Microcoil NMR for downhole microfluidics platform

• US 8,773,125 B2
• Filed: 12/29/2010
• Issued: 07/08/2014
• Est. Priority Date: 12/29/2010
• Status: Active Grant

• Current Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Original Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Inventors: Hopper, Timothy, Hurlimann, Martin, Song, Yi-Qiao
• Primary Examiner(s): Koval, Melissa
• Assistant Examiner(s): PATEL, RISHI R
• Application Number:
  US12/981,116
• Publication Number:
  US 20120169334A1
• Time in Patent Office: 1,287 Days
• Field of Search: 324/303, 324/309, 324/318, 324/321, 600/411
• US Class Current: 324/303
• CPC Class Codes: G01N 24/081 Making measurements of geologic samples, e.g. measurements of moisture, pH, porosity, permeability, tortuosity or viscosity
• CPC Class Codes: G01R 33/302 Miniaturized sample handling arrangements for sampling small quantities, e.g. flow-through microfluidic NMR chips
• CPC Class Codes: G01R 33/34007 Manufacture of RF coils, e.g. using printed circuit board technology; additional hardware for providing mechanical support to the RF coil assembly or to part thereof, e.g. a support for moving the coil assembly relative to the remainder of the MR system
• CPC Class Codes: G01R 33/34053 Solenoid coils; Toroidal coils
• CPC Class Codes: G01R 33/3635 Multi-frequency operation
• CPC Class Codes: G01R 33/445 MR involving a non-standard magnetic field B0, e.g. of low magnitude as in the earth's magnetic field or in nanoTesla spectroscopy, comprising a polarizing magnetic field for pre-polarisation, B0 with a temporal variation of its magnitude or direction such as field cycling of B0 or rotation of the direction of B0, or spatially inhomogeneous B0 like in fringe-field MR or in stray-field imaging

Abstract

Methods and related apparatuses of a downhole micro nuclear magnetic resonance (NMR) device having a resonant tuning (LC) circuit for use in a formation for collecting NMR signals from a fluid in the formation while under downhole pressures and temperatures. The downhole micro NMR device includes: a micro tube for the flowing fluid to flow therethrough; at least one magnet disposed about the micro tube; and at least one micro RF coil structured and arranged approximate to the micro tube and tuned to a Larmor frequency corresponding to a applied magnetic field from the at least one magnet.

Claims

1. A downhole tool for a fluid, the downhole tool comprising:

a nuclear magnetic resonance (NMR) device that comprises;

a micro tube for containing the fluid;

at least one magnet configured to apply a static magnetic field to at least a portion of the fluid within the micro tube, wherein the at least one magnet comprises at least two magnets that each apply different magnetic field strengths along the micro tube; and

at least one coil coupled to a tuning circuit and configured to apply radio frequency (RF) pulses to the portion of the fluid within the micro tube, wherein the coil and circuit are tuned to a Larmor frequency that corresponds to the static magnetic field applied by the at least one magnet.

2. The downhole tool of claim 1, wherein at least one magnet includes angled poles that create a gradient within the applied magnetic field, wherein the gradient is in a direction of fluid flow within the micro tube.

3. The downhole tool of claim 1, wherein at least one magnet is configured to apply a homogeneous static magnetic field.

4. The downhole tool of claim 1, wherein at least one magnet is configured to apply a static magnetic field with at least two distinct regions of substantially different magnetic field strengths.

5. The downhole tool of claim 1, wherein the NMR device is a NMR probe that is controlled by a spectrometer and powered by a power supply.

6. The downhole tool of claim 1, wherein the power used to power the NMR device is less than 75 mW.

7. The downhole tool of claim 1, wherein the at least one coil comprises a metal or a metal alloy.

8. The downhole tool of claim 1, wherein the tuning circuit includes a capacitor and an inductor.

9. The downhole tool of claim 1, wherein the at least one coil comprises at least two coils, wherein each coil is configured to apply RF pulses at spatially separate locations along the micro tube and each coil is tuned to a different Larmor frequency.

10. The downhole tool of claim 9, wherein electrical inductances of the at least two coils are decoupled from each other.

11. The downhole tool of claim 1, wherein the static magnetic field strength is between 0.1 to 2 T.

12. The downhole tool of claim 1, wherein the NMR device comprises one or more coil shielding devices.

13. The downhole tool of claim 1, wherein the at least one coil is a solenoid-shaped coil encompassing a volume along the micro tube.

14. The downhole tool of claim 1, wherein the at least one coil is fabricated on the micro tube.

15. The downhole tool of claim 1, wherein the at least one coil is spiral and substantially planar.

16. The downhole tool of claim 8, wherein the capacitor comprises a variable capacitor.

17. The downhole tool of claim 1, wherein the micro tube has a diameter from 100 microns to 5 millimeters.

18. The downhole tool of claim 1, wherein the micro tube has a length of less than 50 mm.

19. The downhole tool of claim 1, wherein the micro tube comprises a capillary tube.

20. The downhole tool of claim 1, wherein the micro tube comprises a substrate that defines a channel.

21. The downhole tool of claim 20, wherein the substrate comprises at least two pieces that are attached together to form the channel.

22. The downhole tool of claim 20, wherein the substrate comprises an electrically insulating material.

23. The downhole tool of claim 1, further comprising a fluid delivery system in fluid communication with the micro tube.

24. The downhole tool of claim 1, wherein at least one magnet is an array of magnets.

25. The downhole tool of claim 1, wherein at least one magnet is a permanent magnet.

26. The downhole tool of claim 1, wherein the micro tube comprises a substrate that defines a channel and the at least one magnet is disposed on the substrate.

27. The downhole tool of claim 1, wherein at least one magnet comprises a permeable magnetic material.

28. The downhole tool of claim 1, wherein at least a portion of the NMR device is constructed using a substrate and micro fabrication techniques.

29. The downhole micro NMR device of claim 1, wherein the downhole tool comprises a downhole fluid sampling tool.

30. A method for making a downhole nuclear magnetic resonance (NMR) measurement of a fluid using a NMR device, the method comprising:

flowing the fluid into a micro tube of the NMR device;

applying a static magnetic field to at least a portion of the fluid within the micro tube;

wherein applying the static magnetic field comprises applying to the fluid two spatially separate static magnetic fields having different magnetic field strengths;

applying radio frequency (RF) pulses to the portion of the fluid within the micro tube;

detecting magnetic resonance signals generated within the fluid; and

analyzing the detected magnetic resonance signals to extract information about the fluid.

31. The downhole method of claim 30, wherein the applied static magnetic field comprises a homogeneous static field.

32. The downhole method of claim 30, wherein the applied static magnetic field comprises a gradient static field.

33. The downhole method of claim 30, wherein the static magnetic field includes at least two distinct regions of substantially different magnetic field strengths.

34. The downhole method of claim 30, wherein the NMR device is powered by less than 1 mW.

35. The downhole method of claim 30, wherein the RF pulses are applied at spatially separate locations along the micro tube and each of the RF pulses, at spatially separate locations, are applied at different Larmor frequencies.