Integrated biofuel processing system

• US 8,802,905 B2
• Filed: 06/18/2010
• Issued: 08/12/2014
• Est. Priority Date: 06/19/2009
• Status: Expired due to Fees

• Current Assignee: Byogy Renewables, Inc., Texas A&M University System
• Original Assignee: Byogy Renewables, Inc., Texas A&M University System
• Inventors: El-Halwagi, Mahmoud M., Hall, Kenneth R., Spriggs, Harold Dennis
• Primary Examiner(s): MCCAIG, BRIAN A
• Application Number:
  US13/378,602
• Publication Number:
  US 20120095272A1
• Time in Patent Office: 1,516 Days
• Field of Search: 585/7, 585/14, 585240-242, 585/310, 585317-318, 585/324, 585/469, 585/638, 585/733, 44605-606
• US Class Current: 585/240
• CPC Class Codes: C07C 1/24 by elimination of water
• CPC Class Codes: C07C 11/02 Alkenes
• CPC Class Codes: C07C 11/04 Ethylene
• CPC Class Codes: C10G 2300/1003 Waste materials
• CPC Class Codes: C10G 2300/1011 Biomass
• CPC Class Codes: C10G 2300/1014 of vegetal origin
• CPC Class Codes: C10G 2400/02 Gasoline
• CPC Class Codes: C10G 2400/20 C2-C4 olefins
• CPC Class Codes: C10G 3/49 containing crystalline aluminosilicates, e.g. molecular sieves
• CPC Class Codes: C10G 50/00 Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
• CPC Class Codes: C10L 1/04 essentially based on blends of hydrocarbons
• CPC Class Codes: C12P 7/08 produced as by-product or from waste or cellulosic material substrate
• CPC Class Codes: Y02P 20/10 Process efficiency
• CPC Class Codes: Y02P 20/133 Renewable energy sources, e.g. sunlight

Abstract

A unique, integrated non-obvious pathway to convert biomass to biofuels using integration of chemical processes is described herein. The present invention is simple, direct, and provides for the shortest or minimum path between biomass and transportation fuels with alcohols as intermediates, while avoiding hydrogen use during processing. Furthermore, the present invention allows the manufacture of “drop-in” substitutable fuels to be used as-is without modifications instead of conventional petroleum based fuels. The processing described herein is done under mild conditions, under relatively low pressures and temperatures, and under non-corrosive conditions obviating use of special equipment or materials. The novel integration heat and mass generated during the process increases overall process efficiency and lowers financial costs for processing and capital equipment, manages environmental impact, and enables a relatively high degree of yield by an enhanced usage of fresh water and thermal energy in comparison to the amount of biomass processed.

Claims

1. An integrated biofuel production process comprising the steps of:

(a) converting a biomass to yield one or more alcohols and a residual biomass;

(b) gasifying the residual biomass to produce carbon monoxide, hydrogen or mixtures thereof, thereby producing thermal energy;

(c) synthesizing a liquid hydrocarbon fuel from the alcohols through a dehydration and an oligomerization reaction using at least a portion of the thermal energy produced by gasifying the residual biomass;

(d) converting the residual biomass into energy and/or one or more commercially viable co-products, wherein the co-products are selected from the group consisting of acids, ketones, alcohols, ethers, alkylbenzenes, fuel additives, biopolymers, proteins for animal and human consumption, and surfactants; and

(e) further comprising the step of combusting the carbon monoxide, the hydrogen, or mixtures thereof to produce heat and electricity, wherein the heat and electricity are recycled back into the process to perform step (c).

2. The process of claim 1, wherein at least a portion of the thermal energy produced by the gasification of the residual biomass is recycled back into the process to perform step (a).

3. The process of claim 1, wherein step (a) includes a pretreatment process and a hydrolysis process, wherein the pretreatment and hydrolysis processes are done by using a hot wastewater.

4. The process of claim 1, wherein the biomass is selected from the group consisting of grasses, trees, canes, animal waste, food waste, algae, municipal solid waste green waste, purpose grown non-food energy crops, harvest residuals, and other waste and crop biomass materials.

