Electrolyte composition, photoelectric conversion element using the same, and dye-sensitized photovoltaic cell

• US 8,790,551 B2
• Filed: 06/16/2009
• Issued: 07/29/2014
• Est. Priority Date: 07/14/2003
• Status: Active Grant

• Current Assignee: Fujikura Limited
• Original Assignee: Fujikura Limited
• Inventors: Usui, Hiroki, Tanabe, Nobuo, Matsui, Hiroshi, Ezure, Tetsuya, Yanagida, Shozo
• Primary Examiner(s): HAN, KWANG S
• Application Number:
  US12/485,464
• Publication Number:
  US 20090293953A1
• Time in Patent Office: 1,869 Days
• Field of Search: None
• US Class Current: 252/518.1
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: H01B 1/04 mainly consisting of carbon-silicon compounds, carbon or silicon
• CPC Class Codes: H01B 1/122 Ionic conductors
• CPC Class Codes: H01G 9/2009 Solid electrolytes
• CPC Class Codes: H01G 9/2013 the electrolyte comprising ionic liquids, e.g. alkyl imidazolium iodide
• CPC Class Codes: H01G 9/2031 comprising titanium oxide, e.g. TiO2 H01G9/2036 takes precedence
• CPC Class Codes: H01G 9/2036 comprising mixed oxides, e.g. ZnO covered TiO2 particles
• CPC Class Codes: H01M 14/005 Photoelectrochemical storage cells light sensitive devices H01G9/20, semiconductors sensitive to light H01L31/00
• CPC Class Codes: H01M 2300/0091 in the form of mixtures
• CPC Class Codes: H10K 30/821 comprising carbon nanotubes
• CPC Class Codes: Y02E 10/542 Dye sensitized solar cells
• CPC Class Codes: Y10S 977/742 Carbon nanotubes, CNTs

Abstract

An electrolyte composition containing an ionic liquid and conductive particles, an electrolyte composition containing an ionic liquid and oxide semiconductor particles and optionally containing conductive particles, and an electrolyte composition containing an ionic liquid and insulating particles are provided. Furthermore, a photoelectric conversion element comprising: a working electrode, the working electrode comprising an electrode substrate and an oxide semiconductor porous film formed on the electrode substrate and sensitized with a dye; a counter electrode disposed opposing the working electrode; and an electrolyte layer made of these electrolyte compositions is provided.

Claims

1. An electrolyte composition comprising:

an ionic liquid including a room temperature molten salt containing a cation,

oxide semiconductor particles and

a redox pair, the electrolyte composition excluding an organic gelling agent

wherein;

a liquid electrolyte is defined as the electrolyte composition excluding the oxide semiconductor particles,

a rate of change in diffusion coefficients is not less than 25% and not more than 125%, the rate of change in the diffusion coefficients being defined as, and

a compounding amount of the oxide semiconductor particles is not less than 0.05% by weight and not more than 70% by weight with respect to a total amount of the electrolyte composition to make the electrolyte composition into a gel.

2. The electrolyte composition according to claim 1, further comprising conductive particles;

wherein the liquid electrolyte is the same as the electrolyte composition prior to addition of the oxide semiconductor and the conductive particles.

3. The electrolyte composition according to claim 1, wherein the oxide semiconductor particles are one member or a mixture of two or more members selected from the group consisting of TiO₂, SnO₂, WO₃, ZnO, ITO, BaTiO₃, Nb₂O₅, In₂O₃, ZrO₂, Ta₂O₅, La₂O₃, SrTiO₃, Y₂O₃, Ho₂O₃, Bi₂O₃, CeO₂, and Al₂O₃.

4. The electrolyte composition according to claim 3, wherein the TiO₂ is either one of or a mixture of titanium oxide nanotubes and titanium oxide nanoparticles.

5. The electrolyte composition according to claim 2, wherein the conductive particles comprises a material containing carbon as a main component.

6. The electrolyte composition according to claim 5, wherein the material containing carbon as a main component is one member or a mixture of two or more members selected from the group consisting of carbon nanotubes, carbon fibers, and carbon black.

7. The electrolyte composition according to claim 6, wherein the carbon nanotubes are either one of or a mixture of single-wall carbon nanotubes and multi-wall carbon nanotubes.

8. The electrolyte composition according to claim 2, wherein a total compounding amount of the oxide semiconductor particles and the conductive particles is not less than 0.05% by weight and not more than 70% by weight with respect to a total amount of the electrolyte composition.

9. The electrolyte composition according to claim 1, wherein a compounding amount of the oxide semiconductor particles is not less than 0.05% by weight and not more than 70% by weight with respect to the ionic liquid.

10. The electrolyte composition according to claim 2, wherein a total compounding amount of the oxide semiconductor particles and the conductive particles is not less than 0.05% by weight and not more than 70% by weight with respect to the ionic liquid.

11. A photoelectric conversion element comprising the electrolyte composition according to claim 1 contained as an electrolyte.

12. A photoelectric conversion element, comprising:

a working electrode, the working electrode comprising an electrode substrate and an oxide semiconductor porous film formed on the electrode substrate and sensitized with a dye;

a counter electrode disposed opposing the working electrode; and

an electrode layer made of the electrolyte composition according to claim 1 provided between the working electrode and the counter electrode.

13. A dye-sensitized photovoltaic cell, comprising:

a working electrode, the working electrode comprising an electrode substrate and an oxide semiconductor porous film formed on the electrode substrate and sensitized with a dye;

a counter electrode disposed opposing the working electrode; and

an electrolyte layer made of the electrolyte composition according to claim 1 provided between the working electrode and the counter electrode.

14. The electrolyte composition according to claim 5, wherein the material containing carbon as a main component includes carbon nanotubes, carbon fibers, carbon black, and the like.

15. The electrolyte composition according to claim 1, wherein a shift width of equilibrium potentials is not less than 18 mV and not more than 55 mV, the shift width of the equilibrium potentials being defined as {(an equilibrium potential of the redox pair in the electrolyte composition)−

(an equilibrium potential of the redox pair in the liquid electrolyte)}.