Chemical indicator obstruction detection system and method for an aquatic environment

• US 8,797,523 B2
• Filed: 12/13/2012
• Issued: 08/05/2014
• Est. Priority Date: 12/12/2011
• Status: Active Grant

• Current Assignee: Lamotte Chemical Products Company
• Original Assignee: Step Ahead Innovations, Inc.
• Inventors: Clark, James E.
• Primary Examiner(s): Toatley, Gregory J
• Assistant Examiner(s): Underwood, Jarreas C
• Application Number:
  US13/713,668
• Publication Number:
  US 20140016122A1
• Time in Patent Office: 600 Days
• Field of Search: 1124-127, 12391-2398, 151/5
• US Class Current: 356/237.1
• CPC Class Codes: A01K 63/04 Arrangements for treating water specially adapted to receptacles for live fish
• CPC Class Codes: C02F 1/008 Control or steering systems not provided for elsewhere in subclass C02F
• CPC Class Codes: C02F 2103/42 from bathing facilities, e.g. swimming pools
• CPC Class Codes: C02F 2209/005 Processes using a programmable logic controller [PLC]
• CPC Class Codes: C02F 2209/006 comprising a software program or a logic diagram
• CPC Class Codes: C02F 2209/008 comprising telecommunication features, e.g. modems or antennas
• CPC Class Codes: C02F 2209/06 pH
• CPC Class Codes: C02F 2209/14 NH3-N
• CPC Class Codes: C02F 2209/15 N03-N
• CPC Class Codes: C02F 2209/18 PO4-P
• CPC Class Codes: G01N 2021/758 using reversible reaction
• CPC Class Codes: G01N 2021/7786 Fluorescence
• CPC Class Codes: G01N 2021/7793 Sensor comprising plural indicators
• CPC Class Codes: G01N 21/15 Preventing contamination of the components of the optical system or obstruction of the light path
• CPC Class Codes: G01N 21/6428 Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes" in vivo A61B5/00; immunoassay G01N33/53
• CPC Class Codes: G01N 21/77 by observing the effect on a chemical indicator
• CPC Class Codes: G01N 21/78 producing a change of colour
• CPC Class Codes: G01N 21/8507 Probe photometers, i.e. with optical measuring part dipped into fluid sample
• CPC Class Codes: G01N 21/88 Investigating the presence of flaws or contamination
• CPC Class Codes: G01N 2201/127 Calibration; base line adjustment; drift compensation
• CPC Class Codes: G01N 31/22 : using chemical indicators G01N31/02 takes precedence
• CPC Class Codes: G01N 33/18 : Water
• CPC Class Codes: G02B 6/0001 : specially adapted for lighting devices or systems lighting or signalling on vehicles using light guides B60Q1/00; lighting devices for vehicle dashboards B60Q3/10; lighting devices for vehicle interior using light guides B60Q3/62; lighting devices mounted on the vehicle rear part using light guides F21S43/235; measuring arrangements having light conducting pointers G01D13/265; illumination of liquid crystal displays G02F1/1336; illuminated signs G09F13/00
• CPC Class Codes: Y10S 436/805 : Optical property
• CPC Class Codes: Y10S 436/809 : Multifield plates or multicontainer arrays
• CPC Class Codes: Y10T 436/11 : Automated chemical analysis
• CPC Class Codes: Y10T 436/115831 : Condition or time responsive
• CPC Class Codes: Y10T 436/12 : Condition responsive control
• CPC Class Codes: Y10T 436/173076 : Nitrite or nitrate
• CPC Class Codes: Y10T 436/173845 : Amine and quaternary ammonium
• CPC Class Codes: Y10T 436/174614 : Tertiary amine
• CPC Class Codes: Y10T 436/175383 : Ammonia
• CPC Class Codes: Y10T 436/193333 : In aqueous solution
• CPC Class Codes: Y10T 436/207497 : Molecular oxygen
• CPC Class Codes: Y10T 436/25 : including sample preparation
• CPC Class Codes: Y10T 436/25375 : Liberation or purification of sample or separation of material from a sample [e.g., filtering, centrifuging, etc.]

