Concentrated lamellar liquid personal cleansing composition

• US 8,778,910 B2
• Filed: 12/07/2012
• Issued: 07/15/2014
• Est. Priority Date: 12/07/2012
• Status: Active Grant

• Current Assignee: Conopco (Unilever PLC)
• Original Assignee: Conopco (Unilever PLC)
• Inventors: Hu, Yuntao Thomas, Hermanson, Kevin David, Dave, Rajendra Mohanlal, Shiloach, Anat, Moaddel, Teanoosh, Palla-Venkata, Chandra Sekhar, Yang, Lin, Early, James Andrew, Shutak, Alexander Kingston
• Primary Examiner(s): Hui, San-Ming
• Assistant Examiner(s): CALVILLO, Y JEANMARIE Z
• Application Number:
  US13/708,012
• Publication Number:
  US 20140162979A1
• Time in Patent Office: 585 Days
• Field of Search: None
• US Class Current: 514/63
• CPC Class Codes: A61K 2800/596 Mixtures of surface active compounds
• CPC Class Codes: A61K 8/0295 Liquid crystals
• CPC Class Codes: A61K 8/342 Alcohols having more than seven atoms in an unbroken chain
• CPC Class Codes: A61K 8/361 Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
• CPC Class Codes: A61K 8/442 substituted by amido group(s)
• CPC Class Codes: A61K 8/463 containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
• CPC Class Codes: A61K 8/92 Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
• CPC Class Codes: A61Q 19/10 Washing or bathing preparations
• CPC Class Codes: A61Q 5/02 Preparations for cleaning the hair

Abstract

The invention relates to concentrated liquid cleansing compositions in lamellar phase which possess a lotion-like appearance conveying signals of enhanced moisturization. The use of a specific ratio of synthetic anionic surfactant(s) and co-surfactant(s) to fatty acid(s) in a structured liquid product was found to improve lather production by moderating or eliminating the increase in viscosity upon dilution. In a further embodiment, specific small hydrophobic molecules were found to improve freeze/thaw stability and thereby cause the inventive composition to maintain noticeable moisturization signals.

Claims

1. An aqueous, lamellar structured, skin cleaning composition comprising:

a) about 15 to 40% by wt. of synthetic anion surfactant(s);

b) about 5 to 30% by wt. of co-surfactant(s) selected from the group of amphoteric or nonionic surfactants or blends thereof;

c) about 5 to 15% by wt. of C₁₂ to C₁₈ linear alkyl fatty acid(s);

d) wherein the synthetic anionic surfactant(s);

co-surfactant(s) ratio is about 0.5 to 3;

e) wherein the synthetic anionic surfactant(s) and co- surfactant(s) to C₁₂ to C₁₈ linear alkyl fatty acid(s) ratio is about 2 to 6; and

f) an effective amount of freeze-thaw stabilizer(s) selected from isooctanol, isotridecanol, isodecanol, polyoxyethylene(2)isooctylphenyl ether and blends thereof for maintaining at least 55% of the viscosity of the composition after one freeze-thaw cycle using the standard freeze-thaw test.

2. The composition of claim 1 wherein the viscosity either decreases continuously or increases by no more than 3 Pa.s as the composition is diluted with water at 40 C. during skin cleansing and rinsing by a consumer.

3. The composition of claim 1 wherein the pH is in the range of about 5 to 8.

4. The composition of claim 1 wherein the freeze-thaw stabilizer(s) are present in a total concentration of about 0.5 to 5% by wt.

5. The composition of claim 1 wherein the freeze-thaw stabilizer(s) have an HLB value of less than about 5.

6. The composition of claim 1 wherein the freeze-thaw stabilizer(s) have an effective molecular length of greater than about 5 but no greater than about 30 Angstroms.

7. The composition of claim 1 wherein the freeze-thaw stabilizer(s) have a melting point less than about 0°

C.

8. The composition of claim 1 further comprising about 0.5 to 3% by wt. of 12-Hydroxy stearic acid.

9. The composition of claim 1 further comprising non-occlusive emollients in the concentration range of about 0.5 to 25% by wt.

10. The composition of claim 9 wherein the non-occlusive emollients are selected from glycerin, 1, 3 butanediol, or blends thereof.

11. The composition of claim 1 further comprising occlusive emollients in the concentration range of about 0.5 to 25% by wt.

12. The composition of claim 11 wherein the occlusive emollients are selected from mineral oils, tri and diglyceride oils, silicone oils, Petrolatum, paraffin wax or blends thereof.

13. The composition of claim 1 wherein the synthetic anionic surfactants are selected from Sodium lauryl ether sulfate—

1EO, 2EO or 3EO, C12 acyl glycinate, Directly Esterified Fatty Isethionate (DEFI) or sodium trideceth sulfate or blends thereof.

14. The composition of claim 1 wherein the co-surfactant(s) are selected from cocamidopropyl betaine, sodium lauroyl amphoacetate, cocamidopropyl hydroxyl sultaine, alkylpoly glucoside or blends thereof.