class Codes: C09J 5/02 involving pretreatment of the surfaces to be joined
• CPC Class Codes: Y10T 156/10 Methods of surface bonding and/or assembly therefor
• CPC Class Codes: Y10T 29/49 Method of mechanical manufacture
• CPC Class Codes: Y10T 29/49826 Assembling or joining
• CPC Class Codes: Y10T 29/49888 Subsequently coating
• CPC Class Codes: Y10T 428/31511 Of epoxy ether
• CPC Class Codes: Y10T 428/31544 Addition polymer is perhalogenated
• CPC Class Codes: Y10T 428/31678 Of metal
• CPC Class Codes: Y10T 428/31721 Of polyimide

Abstract

The disclosure provides in one embodiment a method of promoting adhesion on a composite surface. The method comprises providing a composite structure having at least one composite surface to be bonded. The method further comprises preparing the at least one composite surface. The method further comprises providing a chemical derivatization compound containing active functional groups that promote adhesion. The method further comprises depositing the chemical derivatization compound on the prepared composite surface to form a functional group-adhesive promoter derivatized layer. The method further comprises applying an adhesive layer to the derivatized layer. The method further comprises heat curing the adhesive layer to result in a bond with another structure made of a composite, a metal, or a combination thereof.

Claims

1. A method of promoting adhesion on a composite surface, the method comprising:

providing a composite structure having at least one composite surface to be bonded;

preparing the at least one composite surface;

providing a chemical derivatization compound containing active molecular functional groups that promote adhesion and detect adhesion mechanisms, wherein the chemical derivatization compound is selected from the group consisting of tetrafluoroaceticanhydride (TFAA), pentafluorophenol, allyl pentafluorobenzene, tridecafluorononyl maleimide, and glycidyloctafluoropentyl ether;

depositing the chemical derivatization compound on the prepared composite surface and activating the molecular functional groups through chemical derivatization reaction mechanisms to form a molecular functional group-adhesive promoter derivatized layer on the prepared composite surface as a bonding agent, the chemical derivatization reaction mechanisms creating reactive molecular functional groups on the prepared composite surface, and the chemical derivatization reaction mechanisms selected from the group consisting of bromination, silination, and thionation;

applying an adhesive layer to the derivatized layer; and

,

heat curing the adhesive layer to result in a bond with another structure made of a composite, a metal, or a combination thereof.

2. The method of claim 1, wherein the composite structure is made of a polymeric composite material selected from the group comprising bismaleimides (BMI), epoxies, and polyimides.

3. The method of claim 1, wherein the composite structure comprises bismaleimide (BMI), and the chemical derivatization compound activates carbon-carbon double bond molecular functional groups on the composite surface of the bismaleimide.

4. The method of claim 1, wherein the composite surface is prepared with one or more surface preparation treatments selected from the group comprising solvent wiping, abrading, grit blasting, sanding, sandblasting, chemical cleaning, and chemical etching.

5. The method of claim 1, wherein the chemical derivatization compound is deposited via chemical vapor deposition or vacuum deposition.

6. The method of claim 1, wherein the prepared composite surface is exposed to a vapor phase chemical derivatization compound containing selected molecular functional groups, wherein selection of the molecular functional groups is based on a resin formulation of the composite structure.

7. The method of claim 1, wherein the resulting bond is selected from the group comprising a structural bond and a repair bond.

8. The method of claim 1, wherein the composite structure and the other structure made of the composite, the metal, or the combination thereof, are aircraft structures.

9. A method for structural bonding of structures comprising:

providing a first structure made of a composite material and a second structure made of a composite material, a metal, or a combination thereof;

preparing a surface to be bonded on each of the first and second structures to form a first prepared surface and a second prepared surface;

providing a chemical derivatization compound containing active molecular functional groups that promote adhesion and detect adhesion mechanisms, wherein the chemical derivatization compound is selected from the group consisting of tetrafluoroaceticanhydride (TFAA), pentafluorophenol, allyl pentafluorobenzene, tridecafluorononyl maleimide, and glycidyloctafluoropentyl ether;

depositing the chemical derivatization compound on each of the first and second prepared surfaces and activating the molecular functional groups through chemical derivatization reaction mechanisms to form a first molecular functional group-adhesive promoter derivatized layer on the first prepared composite surface as a first bonding agent and a second molecular functional group-adhesive promoter derivatized layer on the second prepared composite surface as a second bonding agent, the chemical derivatization reaction mechanisms creating reactive molecular functional groups on the first and second prepared surfaces, and the chemical derivatization reaction mechanisms selected from the group consisting of bromination, silination, and thionation;

applying an adhesive layer to at least one of the derivatized layers of the first and second molecular functional group-adhesive promoter derivatized layers;

joining the first and second structures together with the adhesive layer and the first and second molecular functional group-adhesive promoter derivatized layers therebetween; and

,

heat curing the adhesive layer to the joined first and second structures to form a structural bond between the first and second structures.

10. The method of claim 9, wherein the composite material is selected from the group comprising bismaleimides (BMI), epoxies, and polyimides.

11. The method of claim 9, wherein the surface to be bonded is prepared with one or more surface preparation treatments selected from the group comprising solvent wiping, abrading, grit blasting, sanding, sandblasting, chemical cleaning, and chemical etching.

12. The method of claim 9, wherein the chemical derivatization compound is deposited via chemical vapor deposition or vacuum deposition.

13. The method of claim 9, wherein the first and second structures are aircraft structures.

14. A method for structural bonding of polymeric composite structures of an aircraft, the method comprising:

providing a first polymeric composite aircraft structure and a second polymeric composite aircraft structure;

preparing a surface to be bonded on each of the first and second polymeric composite aircraft structures to form a first prepared surface and a second prepared surface;

providing a chemical derivatization compound containing active molecular functional groups that promote adhesion and detect adhesion mechanisms, wherein the chemical derivatization compound is selected from the group consisting of tetrafluoroaceticanhydride (TFAA), pentafluorophenol, allyl pentafluorobenzene, tridecafluorononyl maleimide, and glycidyloctafluoropentyl ether;

depositing the chemical derivatization compound on each of the first and second prepared surfaces and activating the molecular functional groups through chemical derivatization reaction mechanisms to form a first molecular functional group-adhesive promoter derivatized layer on the first prepared composite surface as a first bonding agent and a second molecular functional group-adhesive promoter derivatized layer on the second prepared composite surface as a second bonding agent, the chemical derivatization reaction mechanisms creating reactive molecular functional groups on the first and second prepared surfaces, and the chemical derivatization reaction mechanisms selected from the group consisting of bromination, silination, and thionation;

applying an adhesive layer to at least one of the first and second molecular functional group-adhesive promoter derivatized layers;

joining the first and second polymeric composite aircraft structures together with the adhesive layer and the first and second molecular functional group-adhesive promoter derivatized layers therebetween; and

,

heat curing the adhesive to the joined first and second polymeric composite aircraft structures to form an aircraft structural bond between the first and second polymeric composite aircraft structures.

15. The method of claim 14, wherein the first and second polymeric composite structures are made of a material selected from the group comprising bismaleimides (BMI), epoxies, and polyimides.

16. The method of claim 14, wherein the surface to be bonded is prepared with one or more surface preparation treatments selected from the group comprising solvent wiping, abrading, grit blasting, sanding, sandblasting, chemical cleaning, and chemical etching.