Abstract

A system and method for determining adverse conditions associated with a chemical indicator in an aquatic environment monitoring system in which reference illumination from an optical reader is used to illuminate a chemical indicator. Response from the reference illumination is used to determine a confidence value that can be part of an analysis associated with a measurement illumination response to produce a confidence adjustment instruction for possible action on the measured response value.

Claims

1. A method for determining error in a chemical indicator reading of an aquatic environment monitoring system, the method comprising:

illuminating a first region of a first chemical indicator of a chemical indicator apparatus with a first reference illumination from an optical reader of the aquatic environment monitoring system;

measuring a first reference response from the first reference illumination;

comparing the first reference response for a deviation from a predetermined trusted reference value stored in a memory of the aquatic environment monitoring system;

determining a first confidence value from said comparing the first reference response to the predetermined trusted reference value;

illuminating a second region of the first chemical indicator with a first measurement illumination;

measuring a first measurement response from the first measurement illumination; and

generating a confidence adjustment based on the first measurement response and the first confidence value.

2. A method according to claim 1, wherein said generating a confidence adjustment includes modifying a value of the first measurement response based on the first confidence value.

3. A method according to claim 2, wherein said determining a first confidence value includes determining a ratio of a value of the reference response to the predetermined trusted reference value and said generating a confidence adjustment includes modifying the value of the first measurement response based on the ratio.

4. A method according to claim 1, wherein said generating a confidence adjustment includes generating an alarm to a user of the aquatic environment monitoring system.

5. A method according to claim 1, wherein the first region is the same region as the second region.

6. A method according to claim 1, further comprising illuminating a third region of the first chemical indicator with a second measurement illumination and measuring a second measurement response from the second measurement illumination, wherein said generating a confidence adjustment includes removing a value of the first measurement response from a calculation of a final measurement value, the final measurement value including a value based on a value of the second measurement response.

7. A method according to claim 6, further comprising illuminating a fourth region of the first chemical indicator with a third measurement illumination and measuring a third measurement response from the third measurement illumination, the final measurement value including a value based on a value of the second measurement response and a value of the third measurement response.

8. A method according to claim 1, wherein said generating a confidence adjustment includes combining the first confidence value with one or more addition confidence values to determine a total confidence level for the measurement response.

9. A method according to claim 8, wherein the one or more additional confidence values are each based on one or more errors in the aquatic environment monitoring system, each of the one or more errors including an error value related to a condition selected from the group consisting of a degradation in a chemical indicator due to photo-aging, a degradation in a chemical indicator due to water-aging, an illumination imbalance related to an optical reader, a degradation of a light source of an optical reader, a displacement due to friction between a chemical indicator apparatus and a monitoring unit, an error intrinsic in a chemical indicator, and any combinations thereof.

10. A method according to claim 1, wherein the deviation from a predetermined trusted reference value includes a deviation due to one or more errors in the aquatic environment monitoring system, each of the one or more errors including an error value related to a condition selected from the group consisting of a physical contamination of the first chemical indicator, a physical contamination in water between an optical reader and the first chemical indicator, an error in distance between the chemical indicator apparatus and an optical reader, a damage to the first chemical indicator.

11. A method according to claim 1, wherein the first and second regions are different regions of the first chemical indicator, the method further comprising:

illuminating the second region with a second reference illumination;

measuring a second reference response from the second reference illumination;

illuminating a fifth region of the first chemical indicator with a fourth measurement illumination;

measuring a fourth measurement response from the fourth measurement illumination, wherein said determining a first confidence value further includes the second reference response and said generating a confidence adjustment is further based on the fourth measurement response.

