Lithium-ion battery
First Claim
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1. A lithium-ion battery comprising:
- a positive electrode comprising a primary active material and an auxiliary active material; and
a negative electrode comprising a negative active material;
wherein the auxiliary active material comprises a lithiated form of a material that does not include electrochemically cyclable lithium in the as-provided state; and
wherein the auxiliary active material is configured to provide a zero voltage crossing potential for the battery that is below a corrosion potential of a current collector of the negative electrode and above a decomposition potential of the primary active material, the auxiliary active material provided in an amount greater than or equal to a difference between an irreversible capacity of the primary active material and an irreversible capacity of the negative active material;
wherein the lithiated material that does not include electrochemically cyclable lithium in the as-provided state comprises an oxide of vanadium; and
wherein the negative active material comprises at least one material from the group consisting of carbon and lithium titanate.
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Abstract
A lithium-ion battery includes a positive electrode having a first active material and a second active material and a negative electrode including a third active material. The second active material includes a lithiated form of a material that does not include electrochemically cyclable lithium in the as-provided state.
238 Citations
15 Claims
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1. A lithium-ion battery comprising:
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a positive electrode comprising a primary active material and an auxiliary active material; and a negative electrode comprising a negative active material; wherein the auxiliary active material comprises a lithiated form of a material that does not include electrochemically cyclable lithium in the as-provided state; and wherein the auxiliary active material is configured to provide a zero voltage crossing potential for the battery that is below a corrosion potential of a current collector of the negative electrode and above a decomposition potential of the primary active material, the auxiliary active material provided in an amount greater than or equal to a difference between an irreversible capacity of the primary active material and an irreversible capacity of the negative active material; wherein the lithiated material that does not include electrochemically cyclable lithium in the as-provided state comprises an oxide of vanadium; and wherein the negative active material comprises at least one material from the group consisting of carbon and lithium titanate. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15)
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Specification