Ammonia storage system

• US 8,771,598 B2
• Filed: 12/15/2009
• Issued: 07/08/2014
• Est. Priority Date: 01/02/2009
• Status: Active Grant

• Current Assignee: Sensirion AG (Sensirion Holding AG)
• Original Assignee: Sensirion AG (Sensirion Holding AG)
• Inventors: Mayer, Felix, Brgi, Lukas, Hornung, Mark, Gerner, Pascal
• Primary Examiner(s): Mui, Christine T
• Application Number:
  US12/653,490
• Publication Number:
  US 20100172816A1
• Time in Patent Office: 1,666 Days
• Field of Search: 422/82.12, 422/102, 422/103
• US Class Current: 422/82.12
• CPC Class Codes: F01N 2560/023 for measuring or detecting HC
• CPC Class Codes: F01N 2560/025 for measuring or detecting O2, e.g. lambda sensors
• CPC Class Codes: F01N 2610/14 Arrangements for the supply of substances, e.g. conduits
• CPC Class Codes: F01N 2610/1406 Storage means for substances, e.g. tanks or reservoirs
• CPC Class Codes: F01N 3/2066 Selective catalytic reduction [SCR]
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

A system for storing ammonia comprises gas detector that is able to detect gases other than ammonia. The system further comprises thermally activatable ammonia stores, which can be activated to release ammonia upon heating. When the ammonia stores are not heated, the system is below ambient pressure and any leak will cause external gas to enter the system. Therefore, the gas detector is used to detect the presence of such external gas, which allows to detect leaks. The gas detector may be embodied as a thermal detector using a single heater and two temperature sensors for detecting a gas flow as well as external gas.

Claims

1. An ammonia storage system comprising:

an ammonia containing section;

a thermally activatable ammonia store disposed in said ammonia containing section;

a valve, wherein opening of the valve allows ammonia gas to flow out of the ammonia containing section through the valve and wherein when said valve is closed, in the absence of a leak, the ammonia containing section contains pure ammonia;

a duct of the ammonia containing section connecting the ammonia store to the valve;

a heater for thermally activating said ammonia store, wherein thermal activation of the ammonia store by the heater releases ammonia into said ammonia containing section, and further comprising

a gas detector disposed in the ammonia containing section at the duct and configured to detect a thermal conductivity of gas within the ammonia containing section;

wherein the system is adapted to issue an alert if the detector detects a thermal conductivity different from the thermal conductivity of pure ammonia.

2. The ammonia storage system of claim 1 wherein the gas detector is adapted for measuring a gas flow in said duct.

3. The ammonia storage system of claim 1 wherein the gas detector comprises a heater, and wherein said heater is adapted for measuring a gas flow in said duct.

4. The ammonia storage system of claim 3 wherein the gas detector comprises at least one temperature sensor adapted to measure a temperature change induced by said heater.

5. The ammonia storage system of claim 4 further comprising at least a first and a second temperature sensor located at different positions in respect to said heater with said heater being arranged between said first and second temperature sensor such that one of said temperature sensors is arranged upstream and the other one of said temperature sensors is arranged downstream of said heater.

6. The ammonia storage system of claim 5 further comprising a control unit designed for calculating said gas flow by using a difference between signals from said first and said second temperature sensor and designed for detecting the presence of a gas other than ammonia from the signal of at least one of said temperature sensors.

7. The ammonia storage system of claim 6 wherein said control unit is designed for detecting the presence of a gas other than ammonia by using a sum of signals from said first and said second temperature sensor.

8. The ammonia storage system of claim 2 further comprising a system controller adapted to detect a leak downstream from said flow detector by detecting a non-zero flow at said flow detector when said valve is closed.

9. A method for operating the ammonia storage system of claim 1 wherein said gas detector is operated at least when said ammonia store is not being activated in order to detect said gas other than ammonia.

10. The method of claim 9 wherein a thermal flow detector is a duct of said ammonia containing section is used for measuring an ammonia flow in said duct as well as for detecting said gas other than ammonia.

11. The method of claim 10 wherein said flow detector is used for measuring a leak downstream from said flow detector by detecting a non-zero flow or a downstream-upstream flow.

12. Use of the system of claim 1 as an ammonia source in a vehicle for controllably releasing ammonia in a Selective Catalytic Reduction (SCR) process for the catalytic decomposition of NO_x compounds.

13. The ammonia storage system of claim 1, wherein the storage system is provided in a vehicle for controllably releasing ammonia in a Selective Catalytic Reduction (SCR) process for the catalytic decomposition of NO_x compounds.

15. The ammonia storage system of claim 1, wherein said thermally activatable ammonia store comprises ammonia physically or chemically bound in a solid storage matrix.

16. The ammonia storage system of claim 2, wherein said thermally activatable ammonia store comprises ammonia physically or chemically bound in a solid storage matrix.

17. The ammonia storage system of claim 3, wherein said thermally activatable ammonia store comprises ammonia physically or chemically bound in a solid storage matrix.

18. The ammonia storage system of claim 7, wherein said thermally activatable ammonia store comprises ammonia physically or chemically bound in a solid storage matrix.

19. The ammonia storage system of claim 8, wherein said thermally activatable ammonia store comprises ammonia physically or chemically bound in a solid storage matrix.

14. An ammonia storage system comprising:

an ammonia containing section;

a thermally activatable ammonia store disposed in said ammonia containing section;

a valve, wherein opening of the valve allows ammonia gas to flow out of the ammonia containing section through the valve and wherein when said valve is closed, in the absence of a leak, the ammonia containing section contains pure ammonia;

a duct of the ammonia containing section connecting the ammonia store to the valve;

a heater for thermally activating said ammonia store, wherein thermal activation of the ammonia store by the heater releases ammonia into said ammonia containing section, and further comprising

a gas detector disposed in the ammonia containing section at the duct,

wherein said gas detector is adapted to detect the presence of a gas other than ammonia in said ammonia containing section by measuring a heat capacity of gas within the ammonia containing section.

20. The ammonia storage system of claim 14, wherein said thermally activatable ammonia store comprises ammonia physically or chemically bound in a solid storage matrix.