12. A machine-readable hardware storage medium including machine-executable instructions for performing a for determining error in a chemical indicator reading of an aquatic environment monitoring system, the instructions comprising:

a set of instructions for illuminating a first region of a first chemical indicator of a chemical indicator apparatus with a first reference illumination from an optical reader of the aquatic environment monitoring system;

a set of instructions for measuring a first reference response from the first reference illumination;

a set of instructions for comparing the first reference response for a deviation from a predetermined trusted reference value stored in a memory of the aquatic environment monitoring system;

a set of instructions for determining a first confidence value from said comparing the first reference response to the predetermined trusted reference value;

a set of instructions for illuminating a second region of the first chemical indicator with a first measurement illumination;

a set of instructions for measuring a first measurement response from the first measurement illumination; and

a set of instructions for generating a confidence adjustment based on the first measurement response and the first confidence value.

13. A machine-readable hardware storage medium according to claim 12, wherein said set of instructions for generating a confidence adjustment includes a set of instructions for modifying a value of the first measurement response based on the first confidence value.

14. A machine-readable hardware storage medium according to claim 13, wherein said set of instructions for determining a first confidence value includes a set of instructions for determining a ratio of a value of the reference response to the predetermined trusted reference value and said set of instructions for generating a confidence adjustment includes a set of instructions for modifying the value of the first measurement response based on the ratio.

15. A machine-readable hardware storage medium according to claim 12, wherein said set of instructions for generating a confidence adjustment includes a set of instructions for generating an alarm to a user of the aquatic environment monitoring system.

16. A machine-readable hardware storage medium according to claim 12, wherein the first region is the same region as the second region.

17. A machine-readable hardware storage medium according to claim 12, further comprising:

a set of instructions for illuminating a third region of the first chemical indicator with a second measurement illumination;

a set of instructions for measuring a second measurement response from the second measurement illumination;

a set of instructions for illuminating a fourth region of the first chemical indicator with a third measurement illumination;

a set of instructions for measuring a third measurement response from the third measurement illumination, wherein said set of instructions for generating a confidence adjustment includes a set of instructions for removing a value of the first measurement response from a calculation of a final measurement value, the final measurement value including a value based on a value of the second measurement response and a value of the third measurement response.

18. A machine-readable hardware storage medium according to claim 12, wherein said set of instructions for generating a confidence adjustment includes a set of instructions for combining the first confidence value with one or more addition confidence values to determine a total confidence level for the measurement response, wherein the one or more additional confidence values are each based on one or more errors in the aquatic environment monitoring system, each of the one or more errors including an error value related to a condition selected from the group consisting of a degradation in a chemical indicator due to photo-aging, a degradation in a chemical indicator due to water-aging, an illumination imbalance related to an optical reader, a degradation of a light source of an optical reader, a displacement due to friction between a chemical indicator apparatus and a monitoring unit, an error intrinsic in a chemical indicator, and any combinations thereof.

19. A machine-readable hardware storage medium according to claim 12, wherein the deviation from a predetermined trusted reference value includes a deviation due to one or more errors in the aquatic environment monitoring system, each of the one or more errors including an error value related to a condition selected from the group consisting of a physical contamination of the first chemical indicator, a physical contamination in water between an optical reader and the first chemical indicator, an error in distance between the chemical indicator apparatus and an optical reader, a damage to the first chemical indicator.

20. A machine-readable hardware storage medium according to claim 12, wherein the first and second regions are different regions of the first chemical indicator, the method further comprising:

a set of instructions for illuminating the second region with a second reference illumination;

a set of instructions for measuring a second reference response from the second reference illumination;

a set of instructions for illuminating a fifth region of the first chemical indicator with a fourth measurement illumination;

a set of instructions for measuring a fourth measurement response from the fourth measurement illumination, wherein said set of instructions for determining a first confidence value is based on the second reference response and said set of instructions for generating a confidence adjustment is based on the fourth measurement response.