Flow in reinforced polyimide compositions

• US 8,784,719 B2
• Filed: 06/30/2011
• Issued: 07/22/2014
• Est. Priority Date: 06/30/2011
• Status: Active Grant

• Current Assignee: SHPP Global Technologies BV
• Original Assignee: SABIC Global Technologies BV (Government of Saudi Arabia)
• Inventors: Sinha, Reema, Bolvari, Anne, Yun, Zheng, Lingannaiah, Chandrashekhar, Kumanan, Anton, Ganguly, Anirban, Mitra, Susanta
• Primary Examiner(s): HEITBRINK, JILL LYNNE
• Application Number:
  US13/174,772
• Publication Number:
  US 20130001824A1
• Time in Patent Office: 1,118 Days
• Field of Search: 264/328.18, 264/331.16, 264/331.19, 522/111, 524/606
• US Class Current: 264/328.18
• CPC Class Codes: B29B 7/90 Fillers or reinforcements , e.g. fibres
• CPC Class Codes: C08K 7/02 Fibres or whiskers
• CPC Class Codes: C08K 7/14 Glass
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 79/08 Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors

Abstract

Reinforced polyimide compositions that include a reinforcing filler and a polyamide flow promoter improve flow promotion while maintaining other mechanical, thermal, flame and/or electrical properties of the compositions. The compositions may include an inorganic or organic reinforcing filler, a polyimide resin such as polyetherimide or polyamideimide and a small amount of an aromatic or aliphatic polyamide as the flow promoter. The resulting compositions may be used in thinner-wall applications while still retaining the advantageous physical properties of reinforced polyimide compositions not having the flow promoter. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

Claims

1. A reinforced polyimide composition comprising:

(a) from about 10 wt % to 60 wt % of a reinforcing filler;

(b) from about 1 wt % to about 10 wt % of a polyamide flow promoter; and

(c) weight % balance of a polyimide base resin;

wherein the polyimide base resin has a general formula of

2. The composition of claim 1, wherein the polyimide base resin comprises polyetherimide or polyamideimide, or a combination thereof.

3. The composition of claim 1, wherein the reinforcing filler comprises glass fiber, glass flake, glass bead, carbon fiber, or aramid fiber, or a combination thereof.

4. The composition of claim 1, wherein the polyamide flow promoter comprises nylon 6, nylon 66, polyphthalamide, nylon 11, nylon 610, nylon 410, nylon 1010, nylon 1012, or nylon 510, or a combination thereof.

5. The composition of claim 1, wherein the polyimide base resin comprises polyetherimide or polyamideimide, or a combination thereof;

wherein the reinforcing filler comprises glass fiber; and

wherein the polyamide flow promoter comprises polyphthalamide.

6. A reinforced polyimide composition comprising:

(a) a polyimide base resin wherein the polyimide base resin has a general formula of

7. The composition of claim 6, wherein the polyimide base resin comprises polyetherimide or polyamideimide, or a combination thereof.

8. The composition of claim 6, wherein the reinforcing filler comprises glass fiber, glass flake, glass beads, carbon fiber, or aramid fiber, or a combination thereof.

9. The composition of claim 6, wherein the polyamide flow promoter comprises nylon 6, nylon 66, polyphthalamide, nylon 11, nylon 610, nylon 410, nylon 1010, nylon 1012, or nylon 510, or a combination thereof.

10. The composition of claim 6, wherein the polyimide base resin comprises polyetherimide or polyamideimide, or a combination thereof;

wherein the reinforcing filler comprises glass fiber; and

wherein the polyamide flow promoter comprises polyphthalamide.

11. A method of increasing linear flow during injection molding of a reinforced polyimide composition, the method comprising combining a polyimide base resin, a reinforcing filler, and a polyamide flow promoter;

wherein the reinforcing filler is combined in an amount resulting in a resin;

filler ratio of from about 1;

2 to about 9;

1; and

wherein the polyamide flow promoter is combined in an amount effective such that the composition exhibits a linear flow during injection molding of at least about 10% greater than that of a reference reinforced polyimide composition consisting essentially of substantially the same proportions of the same polyimide base resin and the same reinforcing filler, in the absence of polyamide flow promoter, under substantially identical conditions;

wherein the polyimide base resin has a general formula of

12. The method of claim 11, wherein the polyimide base resin comprises polyetherimide or polyamideimide, or a combination thereof.

13. The method of claim 11, wherein the reinforcing filler comprises glass fiber, glass flake, glass beads, carbon fiber, or aramid fiber, or a combination thereof.

14. The method of claim 11, wherein the polyamide flow promoter comprises nylon 6, nylon 66, polyphthalamide, nylon 11, nylon 610, nylon 410, nylon 1010, nylon 1012, or nylon 510, or a combination thereof.

15. The method of claim 11, wherein the polyimide base resin comprises a polyetherimide or polyamideimide, or a combination thereof, wherein the reinforcing filler comprises glass fiber;

and wherein the polyamide flow promoter comprises a polyphthalamide.

16. A method of restoring injection molding linear flow loss in a reinforced polyimide composition, the method comprising adding, to a mixture of polyimide base resin and a reinforcing filler, a polyamide flow promoter in an amount sufficient to restore at least about 10% of flow loss observed when comparing injection molding linear flow rate of a reference reinforced polyimide composition consisting essentially of substantially the same proportions of the same polyimide base resin and the same reinforcing filler, in the absence of polyamide flow promoter, under substantially identical injection molding conditions, to injection molding linear flow rate of a substantially identical unfilled reinforced polyimide, in the absence of polyamide flow promoter, under substantially identical injection molding conditions;

wherein the polyimide base resin has a general formula of

17. The method of claim 16, wherein the polyimide base resin comprises polyetherimide or polyamideimide, or a combination thereof.

18. The method of claim 16, wherein the reinforcing filler comprises glass fiber, glass flake, glass beads, carbon fiber, or aramid fiber, or a combination thereof.

19. The method of claim 16, wherein the polyamide flow promoter comprises nylon 6, nylon 66, polyphthalamide, nylon 11, nylon 610, nylon 410, nylon 1010, nylon 1012, or nylon 510, or a combination thereof.

20. The method of claim 16, wherein the polyimide base resin comprises polyetherimide or polyamideimide, or a combination thereof;

wherein the reinforcing filler comprises glass fiber; and

wherein the polyamide flow promoter comprises polyphthalamide.