Low-bandgap, monolithic, multi-bandgap, optoelectronic devices

• US 8,772,623 B2
• Filed: 10/30/2012
• Issued: 07/08/2014
• Est. Priority Date: 05/21/2002
• Status: Active Grant

• Current Assignee: Alliance For Sustainable Energy LLC
• Original Assignee: Alliance For Sustainable Energy LLC
• Inventors: Wanlass, Mark W., Carapella, Jeffrey J.
• Primary Examiner(s): Mowla, Golam
• Application Number:
  US13/664,142
• Publication Number:
  US 20130112244A1
• Time in Patent Office: 616 Days
• Field of Search: 136/249, 136/255, 136/256, 136/261, 136/262, 438/37, 438/57, 438/93, 438/98, 438/705, 438/718, 438/745, 438/752, 438/753, 257/53, 257/184, 257/190, 257/191, 257/200, 257/201
• US Class Current: 136/249
• CPC Class Codes: H01L 31/043 Mechanically stacked PV cells
• CPC Class Codes: H01L 31/046 PV modules composed of a plurality of thin film solar cells deposited on the same substrate
• CPC Class Codes: H01L 31/0475 PV cell arrays made by cells in a planar, e.g. repetitive, configuration on a single semiconductor substrate; PV cell microarrays PV modules composed of a plurality of thin film solar cells deposited on the same substrate H01L31/046
• CPC Class Codes: H01L 31/0687 Multiple junction or tandem solar cells
• CPC Class Codes: H01L 31/06875 inverted grown metamorphic [IMM] multiple junction solar cells, e.g. III-V compounds inverted metamorphic multi-junction cells
• CPC Class Codes: Y02E 10/544 Solar cells from Group III-V materials

Abstract

Low bandgap, monolithic, multi-bandgap, optoelectronic devices (10), including PV converters, photodetectors, and LED'"'"'s, have lattice-matched (LM), double-heterostructure (DH), low-bandgap GaInAs(P) subcells (22, 24) including those that are lattice-mismatched (LMM) to InP, grown on an InP substrate (26) by use of at least one graded lattice constant transition layer (20) of InAsP positioned somewhere between the InP substrate (26) and the LMM subcell(s) (22, 24). These devices are monofacial (10) or bifacial (80) and include monolithic, integrated, modules (MIMs) (190) with a plurality of voltage-matched subcell circuits (262, 264, 266, 270, 272) as well as other variations and embodiments.

Claims

1. A monolithic, multi-bandgap, photovoltaic converter, comprising:

a first subcell comprising GaInAs(P) with a first bandgap and a first lattice constant;

a second subcell comprising GaInAs(P) with a second bandgap and a second lattice constant, wherein the second bandgap is less than the first bandgap and the second lattice constant is greater than the first lattice constant, and further, wherein the second lattice constant is equal to a lattice constant of a InAs_yP_1-y alloy with a bandgap greater than the first bandgap; and

a lattice constant transition material positioned between the first subcell and the second subcell, said lattice constant transition material comprising InAs_yP_1-y alloy with a lattice constant that changes gradually from the first lattice constant to the second lattice constant.

2. The monolithic, multi-bandgap, photovoltaic converter of claim 1, wherein the lattice constant transition material is grown epitaxially on the first subcell with a gradually increasing value for y.

3. The monolithic, multi-bandgap, photovoltaic converter of claim 1, wherein the second subcell is grown epitaxially on the lattice constant transition material,

4. The monolithic, multi-bandgap, photovoltaic converter of claim 1, wherein the first subcell is a lattice-matched, double-heterostructure, comprising homojunction layers of GaInAs(P) clad by InAs_yP_1-y cladding layers wherein the InAs_yP_1-y cladding has a value for y in a range of o<

y<

1, such the InAs_yP_1-y cladding layers of the first subcell have a lattice constant equal to the first lattice constant.

5. The monolithic, multi-bandgap, photovoltaic converter of claim 4, wherein the second subcell is a lattice-matched, double-heterostructure comprising homojunction layers of GaInAs(P) clad by InAs_yP_1-y cladding layers, wherein the InAs_yP_1-y cladding has a value for y in a range of o<

y<

1, such that the InAs_yP_1-y cladding layer of the second subcell have a lattice constant equal to the second lattice constant.

6. The monolithic, multi-bandgap, photovoltaic converter of claim 1, including a InP substrate, and wherein the first subcell is grown epitaxially on the InP substrate.

7. The monolithic, multi-bandgap, photovoltaic converter of claim 1, including a tunnel junction positioned between the first subcell and the second subcell.

8. The monolithic, multi-bandgap, photovoltaic converter of claim 7, wherein the tunnel junction is positioned between the first subcell and the lattice constant transition layer.

9. The monolithic, multi-bandgap, photovoltaic converter of claim 1, wherein the lattice constant of the lattice constant transition material is graded.

10. The monolithic, multi-bandgap, photovoltaic converter of claim 1, wherein the lattice constant of the lattice constant transition material changes in steps of multiple, discrete, increments.

11. The monolithic, multi-bandgap, photovoltaic converter of claim 1, wherein the first bandgap is 0.74 eV.

12. The monolithic, multi-bandgap, photovoltaic converter of claim 6, wherein the first subcell is grown epitaxially on a front surface of the InP substrate, the lattice constant transition layer is grown epitaxially on a back surface of the InP substrate, and the second subcell is grown epitaxially on the lattice constant transition layer.

13. The monolithic, multi-bandgap, photovoltaic converter of claim 12, wherein the InP substrate is doped with deep acceptor atoms to make the substrate more electrically insulating than InP, which is not doped with deep acceptor atoms.

14. The monolithic, multi-bandgap, photovoltaic converter of claim 1, including a InP substrate positioned between the first subcell and the second subcell.

15. The monolithic, multi-bandgap, photovoltaic converter of claim 14, wherein the InP substrate is positioned between the first subcell and the lattice constant transition material.

16. The monolithic, multi-bandgap, photovoltaic converter of claim 1, including an isolation layer positioned between the first subcell and the second subcell.

17. The monolithic, multi-bandgap, photovoltaic converter of claim 16, wherein the isolation layer is positioned between the first subcell and the lattice constant transition material.

18. The monolithic, multi-bandgap, photovoltaic converter of claim 16, including a InP substrate positioned between the first subcell and the second subcell.

19. The monolithic, multi-bandgap, photovoltaic converter of claim 18, wherein the InP substrate is positioned between the second subcell and the isolation layer.

20. The monolithic, multi-bandgap, photovoltaic converter of claim 18, wherein the InP substrate is positioned between the first subcell and the isolation layer.

21. The monolithic, multi-bandgap, photovoltaic converter of claim 14, including a first isolation layer positioned between the InP substrate and the first subcell, and including a second isolation layer positioned between the InP substrate and the second subcell.

22. A monolithic, multi-bandgap, photovoltaic converter, comprising:

a InP substrate with a substrate lattice constant;

a first subcell comprising GaInAs(P) with a first bandgap and a first lattice constant, wherein the first lattice constant is greater than the substrate lattice constant;

a lattice constant transition material positioned between the InP substrate and the first subcell, said lattice constant transition material comprising InAs_yP_1-y alloy with a lattice constant that changes from the substrate lattice constant to the first lattice constant; and

a second subcell comprising GaInAs(P) positioned behind the first subcell, said GaInAs(P) of the second cell having a second bandgap, which is less than the first bandgap, and a second lattice constant.

23. The monolithic, multi-bandgap, photovoltaic converter of claim 22, wherein the second lattice second lattice constant is equal to the first lattice constant.