Corn stillage oil derivatives

• US 8,779,172 B2
• Filed: 05/21/2010
• Issued: 07/15/2014
• Est. Priority Date: 05/22/2009
• Status: Active Grant

• Current Assignee: Cargill, Inc. (Agricultural Services Division)
• Original Assignee: Cargill, Inc. (Agricultural Services Division)
• Inventors: Lochel, Frank P.
• Primary Examiner(s): Cutliff, Yate K
• Application Number:
  US13/321,864
• Publication Number:
  US 20120065414A1
• Time in Patent Office: 1,516 Days
• US Class Current: 554/175
• CPC Class Codes: C11B 13/00 Recovery of fats, fatty oils or fatty acids from waste materials
• CPC Class Codes: C11B 3/02 by chemical reaction C11B3/003 takes precedence
• CPC Class Codes: C11B 3/14 with the use of indifferent gases or vapours, e.g. steam
• CPC Class Codes: C11C 3/006 by oxidation
• CPC Class Codes: Y02W 30/74 Recovery of fats, fatty oils, fatty acids or other fatty substances, e.g. lanolin or waxes

Abstract

Corn stillage oil derivatives having values for Gardner color of 10 or less and methods for making the corn stillage oil derivatives are disclosed. In one aspect, the corn stillage oil derivative comprises a heat bleached corn stillage oil. Preferably, the heat bleached corn stillage oil has a value for Gardner color of from 4 to 8. In another aspect, the corn stillage oil derivative comprises a blown corn stillage oil. Preferably, the blown corn stillage oil has a value for Gardner color of from 5 to 8.

Claims

1. A method for producing a low color corn stillage oil derivative, the method comprising the steps of:

(a) obtaining a corn stillage oil having a Gardner color of at least 12 and a viscosity of from 25 to 35 cSt at 40°

C.;

(b) heating the corn stillage oil to at least 90°

C. for a sufficient period of time to obtain a corn stillage oil derivative having a Gardner color of 10 or less.

2. The method of claim 1, wherein the oil is heated in step (b) to at least 105°

C., and the method farther comprises the step of;

(c) passing air through the heated corn stillage oil to produce a blown-corn stillage oil having a viscosity of at least 50 cSt at 40°

C.

3. The method of claim 2, wherein the blown-corn stillage oil exhibiting a viscosity at 100°

C. of at least 8 cSt.

4. The method of claim 2 wherein the blown-corn stillage oil from step (c) exhibits a viscosity at 40°

C. of at least 60 cSt and a viscosity at 100°

C. of at least 10 cSt.

5. The method of claim 2, wherein the corn stillage oil is heated to a temperature of from 95-115°

C. and step (c) comprises passing air through the heated oil for from 22 to 36 hours to obtain a blown-corn stillage oil having a viscosity of from 55 cSt to 140 cSt at 40 C and from 11 cSt to 14 cSt at 100 C, and wherein the blown-corn stillage oil has a Gardner color of from 5 to 8.

6. The method of claim 2, wherein the corn still oil of step (a) is a vacuum distilled corn stillage oil.

7. The method of claim 2, wherein a time required to pass air through the corn-stillage oil in step (c) to obtain a blown-corn stillage oil having a particular viscosity at 40°

C. is shorter than the time required to manufacture a blown soybean oil having equivalent viscosity under the same temperature and pressure conditions utilizing the same rate of passing air through the blown soybean oil as utilized for the blown corn stillage oil.

8. The method of claim 7, wherein the time required to obtain the blown-corn stillage oil is 25% less than the time to obtain the blown-soybean oil.

9. The method of claim 2, wherein the corn stillage oil has a titre of at least 4 wt % and wherein the blown-corn stillage oil contains 1 wt % or less titre.

10. The method of claim 1, wherein the corn stillage oil is heated during step (b) to from 240 to 270°

C. under a nitrogen blanket for a sufficient time to obtain a corn stillage oil derivative having a Gardner color of about 8 or less.

11. The method of claim 10, wherein the corn stillage oil is heated for from 45 to 60 minutes to obtain a Gardner color of from about 4 to about 8 in the corn stillage oil derivative.

12. The method of claim 10, wherein the corn stillage oil is at atmospheric pressure during heating step (b).

13. The method of claim 1, wherein the corn stillage oil derivative has at least 65 percent by weight triglycerides.

14. The method of claim 1, wherein the corn stillage oil has a titre of at least 4 wt % and wherein the corn stillage oil derivative has a titre of 1 wt % or less.

15. The method of claim 1, wherein the corn stillage oil derivative has viscosity of less than 40 cSt at 40°

C.

16. The method of claim 2, wherein the corn stillage oil comprises from 8 percent by weight to 16 percent by weight free fatty acids and the blown-corn stillage oil has at most 20 relative percent more free fatty acids than the corn stillage oil of step (a).

17. The method of claim 2, wherein the corn stillage oil comprises from 9 percent by weight to 15 percent by weight free fatty acids and the blown-corn stillage oil has at most 10 relative percent more free fatty acids than the corn stillage oil of step (a).

18. The method of claim 2, wherein the blown-corn stillage oil has equivalent free fatty acids as the corn stillage oil of step (a).

23. The method of claim 2, wherein air is sparged through the corn stillage oil in step (c) at a rate of from about 0.009 to 0.011 cubic feet per minute per pound oil.

19. A corn stillage oil derivative having a value of Gardner color of 10 or less.

20. The corn stillage oil derivative of claim 19, wherein the corn stillage oil derivative comprises a blown corn stillage oil having a value of Gardner color from about 5 to about 8.

21. The corn stillage oil derivative of claim 19, wherein the corn stillage oil derivative comprises a heat bleached corn stillage oil having a value of Gardner color from about 4 to about 8.

22. The corn stillage oil derivative of claim 19, wherein the corn stillage oil derivative has a viscosity at 40°

C. from about 50 cSt to about 250 cSt.

24. The corn stillage oil derivative of claim 19, wherein the corn stillage oil derivative has a viscosity at 40°

C. from about 60 cSt to about 225 cSt.