5. The process of claim 1, wherein the one or more alcohols generated in step (a) are further converted to one or more olefins by a dehydration reaction, wherein the one or more olefins are selected from the group consisting of ethylene, propylene, butene, iso-butylene, and combinations and modifications thereof.

6. The process of claim 5, wherein the one or more olefins undergo an oligomerization in an oligomerization reactor in step (c) to generate one or more commercially viable products selected from the group consisting of chemicals, transportation fuels, linear and branched higher olefins, feedstock, detergents, petrochemicals, oil additives, and high-octane gasoline.

7. The process of claim 1, wherein the alcohol is ethanol, wherein the ethanol is further dehydrated in the process to yield ethylene.

8. The process of claim 1, wherein step (c) further comprises an oligomerization step for converting the olefin (e.g., ethylene) to a hydrocarbon fuel.

9. A chemical production process comprising the steps of:

(a) converting a biomass to one or more alcohols and a residual biomass;

(b) gasifying the residual biomass to produce one or more hydrocarbon gasses, carbon monoxide, hydrogen or mixtures thereof;

(c) synthesizing one or more chemicals from the alcohols and the hydrocarbon gases, carbon monoxide, hydrogen, or mixtures thereof; and

(d) combusting the hydrocarbon gasses, the carbon monoxide, the hydrogen, or mixtures thereof to produce heat and electricity, wherein the heat and electricity are recycled back into the process to perform step (c).

10. The process of claim 9, wherein the chemicals is selected from the group consisting of paraffins, olefins, aromatics, and naphthas.

11. The process of claim 9, wherein the chemical is selected from the group consisting of ethylene, acetylene, benzene, cyclohexene, xylene, toluene, ethylbenzene.

12. A process for making one or more hydrocarbon fuels from one or more alcohols comprising the steps of:

(a) dehydrating the one or more alcohols to yield one or more olefins; and

(b) oligomerizing the one or more olefins in an oligomerization reactor to yield one or more commercially viable products selected from the group consisting of chemicals, transportation fuels, linear and branched higher olefins, feedstock, detergents, petrochemicals, oil additives, and high-octane gasoline; and

(c) combusting a carbon monoxide, a hydrogen, or mixtures thereof from a biomass to produce heat and electricity, wherein the heat and electricity are recycled back into the process to perform step (c).

13. The process of claim 12, wherein the process is a “

stand-alone”

process or can be implemented as a “

bolt-on”

addition to existing alcohol producing plants.

14. An integrated biofuel production process comprising the steps of:

(a) pretreating a biomass;

(b) hydrolyzing the converted biomass, wherein the pretreatment and hydrolysis processes are done by using a hot wastewater;

(c) converting a biomass to yield one or more alcohols and a residual biomass;

(d) gasifying the residual biomass to produce carbon monoxide, hydrogen or mixtures thereof, thereby producing thermal energy, wherein at least a portion of the thermal energy produced by the gasification of the residual biomass is recycled back into the process to perform step (c);

(e) synthesizing a liquid hydrocarbon fuel from the alcohols using at least a portion of the thermal energy produced by gasifying the residual biomass;

(f) converting the residual biomass into one or more commercially viable co-products, wherein the co-products are selected from the group consisting of acids, ketones, alcohols, ethers, alkylbenzenes, fuel additives, biopolymers, proteins for animal and human consumption, and surfactants; and

(g) further comprising the step of combusting the carbon monoxide, the hydrogen, or mixtures thereof to produce heat and electricity, wherein the heat and electricity are recycled back into the process to perform step (c).

15. The process of claim 14, wherein the biomass is selected from the group consisting of grasses, trees, canes, animal waste, food waste, algae, municipal solid waste green waste, purpose grown non-food energy crops, harvest residuals, and other waste and crop biomass materials.

16. The process of claim 14, wherein the one or more alcohols generated in step (a) are further converted to one or more olefins by a dehydration reaction, wherein the one or more olefins are selected from the group consisting of ethylene, propylene, butene, iso-butylene, and combinations and modifications thereof.